GB718283A - Improvements in or relating to the production of metal containing synthetic resins - Google Patents
Improvements in or relating to the production of metal containing synthetic resinsInfo
- Publication number
- GB718283A GB718283A GB21907/51A GB2190751A GB718283A GB 718283 A GB718283 A GB 718283A GB 21907/51 A GB21907/51 A GB 21907/51A GB 2190751 A GB2190751 A GB 2190751A GB 718283 A GB718283 A GB 718283A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acetoacetic ester
- aluminium
- butylate
- reacted
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/10—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
Abstract
Synthetic resins are produced by heating at elevated temperatures a halide or an alcoholate (from a monohydric aliphatic alcohol) of a metal with a valency of 3 or more with a compound showing keto-enol tautomerism and which is a b -ketocarboxylic acid, a b -diketone or a malonic acid ester at least one mol. of the latter being used/atomic weight of metal. Metal compounds mentioned are the butylates or propylates of aluminium, iron, titanium, and aluminium chloride. Tautomers mentioned are acetoacetic ester, diethyl malonate, and formylacetophenone. Reaction is preferably effected in vacuo. In Example 1 aluminium butylate is refluxed with acetoacetic ester, volatile components removed by heating to 130-150 DEG C. in vacuo or higher without a vacuum, and an air-drying oil is left as product, (2) aluminium butylate is reacted with diethyl malonate; (3) ferric butylate is reacted with acetoacetic ester; (4) aluminium chloride is reacted with acetoacetic ester in toluene at temperatures which reach 180 DEG C.; (5) titanium butylate is refluxed with acetoacetic ester. Specifications 289,493, [Class 2 (iii)], and 630,319, and U.S.A. Specification 2,169,577 are referred to.ALSO:Synthetic resins are produced by heating at elevated temperatures a halide or an alcoholate (from a monohydric aliphatic alcohol) of a metal with a valency of 3 or more with a compound showing keto-enol tautomerism and which is a b -ketocarboxylic acid, a b -diketone or a malonic acid ester, at least one mol. of the latter being used per atomic weight of metal. Metal compounds mentioned are the butylates or propylates of aluminium, iron, titanium and aluminium chloride. Tautomers mentioned are acetoacetic ester, diethyl malonate and formylacetophenone. Reaction is preferably effected in vacuo. In examples (1) aluminium butylate is refluxed with acetoacetic ester, volatile components removed by heating to 130-150 DEG C. in vacuo or higher without a vacuum, and an airdrying oil is left as product; (2) aluminium butylate is reacted with diethyl malonate; (3) ferric butylate is reacted with acetoacetic ester; (4) aluminium chloride is reacted with acetoacetic ester in toluene at temperatures which reach 180 DEG C.; (5) titanium butylate is refluxed with acetoacetic ester. Specifications 289,483, [Class 2 (iii)], 630,319, [Group IV (a)], and U.S.A. Specification 2,169,577 are referred to.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE718283X | 1951-01-05 | ||
DEC4287A DE976417C (en) | 1951-01-05 | 1951-06-04 | Process for the production of synthetic resins |
DEC4953A DE974107C (en) | 1951-01-05 | 1951-11-12 | Process for improving the shelf life of synthetic resins |
DEC5198A DE975321C (en) | 1951-01-05 | 1951-12-29 | Process for improving the drying properties of autoxidatively drying synthetic resins, oils, paints, putties and adhesives |
Publications (1)
Publication Number | Publication Date |
---|---|
GB718283A true GB718283A (en) | 1954-11-10 |
Family
ID=41509014
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB21907/51A Expired GB718283A (en) | 1951-01-05 | 1951-09-18 | Improvements in or relating to the production of metal containing synthetic resins |
GB22847/51A Expired GB718284A (en) | 1951-01-05 | 1951-10-01 | Process for the modification of metal-containing synthetic resins |
GB28004/53A Expired GB718359A (en) | 1951-01-05 | 1951-10-01 | Process for the modification of metal-containing synthetic resins |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB22847/51A Expired GB718284A (en) | 1951-01-05 | 1951-10-01 | Process for the modification of metal-containing synthetic resins |
GB28004/53A Expired GB718359A (en) | 1951-01-05 | 1951-10-01 | Process for the modification of metal-containing synthetic resins |
Country Status (3)
Country | Link |
---|---|
DE (3) | DE976417C (en) |
GB (3) | GB718283A (en) |
NL (1) | NL83793C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2839421A (en) * | 1955-04-06 | 1958-06-17 | Du Pont | An alkoxy aluminum chelate, a dispersion of it in an organic liquid and a water repellant porous object |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE569946C (en) * | 1931-03-25 | 1933-02-09 | I G Farbenindustrie Akt Ges | Process for the preparation of the aluminum salts of carboxylic acids |
DE966973C (en) * | 1943-07-10 | 1957-09-19 | Rheinpreussen Ag | Process for the production of high molecular weight, spinnable plastics |
-
1951
- 1951-06-04 DE DEC4287A patent/DE976417C/en not_active Expired
- 1951-09-18 GB GB21907/51A patent/GB718283A/en not_active Expired
- 1951-10-01 GB GB22847/51A patent/GB718284A/en not_active Expired
- 1951-10-01 GB GB28004/53A patent/GB718359A/en not_active Expired
- 1951-11-12 DE DEC4953A patent/DE974107C/en not_active Expired
- 1951-12-29 DE DEC5198A patent/DE975321C/en not_active Expired
-
1952
- 1952-04-17 NL NL168846A patent/NL83793C/en active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2839421A (en) * | 1955-04-06 | 1958-06-17 | Du Pont | An alkoxy aluminum chelate, a dispersion of it in an organic liquid and a water repellant porous object |
Also Published As
Publication number | Publication date |
---|---|
DE974107C (en) | 1960-09-15 |
NL83793C (en) | 1957-01-15 |
DE976417C (en) | 1963-08-14 |
DE975321C (en) | 1961-11-09 |
GB718359A (en) | 1954-11-10 |
GB718284A (en) | 1954-11-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2157164A (en) | Manufacture of esters of phosphoric acid | |
GB718283A (en) | Improvements in or relating to the production of metal containing synthetic resins | |
US2957900A (en) | Compounds containing boron and silicon | |
ES419771A1 (en) | Method for making higher alkyl tin thichlorides | |
GB1392562A (en) | Antiperspirant compositions | |
GB1213558A (en) | Process for the production of 1,1-dihydroperfluoroalkanols | |
US2556134A (en) | Preparation of thioether esters | |
US2407302A (en) | Condensation of ketenes with ketoesters | |
Bradley et al. | 979. Structural chemistry of the alkoxides. Part III. Secondary alkoxides of silicon, titanium, and zirconium | |
US2218026A (en) | Organic condensation | |
US2517543A (en) | Acetals of 2-oxy-tetrahydropyran and tetrahydrofuran-3-aldehydes and process of preparing the same | |
US2116347A (en) | Alpha-salicylo-aliphatic acid esters | |
US2451610A (en) | Preparation of 4-alkyl-quinolines | |
US2496791A (en) | Method of forming unsaturated acid esters | |
US3492360A (en) | 2-methyl-6-(4'-methyl-3'-cyclohexen- 1'-yl)-5-hepten-2-ol | |
GB698736A (en) | Manufacture of alkoxy substituted pentanes and tetrahydropyrans | |
US2700048A (en) | Process of producing organometallic compounds | |
US2530273A (en) | Preparation of aryl diketones | |
US2535009A (en) | Process for producing esters of alkoxy carboxylic acids | |
GB786322A (en) | Pest control agent | |
GB907558A (en) | Improved process for the production of organometallic complexes | |
US2600387A (en) | Carboxyalkylation of ketonic compounds | |
DE920546C (en) | Process for the preparation of derivatives of 3- (4'-oxyphenyl) -3- (4 "-oxy-3" -aminomethyl-phenyl) -oxindole | |
GB452934A (en) | Improvements in or relating to the manufacture and production of alkyl halides | |
GB1003090A (en) | Process for the production of n,n,n-triorgano-substituted borazoles |