GB743990A - Production of lower aliphatic acids, particularly acetic acid - Google Patents
Production of lower aliphatic acids, particularly acetic acidInfo
- Publication number
- GB743990A GB743990A GB2579252A GB2579252A GB743990A GB 743990 A GB743990 A GB 743990A GB 2579252 A GB2579252 A GB 2579252A GB 2579252 A GB2579252 A GB 2579252A GB 743990 A GB743990 A GB 743990A
- Authority
- GB
- United Kingdom
- Prior art keywords
- light ends
- acids
- oxidation
- distilled
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title abstract 8
- 125000001931 aliphatic group Chemical group 0.000 title abstract 6
- 238000007254 oxidation reaction Methods 0.000 abstract 12
- 239000000047 product Substances 0.000 abstract 12
- 238000009835 boiling Methods 0.000 abstract 11
- 230000003647 oxidation Effects 0.000 abstract 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 11
- 229930195733 hydrocarbon Natural products 0.000 abstract 8
- 150000002430 hydrocarbons Chemical class 0.000 abstract 8
- 239000004215 Carbon black (E152) Substances 0.000 abstract 7
- 239000000203 mixture Substances 0.000 abstract 7
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 abstract 6
- 239000002253 acid Substances 0.000 abstract 6
- 150000007513 acids Chemical class 0.000 abstract 5
- 125000004432 carbon atom Chemical group C* 0.000 abstract 5
- 239000007788 liquid Substances 0.000 abstract 5
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 4
- 229910001882 dioxygen Inorganic materials 0.000 abstract 4
- 239000007789 gas Substances 0.000 abstract 4
- 239000007791 liquid phase Substances 0.000 abstract 4
- 238000000034 method Methods 0.000 abstract 4
- 239000012188 paraffin wax Substances 0.000 abstract 4
- 238000001816 cooling Methods 0.000 abstract 3
- 238000004821 distillation Methods 0.000 abstract 3
- 230000001590 oxidative effect Effects 0.000 abstract 3
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical class CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- SGGOJYZMTYGPCH-UHFFFAOYSA-L manganese(2+);naphthalene-2-carboxylate Chemical compound [Mn+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 SGGOJYZMTYGPCH-UHFFFAOYSA-L 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000003208 petroleum Substances 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 239000008346 aqueous phase Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000000998 batch distillation Methods 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 235000005985 organic acids Nutrition 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H71/00—Details of the protective switches or relays covered by groups H01H73/00 - H01H83/00
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/487—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2579252A GB743990A (en) | 1952-10-15 | 1952-10-15 | Production of lower aliphatic acids, particularly acetic acid |
| NL182043A NL98985C (enrdf_load_html_response) | 1952-10-15 | 1953-10-14 | |
| NL263236A NL103456C (enrdf_load_html_response) | 1952-10-15 | 1961-04-06 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2579252A GB743990A (en) | 1952-10-15 | 1952-10-15 | Production of lower aliphatic acids, particularly acetic acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB743990A true GB743990A (en) | 1956-01-25 |
Family
ID=10233381
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2579252A Expired GB743990A (en) | 1952-10-15 | 1952-10-15 | Production of lower aliphatic acids, particularly acetic acid |
Country Status (2)
| Country | Link |
|---|---|
| GB (1) | GB743990A (enrdf_load_html_response) |
| NL (2) | NL98985C (enrdf_load_html_response) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2926191A (en) * | 1956-05-22 | 1960-02-23 | Distillers Co Yeast Ltd | Chemical process |
| EP0003399A1 (en) * | 1978-01-27 | 1979-08-08 | BP Chemicals Limited | A method for increasing the selectivity to acetic acid in the production of a mixture of C1 to C3 monocarboxylic acids by oxidation of paraffinic hydrocarbons |
-
1952
- 1952-10-15 GB GB2579252A patent/GB743990A/en not_active Expired
-
1953
- 1953-10-14 NL NL182043A patent/NL98985C/xx active
-
1961
- 1961-04-06 NL NL263236A patent/NL103456C/xx active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2926191A (en) * | 1956-05-22 | 1960-02-23 | Distillers Co Yeast Ltd | Chemical process |
| EP0003399A1 (en) * | 1978-01-27 | 1979-08-08 | BP Chemicals Limited | A method for increasing the selectivity to acetic acid in the production of a mixture of C1 to C3 monocarboxylic acids by oxidation of paraffinic hydrocarbons |
Also Published As
| Publication number | Publication date |
|---|---|
| NL103456C (enrdf_load_html_response) | 1962-11-17 |
| NL98985C (enrdf_load_html_response) | 1961-08-18 |
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