GB728953A - Improvements in or relating to organotin compounds and resins including same - Google Patents
Improvements in or relating to organotin compounds and resins including sameInfo
- Publication number
- GB728953A GB728953A GB15012/51A GB1501251A GB728953A GB 728953 A GB728953 A GB 728953A GB 15012/51 A GB15012/51 A GB 15012/51A GB 1501251 A GB1501251 A GB 1501251A GB 728953 A GB728953 A GB 728953A
- Authority
- GB
- United Kingdom
- Prior art keywords
- radical
- vinyl
- radicals
- hydrocarbon
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title abstract 6
- 229920005989 resin Polymers 0.000 title 1
- 239000011347 resin Substances 0.000 title 1
- -1 hydrocarbon aralkyl radical Chemical class 0.000 abstract 23
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 11
- 150000003254 radicals Chemical class 0.000 abstract 11
- 229910052799 carbon Inorganic materials 0.000 abstract 10
- 229930195733 hydrocarbon Natural products 0.000 abstract 10
- 239000004215 Carbon black (E152) Substances 0.000 abstract 9
- 150000001721 carbon Chemical group 0.000 abstract 6
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 4
- 229910052731 fluorine Inorganic materials 0.000 abstract 4
- 239000011737 fluorine Substances 0.000 abstract 4
- 239000002904 solvent Substances 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 235000019864 coconut oil Nutrition 0.000 abstract 3
- 239000003240 coconut oil Substances 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 3
- 229910052718 tin Inorganic materials 0.000 abstract 3
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 abstract 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- RWNKSTSCBHKHTB-UHFFFAOYSA-N Hexachloro-1,3-butadiene Chemical compound ClC(Cl)=C(Cl)C(Cl)=C(Cl)Cl RWNKSTSCBHKHTB-UHFFFAOYSA-N 0.000 abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 abstract 2
- 150000001733 carboxylic acid esters Chemical class 0.000 abstract 2
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract 2
- 150000003573 thiols Chemical class 0.000 abstract 2
- 229920001567 vinyl ester resin Polymers 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 abstract 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 abstract 1
- ZCKZKCRZJLLYAO-UHFFFAOYSA-N 1-(2-ethoxyethoxy)-2-octylbenzene Chemical compound C(CCCCCCC)C1=C(OCCOCC)C=CC=C1 ZCKZKCRZJLLYAO-UHFFFAOYSA-N 0.000 abstract 1
- DNJRKFKAFWSXSE-UHFFFAOYSA-N 1-chloro-2-ethenoxyethane Chemical class ClCCOC=C DNJRKFKAFWSXSE-UHFFFAOYSA-N 0.000 abstract 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical class C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 abstract 1
- DRHABPMHZRIRAH-UHFFFAOYSA-N 2,4,4,6,6-pentamethylhept-2-ene Chemical group CC(C)=CC(C)(C)CC(C)(C)C DRHABPMHZRIRAH-UHFFFAOYSA-N 0.000 abstract 1
- URRHKOYTHDCSDA-UHFFFAOYSA-N 2,5,8,11-tetramethyldodec-2-ene Chemical group CC(C)CCC(C)CCC(C)CC=C(C)C URRHKOYTHDCSDA-UHFFFAOYSA-N 0.000 abstract 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- GNUGVECARVKIPH-UHFFFAOYSA-N 2-ethenoxypropane Chemical compound CC(C)OC=C GNUGVECARVKIPH-UHFFFAOYSA-N 0.000 abstract 1
- MZNSQRLUUXWLSB-UHFFFAOYSA-N 2-ethenyl-1h-pyrrole Chemical class C=CC1=CC=CN1 MZNSQRLUUXWLSB-UHFFFAOYSA-N 0.000 abstract 1
- 125000002941 2-furyl group Chemical group O1C([*])=C([H])C([H])=C1[H] 0.000 abstract 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- 125000000175 2-thienyl group Chemical group S1C([*])=C([H])C([H])=C1[H] 0.000 abstract 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical class C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 abstract 1
- 125000006283 4-chlorobenzyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1Cl)C([H])([H])* 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 abstract 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 abstract 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 abstract 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 abstract 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 abstract 1
- 125000006177 alkyl benzyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 abstract 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 239000001506 calcium phosphate Substances 0.000 abstract 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-M chloroacetate Chemical compound [O-]C(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-M 0.000 abstract 1
- 229940089960 chloroacetate Drugs 0.000 abstract 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- IEPRKVQEAMIZSS-AATRIKPKSA-N diethyl fumarate Chemical compound CCOC(=O)\C=C\C(=O)OCC IEPRKVQEAMIZSS-AATRIKPKSA-N 0.000 abstract 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 229940093495 ethanethiol Drugs 0.000 abstract 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 abstract 1
- CVUNPKSKGHPMSY-UHFFFAOYSA-N ethyl 2-chloroprop-2-enoate Chemical class CCOC(=O)C(Cl)=C CVUNPKSKGHPMSY-UHFFFAOYSA-N 0.000 abstract 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- JFZUABNDWZQLIJ-UHFFFAOYSA-N methyl 2-[(2-chloroacetyl)amino]benzoate Chemical compound COC(=O)C1=CC=CC=C1NC(=O)CCl JFZUABNDWZQLIJ-UHFFFAOYSA-N 0.000 abstract 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 abstract 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000000552 p-cresyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1O*)C([H])([H])[H] 0.000 abstract 1
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 abstract 1
- UCUUFSAXZMGPGH-UHFFFAOYSA-N penta-1,4-dien-3-one Chemical compound C=CC(=O)C=C UCUUFSAXZMGPGH-UHFFFAOYSA-N 0.000 abstract 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 abstract 1
- 229920001596 poly (chlorostyrenes) Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- NBOMNTLFRHMDEZ-UHFFFAOYSA-N thiosalicylic acid Chemical compound OC(=O)C1=CC=CC=C1S NBOMNTLFRHMDEZ-UHFFFAOYSA-N 0.000 abstract 1
- 229940103494 thiosalicylic acid Drugs 0.000 abstract 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 abstract 1
- 229940078499 tricalcium phosphate Drugs 0.000 abstract 1
- 229910000391 tricalcium phosphate Inorganic materials 0.000 abstract 1
- 235000019731 tricalcium phosphate Nutrition 0.000 abstract 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/226—Compounds with one or more Sn-S linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A resinous composition comprises a vinyl chloride polymer or copolymer thereof with another ethylenically unsaturated compound and from 0.2 to 5.0 per cent of an organo-tin compound of the general formula <FORM:0728953/IV (a)/1> wherein R1 represents a hydrocarbon alkyl, hydrocarbon aryl or hydrocarbon aralkyl radical which may be substituted by an ether, carboxylic, carboxylic ester, thiol or hydroxy radical or by a halogen other than fluorine on an aromatic ring carbon or by fluorine on any carbon atom or by an aliphatic hydrocarbon radical containing an ethylenic or acetylenic linkage, or R1 is a heterocyclic radical, said R1 radical being attached to the sulphur atom by means of a carbon atom, and R2 represents an aliphatic hydrocarbon, aryl hydrocarbon or heterocyclic radical which may be substituted by an ether radical, said R2 radical being attached to the tin atom by means of a carbon atom (see Group IV (b)). Both the R1 radicals or the R2 radicals may be the same or different. Suitable compounds for copolymerization with vinyl chloride are vinyl esters, e.g. vinyl bromide and fluoride, fatty acid vinyl esters such as vinyl acetate, chloroacetate and butyrate and vinyl alkyl sulphonates, vinyl ethers, e.g. vinyl ethyl ether, vinyl isopropyl ether and vinyl chloroethyl ethers, cyclic ethylenically unsaturated compounds, e.g. styrene, the mono-and polychlorostyrenes, coumarone, indene, vinyl naphthalenes, vinyl pyridines and vinyl pyrroles, acrylic acid and its derivatives, e.g. ethyl acrylate, methyl methacrylate, ethyl methacrylate, ethyl chloroacrylates, acrylonitrile, methacrylonitrile, diethyl maleate and diethyl fumarate, vinylidene compounds, e.g. vinylidene chloride, bromide and fluorochloride, unsaturated ethylenic hydrocarbons, e.g. ethylene, propylene and isobutene, allyl compounds, e.g. allyl acetate, allyl chloride and allyl ethyl ether, and conjugated and cross-conjugated ethylenically unsaturated compounds, e.g. butadiene, isoprene, chloroprene, 2,3-dimethylbutadiene-1,3, piperylene and divinyl ketone. The resinous composition may be in the form of a thin flexible film and may contain other ingredients such as di-(2-ethylhexyl)-phthalate, tricalcium phosphate and a silicate pigment.ALSO:<FORM:0728953/IV (b)/1> wherein R1 represents a hydrocarbon alkyl, hydrocarbon aryl or hydrocarbon aralkyl aralkyl radical which may be substituted by an ether, carboxylic, carboxylic ester, thiol or hydroxy radical or by a halogen other than fluorine on an aromatic ring carbon atom or by fluorine on any carbon atom or by an aliphatic hydrocarbon radical containing an ethylenic or acetylenic linkage, or R1 is a heterocyclic radical, said R1 radical being attached to the sulphur atom by means of a carbon atom, and R2 represents an aliphatic hydrocarbon, aryl hydrocarbon or heterocyclic radical which may be substituted by an ether radical, said R2 radical being attached to the tin atom by means of a carbon atom, and the preparation thereof by reacting at a temperature in the range of 40 DEG to 180 DEG C. a mercaptan of the formula R1SH and a stannone of the formula <FORM:0728953/IV (b)/2> wherein R1 and R2 have the above significance. The organo-tin compounds may also be prepared by reacting at a temperature in the range of 60 DEG to 200 DEG C. an alkali metal mercaptide of the formula R2S-alk and a diorgano-tin halide of the formula <FORM:0728953/IV (b)/3> wherein R1 and R2 have the above significanec and alk represents an alkali metal. Non-reactive solvents may be used in either of the above processes, e.g. hydrocarbon solvents such as benzene, toluene, xylene or petroleum ether, or chlorinated solvents such as carbon tetrachloride, trichloroethylene, tetrachloroethylene or hexachlorobutadiene, or oxygenated solvents such as diethyl ether. The radicals R2 may be the same or different and may represent methyl, ethyl, isobutyl, n-butyl, n-hexyl, lauryl, hexadecyl, phenyl b -naphthyl, 2-thienyl, 2-furyl, xenyl and 2-ethoxyethyl radicals or alkyl radicals derived from reduced coconut oil. The Specification refers to a large number of mercaptans from which the R1 radicals are derived, and the R1 radicals may be the same or different. In the examples, compounds of the above general formula are prepared wherein the R1 radicals are derived from butyl, amyl, t-dodecyl, hexadecyl, t-hexadecyl, octadecyl, tridecyl, benzyl, alkylbenzyl, p-chlorobenzyl, phenyl, p-cresyl and a - and b -naphthyl mercaptans, methylbenzoate-2-thiol, alpha-thiophenethiol 2 - { 2 - (2 - octylphenoxy) ethoxy } ethane thiol, 2-mercaptoethanol, thiosalicylic acid, the mercaptans obtained by the addition of hydrogen sulphide to triisobutylene, tetraisobutylene, 8-carbon olefines, and mixtures of 8-, 12- and 14-carbon olefines, and alkyl mercaptans where the alkyl radicals are derived from reduced coconut oil, and the R2 radicals represent methyl, n-butyl, phenyl and 2-thienyl radicals and alkyl radicals derived from reduced coconut oil.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US728953XA | 1950-06-27 | 1950-06-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB728953A true GB728953A (en) | 1955-04-27 |
Family
ID=22110393
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB15012/51A Expired GB728953A (en) | 1950-06-27 | 1951-06-25 | Improvements in or relating to organotin compounds and resins including same |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB728953A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1146250B (en) * | 1957-06-18 | 1963-03-28 | Advance Produktion G M B H Deu | Process for the production of molding compounds stabilized against the effects of heat and based on halogen-containing vinyl polymers |
| FR2369287A1 (en) * | 1976-11-02 | 1978-05-26 | M & T Chemicals Inc | PROCESS FOR THE PREPARATION OF ORGANIC TIN DERIVATIVES OF MERCAPTOALCOOLIC ESTERS |
| CN110183484A (en) * | 2019-05-06 | 2019-08-30 | 衡阳师范学院 | Two (thio-methyl salicylate) two (o-chlorobenzyl) tin complexs of one kind and preparation method and application |
-
1951
- 1951-06-25 GB GB15012/51A patent/GB728953A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1146250B (en) * | 1957-06-18 | 1963-03-28 | Advance Produktion G M B H Deu | Process for the production of molding compounds stabilized against the effects of heat and based on halogen-containing vinyl polymers |
| FR2369287A1 (en) * | 1976-11-02 | 1978-05-26 | M & T Chemicals Inc | PROCESS FOR THE PREPARATION OF ORGANIC TIN DERIVATIVES OF MERCAPTOALCOOLIC ESTERS |
| CN110183484A (en) * | 2019-05-06 | 2019-08-30 | 衡阳师范学院 | Two (thio-methyl salicylate) two (o-chlorobenzyl) tin complexs of one kind and preparation method and application |
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