GB717483A - Process for the recovery of sulphur from hydrogen sulphide - Google Patents
Process for the recovery of sulphur from hydrogen sulphideInfo
- Publication number
- GB717483A GB717483A GB3230852A GB3230852A GB717483A GB 717483 A GB717483 A GB 717483A GB 3230852 A GB3230852 A GB 3230852A GB 3230852 A GB3230852 A GB 3230852A GB 717483 A GB717483 A GB 717483A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sulphur
- hydrogen sulphide
- catalyst
- stage
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/0426—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process characterised by the catalytic conversion
- C01B17/0439—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process characterised by the catalytic conversion at least one catalyst bed operating below the dew-point of sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
Abstract
In recovering sulphur from hydrogen sulphide by interacting hydrogen sulphide and sulphur dioxide in two catalyst stages using a granular catalyst in fixed beds, the first stage being carried out at a temperature of about 300 DEG C. or higher such that sulphur is produced as a vapour and the second at a lower temperature such that sulphur is deposited on the catalyst, sulphur being separated from the gases leaving the first stage before passing them to the second two catalyst chambers are used in the second stage alternatively for reaction and regeneration. The hydrogen sulphide is reacted with sufficient sulphur dioxide to convert all the hydrogen sulphide being treated to sulphur and water vapour assuming complete reaction, i.e. the minimum ratio of hydrogen sulphide to sulphur dioxide is 2 : 1 by volume. The catalyst may be alumina, bauxite or bauxite promoted with iron oxide. The temperature in the second stage reaction may be maintained at 150 DEG C. The gases resulting from the second stage reaction may be used, after heating, in the regeneration process.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3230852A GB717483A (en) | 1952-12-19 | 1952-12-19 | Process for the recovery of sulphur from hydrogen sulphide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3230852A GB717483A (en) | 1952-12-19 | 1952-12-19 | Process for the recovery of sulphur from hydrogen sulphide |
Publications (1)
Publication Number | Publication Date |
---|---|
GB717483A true GB717483A (en) | 1954-10-27 |
Family
ID=10336574
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3230852A Expired GB717483A (en) | 1952-12-19 | 1952-12-19 | Process for the recovery of sulphur from hydrogen sulphide |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB717483A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2077155A5 (en) * | 1970-05-22 | 1971-10-15 | Pan American Petroleum Corp | |
DE2222731A1 (en) * | 1971-06-21 | 1973-01-11 | Amoco Prod Co | METHOD OF CATALYTIC CONVERSION OF A GAS FLOW CONTAINING HYDROGEN SULFUR |
USRE28830E (en) | 1970-05-22 | 1976-05-25 | Amoco Production Company | Method for reducing sulfur compounds in sulfur plant effluent |
US4071607A (en) | 1975-12-08 | 1978-01-31 | Metallgesellschaft Aktiengesellschaft | Process for producing sulfur |
US4155990A (en) * | 1977-01-05 | 1979-05-22 | Hitachi, Ltd. | Process for removal and recovery of sulfide from coal gas |
US4255408A (en) | 1977-11-11 | 1981-03-10 | Thermo-Mist Company | Process for removing sulfur and sulfur compounds from the effluent of industrial processes |
US4263271A (en) * | 1978-03-15 | 1981-04-21 | Bergwerksverband Gmbh | Process for eliminating hydrogen sulfide from gas mixtures |
US4309402A (en) * | 1977-12-10 | 1982-01-05 | Davy International Ag | Process and apparatus for production of elemental sulfur |
US4426369A (en) | 1981-03-02 | 1984-01-17 | Standard Oil Company (Indiana) | Low temperature Claus process with water removal |
US4430317A (en) | 1981-03-02 | 1984-02-07 | Standard Oil Company (Indiana) | Low temperature Claus process with water removal |
-
1952
- 1952-12-19 GB GB3230852A patent/GB717483A/en not_active Expired
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2077155A5 (en) * | 1970-05-22 | 1971-10-15 | Pan American Petroleum Corp | |
USRE28830E (en) | 1970-05-22 | 1976-05-25 | Amoco Production Company | Method for reducing sulfur compounds in sulfur plant effluent |
DE2222731A1 (en) * | 1971-06-21 | 1973-01-11 | Amoco Prod Co | METHOD OF CATALYTIC CONVERSION OF A GAS FLOW CONTAINING HYDROGEN SULFUR |
US4071607A (en) | 1975-12-08 | 1978-01-31 | Metallgesellschaft Aktiengesellschaft | Process for producing sulfur |
US4155990A (en) * | 1977-01-05 | 1979-05-22 | Hitachi, Ltd. | Process for removal and recovery of sulfide from coal gas |
US4255408A (en) | 1977-11-11 | 1981-03-10 | Thermo-Mist Company | Process for removing sulfur and sulfur compounds from the effluent of industrial processes |
US4309402A (en) * | 1977-12-10 | 1982-01-05 | Davy International Ag | Process and apparatus for production of elemental sulfur |
US4263271A (en) * | 1978-03-15 | 1981-04-21 | Bergwerksverband Gmbh | Process for eliminating hydrogen sulfide from gas mixtures |
US4426369A (en) | 1981-03-02 | 1984-01-17 | Standard Oil Company (Indiana) | Low temperature Claus process with water removal |
US4430317A (en) | 1981-03-02 | 1984-02-07 | Standard Oil Company (Indiana) | Low temperature Claus process with water removal |
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