GB725476A - Anti-oxidant - Google Patents

Anti-oxidant

Info

Publication number
GB725476A
GB725476A GB14902/53A GB1490253A GB725476A GB 725476 A GB725476 A GB 725476A GB 14902/53 A GB14902/53 A GB 14902/53A GB 1490253 A GB1490253 A GB 1490253A GB 725476 A GB725476 A GB 725476A
Authority
GB
United Kingdom
Prior art keywords
thiophenols
oil
alkali metal
dibromo
metal hydroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB14902/53A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB725476A publication Critical patent/GB725476A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/086—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing sulfur atoms bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/135—Steam engines or turbines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/16—Dielectric; Insulating oil or insulators
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/17—Electric or magnetic purposes for electric contacts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Sulphur-containing products useful as antioxidants for mineral oils are prepared by reacting an "acid oil" with an alkali metal hydroxide in amount equivalent to the thiophenols in the oil and with a halohydrocarbon having at least two but not more than twice as many halogen atoms as carbon atoms, in amount at most equivalent to the thiophenols in the oil, and removing the unreacted components, the alkali metal halide, water and resinous components from the reaction mixture. By "acid oil" is meant the product containing thiophenols and possibly phenols, obtained in the refining of cracked gasoline by treating it with an alkaline solution and releasing the thiophenols and phenols from the alkaline solution by acidification. The halohydrocarbon can be added to the acid oil simultaneously with the alkali metal hydroxide or after the thiophenolate has been formed. Specified halogen compounds are dichloro- and dibromo-methane, 1,2-dichloroethane, 1,1,2-trichloroethane and 2,5-dibromo-2,5-dimethylhexane. Mixtures may be used. The alkali metal hydroxide is preferably used in an aqueous or alcoholic solution, and reaction temperatures of 70 DEG to 140 DEG or higher are generally used. The reaction mixture is afterwards separated into phases, if necessary by adding water, and the upper phase mixed with a diluent, e.g. gasoline. It is then washed with water, treated with a little dilute acid and distilled. The product may be deodorized by treatment with alcoholic caustic soda.ALSO:Sulphur-containing compounds which are substantially reaction products of thiophenolates and halohydrocarbons are used as antioxidants for mineral oils and for lubricants containing mineral oils. The products are prepared by reacting an "acid oil" with an alkali metal hydroxide in amount equivalent to the thiophenols in the oil and with a halohydrocarbon having at least two but not more than twice as many halogen atoms as carbon atoms, in amount at most equivalent to the thiophenols in the oil, and removing the unreacted components, halide, water and resinous components from the mixture. By "acid oil" is meant the product obtained in the refining of cracked gasoline by treating it with an alkaline solution and releasing the thiophenols and phenols by acidification. Special halohydrocarbons are dichloro-and dibromo-methane, 1, 2-dichlorethane, 1, 1, 2 trichloroethane, and 2, 5-dibromo-2, 5-dimethyl-hexane.
GB14902/53A 1952-05-30 1953-05-28 Anti-oxidant Expired GB725476A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL725476X 1952-05-30

Publications (1)

Publication Number Publication Date
GB725476A true GB725476A (en) 1955-03-02

Family

ID=19817792

Family Applications (1)

Application Number Title Priority Date Filing Date
GB14902/53A Expired GB725476A (en) 1952-05-30 1953-05-28 Anti-oxidant

Country Status (4)

Country Link
US (1) US2813834A (en)
BE (1) BE520273A (en)
FR (1) FR1082818A (en)
GB (1) GB725476A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9296956B2 (en) 2010-10-28 2016-03-29 Chevron U.S.A. Inc. Method for reducing mercaptans in hydrocarbons

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2278224A (en) * 1940-03-12 1942-03-31 Subkow Philip Inhibitor
US2460567A (en) * 1944-10-04 1949-02-01 Goodrich Co B F Aromatic mercapto-aliphatic ethers as modifiers for butadiene emulsion polymerization

Also Published As

Publication number Publication date
FR1082818A (en) 1955-01-03
US2813834A (en) 1957-11-19
BE520273A (en)

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