GB717407A - Formed detergents - Google Patents
Formed detergentsInfo
- Publication number
- GB717407A GB717407A GB25309/50A GB2530950A GB717407A GB 717407 A GB717407 A GB 717407A GB 25309/50 A GB25309/50 A GB 25309/50A GB 2530950 A GB2530950 A GB 2530950A GB 717407 A GB717407 A GB 717407A
- Authority
- GB
- United Kingdom
- Prior art keywords
- orthophosphoric acid
- radicle
- esters
- active
- ethylene oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/34—Derivatives of acids of phosphorus
- C11D1/345—Phosphates or phosphites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/34—Derivatives of acids of phosphorus
- C11D1/342—Phosphonates; Phosphinates or phosphonites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/34—Organic compounds, e.g. vitamins containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
A detergent in shaped form, suitable for repeated use after the manner of soap tablets, consists of or comprises a primary and/or secondary ester of orthophosphoric acid, or a salt of such an ester, wherein at least one hydrocarbon group having at least 8 carbon atoms is linked to the phosphoric acid radicle through a chain of the general formula O(RO)n, in which R denotes an aliphatic divalent radicle containing at least two carbon atoms and n denotes an integer not less than 2. In the preparation of suitable esters, a compound containing the surface-active radicle (i.e. the hydrocarbon group having at least 8 carbon atoms, referred to above) may be condensed with a compound supplying the (RO)n chain and carrying a hydroxyl group, and the condensation product then esterified with orthophosphoric acid. Thus, oleic acid can be reacted with a plurality of molecules of ethylene oxide or propylene oxide and the reaction product esterified with orthophosphoric acid. It is also possible, however, to react oleic acid amide with ethylene oxide and esterify the reaction product with orthophosphoric acid. Alternatively, the compound carrying the hydroxyl group may first be converted into an orthophosphoric acid ester, and then the surface-active radicle introduced into the molecule of the ester so that it is linked to the phosphorus atom through the (RO)n chain. Where, in the preparation of the esters, the material to be esterified with orthophosphoric acid contains in its molecule more than one hydroxyl group available for esterification, polyesters of orthophosphoric acid may be produced and utilized in the shaped detergents. The secondary esters or their salts can carry the same surface-active radicle twice or two different surface active radicles in the same molecule. Alternatively, they may contain only one surface-active radicle. Salts of the esters mentioned are the alkali, ammonia and amine salts. The shaped detergents may also contain adjuvant materials (see Group III). In the examples, shaped detergents are prepared from mixtures of (1) sodium stearate, sodium salt of mono-(dibutylphenyl)-polyglycol (10 ethylene oxide radicles) orthophosphate and water, and (2) monolauryl orthophosphate, mono-octadecyl orthophosphate, the orthophosphoric acid mono- and di-esters of dibutylphenylpolyglycol (10 ethylene oxide radicles), water and sufficient caustic soda to bring the pH of the mixture to 6-7.ALSO:A detergent in shaped form, suitable for repeated use after the manner of soap tablets, consists of or comprises a primary and/or secondary ester of orthophosphoric acid, or a salt of such an ester, wherein at least one hydrocarbon group having at least 8 carbon atoms is linked to the phosphoric acid radicle through a chain of the general formula O(RO)n in which R denotes an aliphatic divalent radicle containing at least two carbon atoms and n denotes an integer not less than 2. In the preparation of suitable esters, a compound containing the surface-active radicle (i.e. the hydrocarbon group having at least 8 carbon atoms, referred to above) may be condensed with a compound supplying the (RO)n chain and carrying a hydroxyl group, and the condensation product then esterified with orthophosphoric acid. Thus, oleic acid can be reacted with a plurality of molecules of ethylene oxide or propylene oxide and the reaction product esterified with orthophosphoric acid. It is also possible, however, to react oleic acid amide with ethylene oxide and esterify the reaction product with orthophosphoric acid. Alternatively, the compound carrying the hydroxyl group may first be converted into an orthophosphoric acid ester, and then the surface active radicle introduced into the molecule of the ester so that it is linked to the phosphorus atom through the (RO)n chain. Where, in the preparation of the esters, the material to be esterified with orthophosphoric acid contains in its molecule more than one hydroxyl group available for esterification, polyesters of orthophosphoric acid may be produced and utilized in the shaped detergents. The secondary esters or their salts can carry the same surface-active radicle twice or two different surface-active radicles in the same molecule. Alternatively they may contain only one surface-active radicle. Salts of the esters mentioned are the alkali, ammonia and amine salts. The shaped detergents may contain adjuvant materials such as soaps, other synthetic detergents (of which a list is given) filling agents and building agents. Thus, they may contain water glass, phosphates including polyphosphates and metaphosphates, borax, water-soluble cellulose derivatives, alginates, water-soluble starches, polyvinyl alcohol and water-soluble salts of polyhydroxy acids. Filling materials particularly mentioned are the salts of phosphoric acid esters of starch, cellulose, other polysaccharides, polyglycerol, polyglycol or polyvinyl alcohol. In the examples, shaped detergents are prepared from mixtures of (1) sodium stearate, sodium salt of mono-(dibutyl-phenyl)-polyglycol (10 ethylene oxide radicles) orthophosphate and water, and (2) monolauryl orthophosphate, mono-octadecyl orthophosphate, the orthophosphoric acid mono- and di-esters of dibutylphenylpolyglycol (10 ethylene oxide radicles), water and sufficient caustic soda to bring the pH of the mixture to 6-7.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE289076X | 1949-03-11 | ||
DE742534X | 1951-11-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB717407A true GB717407A (en) | 1954-10-27 |
Family
ID=25777271
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB25309/50A Expired GB717407A (en) | 1949-03-11 | 1950-10-17 | Formed detergents |
GB29985/52A Expired GB742534A (en) | 1949-03-11 | 1952-11-26 | Solid shaped detergent compositions |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB29985/52A Expired GB742534A (en) | 1949-03-11 | 1952-11-26 | Solid shaped detergent compositions |
Country Status (7)
Country | Link |
---|---|
US (1) | US2765279A (en) |
BE (1) | BE499590A (en) |
CH (2) | CH289076A (en) |
DE (1) | DE973122C (en) |
FR (2) | FR1110253A (en) |
GB (2) | GB717407A (en) |
NL (2) | NL156859B (en) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1038692B (en) * | 1956-11-20 | 1958-09-11 | Huels Chemische Werke Ag | Synthetic detergents and cleaning agents containing organic phosphorus compounds |
NL257200A (en) * | 1960-03-22 | |||
FR1317586A (en) * | 1961-03-17 | 1963-05-08 | ||
BE623550A (en) * | 1961-10-13 | |||
CA777769A (en) * | 1963-03-18 | 1968-02-06 | H. Roy Clarence | Substituted methylene diphosphonic acid compounds and detergent compositions |
DE1260066B (en) * | 1963-07-24 | 1968-02-01 | Henkel & Cie Gmbh | Detergent or auxiliary laundry detergent tablets |
US3363032A (en) * | 1964-06-11 | 1968-01-09 | Monsanto Co | Long chain aliphatic benzylphosphonic acids, esters and salts |
US3368978A (en) * | 1964-12-28 | 1968-02-13 | Monsanto Co | Builder compositions and detergent compositions using same |
US3471552A (en) * | 1965-08-24 | 1969-10-07 | Plains Chem Dev Co | Aliphatic polyphosphonic acids and derivatives thereof |
US3471406A (en) * | 1965-09-07 | 1969-10-07 | Plains Chem Dev Co | Detergent compositions containing methane tri and tetra phosphonic acid compounds |
CA813301A (en) * | 1966-09-06 | 1969-05-20 | E. Zimmerer Roger | Detergent composition |
US3442938A (en) * | 1967-01-31 | 1969-05-06 | Merck & Co Inc | Prosphanilic acid derivatives |
JPS5927800B2 (en) * | 1977-02-25 | 1984-07-07 | 花王株式会社 | scoring pad |
JPS5512164A (en) * | 1978-07-13 | 1980-01-28 | Kao Corp | Antibiotic soap |
US4587034A (en) * | 1979-07-09 | 1986-05-06 | Societe Nationale Elf Aquitaine (Production) | Triphosphonic esters |
FR2460960A1 (en) * | 1979-07-09 | 1981-01-30 | Elf Aquitaine | NEW THREE-PHOSPHONIC ESTHERS USEFUL IN THE EXTRACTION OF HEAVY METALS |
FR2460958A1 (en) * | 1979-07-09 | 1981-01-30 | Elf Aquitaine | NEW DIPHOSPHONIC COMPOUNDS USEFUL IN THE EXTRACTION OF HEAVY METALS |
US4631142A (en) * | 1979-07-09 | 1986-12-23 | Societe Nationale Elf Aquitaine (Production) | Diphosphonic extractants |
DE3240688A1 (en) * | 1982-11-04 | 1984-05-30 | Henkel KGaA, 4000 Düsseldorf | USE OF ALKYLMONOPHOSPHONIC ACIDS AS A KILLING SUBSTANCE |
DE3612701A1 (en) * | 1986-04-15 | 1987-10-22 | Degussa | DETERGENT IN PIECE SHAPE |
DE3812693A1 (en) * | 1988-03-19 | 1989-09-28 | Reckitt Gmbh | CLEANING TABLET FOR DENTAL PROSTHESIS |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR471875A (en) * | 1913-07-02 | 1914-11-13 | Frank Michael Lewis | Arc light electrode |
BE378069A (en) * | 1930-04-08 | |||
DE605973C (en) * | 1930-11-30 | 1934-11-22 | I G Farbenindustrie Akt Ges | Process for the production of ethers from hydroxyl-containing organic compounds and ethylene oxide |
NL41743C (en) * | 1934-01-24 | |||
US2169829A (en) * | 1937-06-09 | 1939-08-15 | William G Beckers | Detergent composition |
US2254124A (en) * | 1939-06-05 | 1941-08-26 | Du Pont | Organic compound of quinquevalent phosphorus |
US2336230A (en) * | 1941-08-15 | 1943-12-07 | Eastman Kodak Co | Surface-active agent |
US2397422A (en) * | 1945-03-24 | 1946-03-26 | Monsanto Chemicals | Esters of paraffin phosphonic acids |
US2594454A (en) * | 1946-05-31 | 1952-04-29 | Monsanto Chemicals | Organic phosphorus acids and esters |
US2545357A (en) * | 1946-06-04 | 1951-03-13 | American Cyanamid Co | Detergent composition and method of preparing same |
-
1950
- 1950-03-17 DE DEM2368A patent/DE973122C/en not_active Expired
- 1950-10-17 GB GB25309/50A patent/GB717407A/en not_active Expired
- 1950-10-18 FR FR1110253D patent/FR1110253A/en not_active Expired
- 1950-10-26 NL NL156859A patent/NL156859B/xx unknown
- 1950-10-30 CH CH289076D patent/CH289076A/en unknown
- 1950-11-24 BE BE499590D patent/BE499590A/xx unknown
-
1952
- 1952-11-14 NL NL173813A patent/NL173813B/xx unknown
- 1952-11-25 US US322563A patent/US2765279A/en not_active Expired - Lifetime
- 1952-11-25 FR FR66569D patent/FR66569E/en not_active Expired
- 1952-11-26 GB GB29985/52A patent/GB742534A/en not_active Expired
- 1952-11-27 CH CH295584D patent/CH295584A/en unknown
Also Published As
Publication number | Publication date |
---|---|
CH295584A (en) | 1953-12-31 |
NL173813B (en) | 1954-11-15 |
NL156859B (en) | 1953-11-16 |
DE973122C (en) | 1959-12-03 |
FR66569E (en) | 1957-04-16 |
CH289076A (en) | 1953-02-28 |
US2765279A (en) | 1956-10-02 |
GB742534A (en) | 1955-12-30 |
FR1110253A (en) | 1956-02-10 |
BE499590A (en) | 1953-03-16 |
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