GB700337A - Improvements in or relating to drying oils - Google Patents
Improvements in or relating to drying oilsInfo
- Publication number
- GB700337A GB700337A GB22271/51D GB2227151D GB700337A GB 700337 A GB700337 A GB 700337A GB 22271/51 D GB22271/51 D GB 22271/51D GB 2227151 D GB2227151 D GB 2227151D GB 700337 A GB700337 A GB 700337A
- Authority
- GB
- United Kingdom
- Prior art keywords
- peroxide
- butyl
- oils
- peroxy
- amyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003921 oil Substances 0.000 title abstract 4
- 238000001035 drying Methods 0.000 title abstract 3
- 150000002978 peroxides Chemical class 0.000 abstract 5
- 235000019198 oils Nutrition 0.000 abstract 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 241001125048 Sardina Species 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- -1 isopropyl t-butyl peroxide Chemical compound 0.000 abstract 2
- QBAQOCDXTIIQOF-UHFFFAOYSA-N 1-chloro-2-hydroperoxy-2-methylpropane Chemical compound ClCC(C)(C)OO QBAQOCDXTIIQOF-UHFFFAOYSA-N 0.000 abstract 1
- KIXWZUXGOBMLHH-UHFFFAOYSA-N 1-tert-butylperoxyethanol Chemical compound CC(O)OOC(C)(C)C KIXWZUXGOBMLHH-UHFFFAOYSA-N 0.000 abstract 1
- ZMMYZOSYBMIWIR-UHFFFAOYSA-N 2,2,4-trimethyl-4-(2,4,4-trimethylpentan-2-ylperoxy)pentane Chemical compound CC(C)(C)CC(C)(C)OOC(C)(C)CC(C)(C)C ZMMYZOSYBMIWIR-UHFFFAOYSA-N 0.000 abstract 1
- BZGMEGUFFDTCNP-UHFFFAOYSA-N 2-hydroperoxy-2-methylpentane Chemical compound CCCC(C)(C)OO BZGMEGUFFDTCNP-UHFFFAOYSA-N 0.000 abstract 1
- UVTIZRNEWKAOEM-UHFFFAOYSA-N 2-tert-butylperoxy-2-methylbutane Chemical compound CCC(C)(C)OOC(C)(C)C UVTIZRNEWKAOEM-UHFFFAOYSA-N 0.000 abstract 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- 241000273930 Brevoortia tyrannus Species 0.000 abstract 1
- 244000020518 Carthamus tinctorius Species 0.000 abstract 1
- 235000003255 Carthamus tinctorius Nutrition 0.000 abstract 1
- 244000068988 Glycine max Species 0.000 abstract 1
- 235000010469 Glycine max Nutrition 0.000 abstract 1
- 240000007049 Juglans regia Species 0.000 abstract 1
- 235000009496 Juglans regia Nutrition 0.000 abstract 1
- 240000006240 Linum usitatissimum Species 0.000 abstract 1
- 235000004431 Linum usitatissimum Nutrition 0.000 abstract 1
- 235000010678 Paulownia tomentosa Nutrition 0.000 abstract 1
- 240000002834 Paulownia tomentosa Species 0.000 abstract 1
- 235000004347 Perilla Nutrition 0.000 abstract 1
- 244000124853 Perilla frutescens Species 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000001273 butane Substances 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000004359 castor oil Substances 0.000 abstract 1
- 235000019438 castor oil Nutrition 0.000 abstract 1
- UOCJDOLVGGIYIQ-PBFPGSCMSA-N cefatrizine Chemical group S([C@@H]1[C@@H](C(N1C=1C(O)=O)=O)NC(=O)[C@H](N)C=2C=CC(O)=CC=2)CC=1CSC=1C=NNN=1 UOCJDOLVGGIYIQ-PBFPGSCMSA-N 0.000 abstract 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 abstract 1
- 239000010685 fatty oil Substances 0.000 abstract 1
- 229940013317 fish oils Drugs 0.000 abstract 1
- 235000004426 flaxseed Nutrition 0.000 abstract 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 abstract 1
- 229910052740 iodine Inorganic materials 0.000 abstract 1
- 239000011630 iodine Substances 0.000 abstract 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 abstract 1
- 239000001294 propane Substances 0.000 abstract 1
- 235000019512 sardine Nutrition 0.000 abstract 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 abstract 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tertâbutyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 abstract 1
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract 1
- 239000008158 vegetable oil Substances 0.000 abstract 1
- 235000020234 walnut Nutrition 0.000 abstract 1
- 239000010698 whale oil Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F5/00—Obtaining drying-oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F7/00—Chemical modification of drying oils
- C09F7/02—Chemical modification of drying oils by oxidising
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Fats And Perfumes (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
The drying properties of fatty oils having an iodine value of at least 120 are improved by heating the oils at about 100-250 DEG C. with a peroxide containing a tertiary-alkyl peroxy radical. From 0.5 to 10 per cent. by weight of the peroxide may be used, and particularly from 2 to 6 per cent. Heating may be for 1 to 20 hours, preferably at 150-200 DEG C., and particularly about 175 DEG C. Drying oils which may be treated include fish oils, such as sardine (pilchard), menhaden and whale oil, and vegetable oils such as soya bean, hempseed, linseed, perilla, safflower, oiticica, walnut, tung and dehydrated castor oil. The tertiary alkyl peroxy group of the peroxide is preferably joined to a carbon atom of another radical. Specified peroxides are di-t-butyl peroxide, di-t-amly peroxide, di-t-octyl peroxide, mono-chloro-di-t-butyl peroxide, dichloro-di-t-butyl peroxide, monobromo-di-t-amyl peroxide, t-butyl t-amyl peroxide, isopropyl t-butyl peroxide, ethyl t-amyl peroxide, t-butyl hydro peroxide, t-hexyl hydroperoxide, monochloro-t-butyl hydroperoxide, t-butyl perbenzoate, t-amyl peracetate, di-t-butyl perphthalate, 2:2-bis-(t-butyl peroxy) propane, 2:2-bis-(t-butyl peroxy) butane and 1-(t-butyl peroxy) ethanol. The oils may first be winterised so as to stand clear for at least 2 hours at 32 DEG F., and they may also be alkali-refined. Examples are given. Specification 653,530 is referred to.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US1048508XA | 1950-09-26 | 1950-09-26 | |
US700337XA | 1950-09-26 | 1950-09-26 | |
US927460XA | 1950-09-26 | 1950-09-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB700337A true GB700337A (en) | 1953-11-25 |
Family
ID=33033114
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB22271/51D Expired GB700337A (en) | 1950-09-26 | 1951-09-24 | Improvements in or relating to drying oils |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE506019A (en) |
FR (1) | FR1048508A (en) |
GB (1) | GB700337A (en) |
-
0
- BE BE506019D patent/BE506019A/xx unknown
-
1951
- 1951-09-24 GB GB22271/51D patent/GB700337A/en not_active Expired
- 1951-09-24 FR FR1048508D patent/FR1048508A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR1048508A (en) | 1953-12-22 |
BE506019A (en) |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB926862A (en) | Improvements in or relating to bases for cosmetics | |
GB1534432A (en) | Emulsion compositions | |
GB700337A (en) | Improvements in or relating to drying oils | |
GB759339A (en) | Improvements in or relating to stabilized rubbery compositions | |
GB901639A (en) | Improvements in or relating to polymer blends | |
GB1075307A (en) | Process for the preparation of urethane oils | |
US2588902A (en) | Peroxide treatment of fatty oils | |
GB766394A (en) | Improvements in or relating to refining vegetable oils | |
GB690352A (en) | Polymerization products of aromatic vinyl compounds | |
GB597218A (en) | Improvements in or relating to resinous electrically insulating compositions and to electrical apparatus impregnated therewith | |
GB614781A (en) | New coating compositions | |
GB859467A (en) | Improvements in or relating to drying oils | |
GB1026878A (en) | Aqueous surface coating compositions | |
GB880354A (en) | Drying compositions | |
GB647352A (en) | Improvements in and relating to styrene copolymers | |
GB614532A (en) | Coreaction products from drying oils and copolymers of cyclopentadiene and styrene | |
GB841554A (en) | Improvements in or relating to the manufacture of polymeric fatty acids | |
GB612621A (en) | Improvements in the manufacture of dispersing agents | |
GB679144A (en) | Improvements in styrene-drying oil modified alkyd resins | |
GB993592A (en) | Catalytic composition for use in air-drying coating compositions | |
GB616818A (en) | Improvements in the manufacture of dispersing agents | |
GB599133A (en) | Improvements in or relating to chlorinated products of fatty acids | |
GB683126A (en) | Improvements in or relating to the preparation of styrene interpolymer compositions | |
GB561803A (en) | Making unsaturated fatty acids | |
GB754243A (en) | Improvements in or relating to a process for the emulsion copolymerisation of vinyl compounds |