GB720199A - Improvements in or relating to solutions of acrylonitrile polymers - Google Patents

Improvements in or relating to solutions of acrylonitrile polymers

Info

Publication number
GB720199A
GB720199A GB488052A GB488052A GB720199A GB 720199 A GB720199 A GB 720199A GB 488052 A GB488052 A GB 488052A GB 488052 A GB488052 A GB 488052A GB 720199 A GB720199 A GB 720199A
Authority
GB
United Kingdom
Prior art keywords
acrylonitrile
lower alkyl
solutions
fibres
films
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB488052A
Inventor
John Downing
James Wotherspoon Fisher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Acordis UK Ltd
Original Assignee
British Celanese Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Celanese Ltd filed Critical British Celanese Ltd
Priority to GB488052A priority Critical patent/GB720199A/en
Publication of GB720199A publication Critical patent/GB720199A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/09Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
    • C08J3/091Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids characterised by the chemical constitution of the organic liquid
    • C08J3/096Nitrogen containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/18Homopolymers or copolymers of nitriles
    • C08J2333/20Homopolymers or copolymers of acrylonitrile

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Artificial Filaments (AREA)

Abstract

Copolymers of acrylonitrile with lower alkyl esters of acrylic or lower alkyl acrylic acids which contain 85 to 94 per cent of acrylonitrile are dissolved in nitromethane which is either anhydrous or contains not more than 3 per cent of water. The lower alkyl groups forming the esters or substituting the acrylic acid are those containing 1 to 4 carbon atoms. The solutions may be formed into fibres or films by the dry or wet spinning and casting techniques. After formation the fibres and films may be oriented by hot-stretching. The preparation is described of a copolymer of acrylonitrile and methyl acrylate by copolymerization of the monomers in a mixture of water and methyl alcohol using a mixture of ammonium persulphate and sodium metabisulphite as a catalyst. Specifications 636,476, 711,344 and 712,984 are referred to.
GB488052A 1952-02-25 1952-02-25 Improvements in or relating to solutions of acrylonitrile polymers Expired GB720199A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB488052A GB720199A (en) 1952-02-25 1952-02-25 Improvements in or relating to solutions of acrylonitrile polymers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB488052A GB720199A (en) 1952-02-25 1952-02-25 Improvements in or relating to solutions of acrylonitrile polymers

Publications (1)

Publication Number Publication Date
GB720199A true GB720199A (en) 1954-12-15

Family

ID=9785567

Family Applications (1)

Application Number Title Priority Date Filing Date
GB488052A Expired GB720199A (en) 1952-02-25 1952-02-25 Improvements in or relating to solutions of acrylonitrile polymers

Country Status (1)

Country Link
GB (1) GB720199A (en)

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