GB727717A - Improvements in methods of chemically modifying butyl rubber and products resulting therefrom - Google Patents

Improvements in methods of chemically modifying butyl rubber and products resulting therefrom

Info

Publication number
GB727717A
GB727717A GB28483/53A GB2848353A GB727717A GB 727717 A GB727717 A GB 727717A GB 28483/53 A GB28483/53 A GB 28483/53A GB 2848353 A GB2848353 A GB 2848353A GB 727717 A GB727717 A GB 727717A
Authority
GB
United Kingdom
Prior art keywords
parts
butyl rubber
butyl
butadiene
methods
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28483/53A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Uniroyal Inc
Original Assignee
United States Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by United States Rubber Co filed Critical United States Rubber Co
Publication of GB727717A publication Critical patent/GB727717A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Butyl rubber is vulcanized by heating it with a dimethylol phenol and chlorosulphonated polythene in the presence of zinc oxide or of a zinc salt of a fatty acid. The Butyl rubber may be derived from isobutylene or ethyl methyl ethylene and butadiene, isoprene, piperylene, 1,2-, 1,3-, 1,4-, or 2,3-dimethyl butadiene or 1-ethyl butadiene. The dimethylol phenol may be resinous or not, and specified are 2,6-di-methylol 4-hydrocarbon phenols where the hydrocarbon is methyl, tertiary-butyl, octyl, tertiary-octyl, dodecyl, phenyl, benzyl, alpha, alpha-dimethyl-benzyl and cyclohexyl. Specified zinc salts are the laurate and stearate. Preferred amounts of phenol are about 4 to 15 parts, of chlorosulphonated polythene about 2 to 10 parts, and of zinc oxide (or its salt equivalent) 1 to 5 parts, all per 100 parts of Butyl, while preferred temperatures are 320-370 DEG F. The rubber may be compounded with reinforcing material, e.g. carbon black, and used for curing bags or inner tubes. Specification 718,768 is referred to.
GB28483/53A 1952-12-30 1953-10-15 Improvements in methods of chemically modifying butyl rubber and products resulting therefrom Expired GB727717A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US727717XA 1952-12-30 1952-12-30

Publications (1)

Publication Number Publication Date
GB727717A true GB727717A (en) 1955-04-06

Family

ID=22109649

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28483/53A Expired GB727717A (en) 1952-12-30 1953-10-15 Improvements in methods of chemically modifying butyl rubber and products resulting therefrom

Country Status (1)

Country Link
GB (1) GB727717A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0032123A2 (en) * 1980-01-04 1981-07-15 Monsanto Company Mono-olefin polymers having methylol phenolic groups grafted thereto, a process for their production and polymer blends containing them

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0032123A2 (en) * 1980-01-04 1981-07-15 Monsanto Company Mono-olefin polymers having methylol phenolic groups grafted thereto, a process for their production and polymer blends containing them
EP0032123A3 (en) * 1980-01-04 1981-07-22 Monsanto Company Mono-olefin polymers having methylol phenolic groups grafted thereto, a process for their production and polymer blends containing them

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