GB715382A - Improvements in or relating to the polymerisation of unsaturated compounds - Google Patents
Improvements in or relating to the polymerisation of unsaturated compoundsInfo
- Publication number
- GB715382A GB715382A GB2466950A GB2466950A GB715382A GB 715382 A GB715382 A GB 715382A GB 2466950 A GB2466950 A GB 2466950A GB 2466950 A GB2466950 A GB 2466950A GB 715382 A GB715382 A GB 715382A
- Authority
- GB
- United Kingdom
- Prior art keywords
- group
- vinyl
- percompound
- carbon atom
- nitrogen atom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerization Catalysts (AREA)
Abstract
Compounds containing a CH2 = C < group are polymerized, e.g. in aqueous media, bulk, or solution, in the presence of a polymerization catalyst consisting of a percompound and an organic compound containing a thiocarbonyl group the carbon atom of which is linked directly to (a) a nitrogen atom and (b) either another nitrogen atom or a carbon atom. Oxygen is preferably removed from the monomer prior to the addition of the catalyst. Specified compounds containing a CH2 = C < group are styrene, vinyl naphthalene, vinyl acetate, vinyl and vinylidene halides, acrylonitrile, methacrylonitrile, and the methyl and ethyl esters of acrylic, methacrylic and alphachloroacrylic acids. Compounds mentioned containing a thiocarbonyl group, which may be in a tautomeric form, are thiourea, N, N1-diethylthiourea, ethylene thiourea, thiouracil, mercaptobenzimidazole, and quinoline-2-thiol. The percompound may be t-butyl hydroperoxide or benzoyl peroxide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2466950A GB715382A (en) | 1950-10-10 | 1950-10-10 | Improvements in or relating to the polymerisation of unsaturated compounds |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2466950A GB715382A (en) | 1950-10-10 | 1950-10-10 | Improvements in or relating to the polymerisation of unsaturated compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
GB715382A true GB715382A (en) | 1954-09-15 |
Family
ID=10215393
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2466950A Expired GB715382A (en) | 1950-10-10 | 1950-10-10 | Improvements in or relating to the polymerisation of unsaturated compounds |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB715382A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2361096A1 (en) * | 1974-08-12 | 1978-03-10 | Colgate Palmolive Co | POLYMERISABLE COMPOSITION FOR DENTAL CARE |
US8067500B2 (en) | 2007-03-02 | 2011-11-29 | Denki Kagaku Kogyo Kabushiki Kaisha | Curable composition, bonding method and assembly |
WO2014156077A1 (en) * | 2013-03-28 | 2014-10-02 | クラレノリタケデンタル株式会社 | Curable composition |
-
1950
- 1950-10-10 GB GB2466950A patent/GB715382A/en not_active Expired
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2361096A1 (en) * | 1974-08-12 | 1978-03-10 | Colgate Palmolive Co | POLYMERISABLE COMPOSITION FOR DENTAL CARE |
US8067500B2 (en) | 2007-03-02 | 2011-11-29 | Denki Kagaku Kogyo Kabushiki Kaisha | Curable composition, bonding method and assembly |
WO2014156077A1 (en) * | 2013-03-28 | 2014-10-02 | クラレノリタケデンタル株式会社 | Curable composition |
CN105101935A (en) * | 2013-03-28 | 2015-11-25 | 可乐丽则武齿科株式会社 | Curable composition |
US20160051450A1 (en) * | 2013-03-28 | 2016-02-25 | Kuraray Noritake Dental Inc. | Curable composition |
EP2979681A4 (en) * | 2013-03-28 | 2016-09-21 | Kuraray Noritake Dental Inc | Curable composition |
JPWO2014156077A1 (en) * | 2013-03-28 | 2017-02-16 | クラレノリタケデンタル株式会社 | Curable composition |
US9889070B2 (en) | 2013-03-28 | 2018-02-13 | Kuraray Noritake Dental Inc. | Curable composition |
CN105101935B (en) * | 2013-03-28 | 2018-02-23 | 可乐丽则武齿科株式会社 | Solidification compound |
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