GB703516A - Tertiary alkyl cyclohexane carboxylic acids and salts thereof - Google Patents
Tertiary alkyl cyclohexane carboxylic acids and salts thereofInfo
- Publication number
- GB703516A GB703516A GB30226/51A GB3022651A GB703516A GB 703516 A GB703516 A GB 703516A GB 30226/51 A GB30226/51 A GB 30226/51A GB 3022651 A GB3022651 A GB 3022651A GB 703516 A GB703516 A GB 703516A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tertiary alkyl
- salt
- temperature
- carboxylic acids
- cyclohexane carboxylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C61/08—Saturated compounds having a carboxyl group bound to a six-membered ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises tertiary alkyl cyclohexane carboxylic acids and a salt thereof and their method of preparation which comprises contacting an alkaline aqueous solution of a water soluble salt of the corresponding tertiary alkyl aromatic acid with hydrogen at elevated pressure and a temperature of at least 150 DEG C. in the presence of a hydrogenation catalyst, and subsequently converting the resulting salt to the acid. As water-soluble salt there may be used an alkali or alkaline earth metal or ammonium salt. The hydrogenation may be effected at a pressure between 500 and 3,000 pounds per square inch in the presence of Raney nickel, at a temperature of 150-190 DEG C to produce the cis isomer and at a temperature of 190-300 DEG C. to produce the trans isomer.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US703516XA | 1950-12-26 | 1950-12-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB703516A true GB703516A (en) | 1954-02-03 |
Family
ID=22094776
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB30226/51A Expired GB703516A (en) | 1950-12-26 | 1951-12-27 | Tertiary alkyl cyclohexane carboxylic acids and salts thereof |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB703516A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7855340B2 (en) | 2001-09-25 | 2010-12-21 | Exxonmobil Chemical Patents Inc. | Plasticised polyvinyl chloride |
WO2011145329A1 (en) * | 2010-05-18 | 2011-11-24 | クミアイ化学工業株式会社 | Chemical damage reducing agent for herbicide, herbicidal composition reduced in chemical damage, and method for reducing chemical damage on crop |
-
1951
- 1951-12-27 GB GB30226/51A patent/GB703516A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7855340B2 (en) | 2001-09-25 | 2010-12-21 | Exxonmobil Chemical Patents Inc. | Plasticised polyvinyl chloride |
WO2011145329A1 (en) * | 2010-05-18 | 2011-11-24 | クミアイ化学工業株式会社 | Chemical damage reducing agent for herbicide, herbicidal composition reduced in chemical damage, and method for reducing chemical damage on crop |
JP5814233B2 (en) * | 2010-05-18 | 2015-11-17 | クミアイ化学工業株式会社 | Herbicide safener, herbicide composition with reduced safeguard, and crop safeguard method |
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