GB690386A - A process for the manufacture of organic phosphorus-containing compounds - Google Patents

A process for the manufacture of organic phosphorus-containing compounds

Info

Publication number
GB690386A
GB690386A GB3302849A GB3302849A GB690386A GB 690386 A GB690386 A GB 690386A GB 3302849 A GB3302849 A GB 3302849A GB 3302849 A GB3302849 A GB 3302849A GB 690386 A GB690386 A GB 690386A
Authority
GB
United Kingdom
Prior art keywords
tertiary
mono
bis
general formula
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3302849A
Inventor
Denis William Pound
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pest Control Ltd
Original Assignee
Pest Control Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pest Control Ltd filed Critical Pest Control Ltd
Publication of GB690386A publication Critical patent/GB690386A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/22—Amides of acids of phosphorus
    • C07F9/24—Esteramides
    • C07F9/2404—Esteramides the ester moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/2433—Compounds containing the structure N-P(=X)n-X-acyl, N-P(=X)n-X-heteroatom, N-P(=X)n-X-CN (X = O, S, Se; n = 0, 1)
    • C07F9/245—Compounds containing the structure N-P(=X)n-X-acyl, N-P(=X)n-X-heteroatom, N-P(=X)n-X-CN (X = O, S, Se; n = 0, 1) containing the structure N-P(=X)n-X-P (X = O, S, Se; n = 0, 1)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/22—Amides of acids of phosphorus
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/22—Amides of acids of phosphorus
    • C07F9/224—Phosphorus triamides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/22—Amides of acids of phosphorus
    • C07F9/26—Amides of acids of phosphorus containing P-halide groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Compounds of the general formula <FORM:0690386/IV (b)/1> wherein X represents a mono- or di-alkylamino group and Y a mono- or di-alkylamino or alkyloxy group (but excluding the case where X and Y are identical dialkylamino groups), the term "alkyl" including "cycloalkyl" and all the alkyl groups preferably containing not more than 6 carbon atoms, are manufactured by reacting two molecular proportions of a compound of the general formula <FORM:0690386/IV (b)/2> in solution in a tertiary alkylamine or a tertiary alkylcycloalkylamine having 6-10 carbon atoms in the molecule and an inert solvent, with one molecular proportion (or a moderate excess) of water. The starting materials may be prepared by the process of Specification 690,385, and may be used without isolation from the reaction mixture, which may already contain the necessary solvent and sufficient of the tertiary amine (which is preferably employed in excess of 1 mol. per mol. of the compound XYPOCl). The products may be isolated as in Specification 652,981. In examples, the following compounds are warmed with water in the presence of methyldibutylamine and chloroform: (1) bis - (ethylamino) - chlorophosphine oxide; (2) bis-(isopropylamino)-chlorophosphine oxide (produced in situ from phosphorus oxychloride and isopropylamine); (3) ethyl dimethylaminochlorophosphonite (nomenclature as recommended by Michell, "British Chemical Nomenclature," 1948). According to the Provisional Specification, any tertiary amine may be employed.
GB3302849A 1947-10-17 1949-12-23 A process for the manufacture of organic phosphorus-containing compounds Expired GB690386A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2786947A GB631549A (en) 1947-10-17 1947-10-17 Improvements in or relating to the manufacture of compounds containing phosphorus having insecticidal properties

Publications (1)

Publication Number Publication Date
GB690386A true GB690386A (en) 1953-04-22

Family

ID=10261765

Family Applications (4)

Application Number Title Priority Date Filing Date
GB2786947A Expired GB631549A (en) 1947-10-17 1947-10-17 Improvements in or relating to the manufacture of compounds containing phosphorus having insecticidal properties
GB3156048A Expired GB652981A (en) 1947-10-17 1948-12-06 Improvements in or relating to the manufacture of compounds containing phosphorus having insecticidal properties
GB3302849A Expired GB690386A (en) 1947-10-17 1949-12-23 A process for the manufacture of organic phosphorus-containing compounds
GB3302749A Expired GB690385A (en) 1947-10-17 1949-12-23 Improvements in or relating to phosphorus-containing organic compounds

Family Applications Before (2)

Application Number Title Priority Date Filing Date
GB2786947A Expired GB631549A (en) 1947-10-17 1947-10-17 Improvements in or relating to the manufacture of compounds containing phosphorus having insecticidal properties
GB3156048A Expired GB652981A (en) 1947-10-17 1948-12-06 Improvements in or relating to the manufacture of compounds containing phosphorus having insecticidal properties

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB3302749A Expired GB690385A (en) 1947-10-17 1949-12-23 Improvements in or relating to phosphorus-containing organic compounds

Country Status (6)

Country Link
BE (3) BE485264A (en)
CH (3) CH275704A (en)
DE (4) DE814294C (en)
FR (4) FR973517A (en)
GB (4) GB631549A (en)
NL (2) NL70079C (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2671109A (en) * 1949-11-16 1954-03-02 Pest Control Ltd Preparation of bis-dialkylamino phosphonous anhydrides
US2706738A (en) * 1950-03-23 1955-04-19 Victor Chemical Works Method of preparing pyrophosphortetraamides of secondary aliphatic and secondary heterocyclic amines in the presence of an inorganic base
BE516874A (en) * 1950-06-26
FR1094647A (en) * 1952-04-11 1955-05-23
US2745862A (en) * 1952-06-20 1956-05-15 Allied Chem & Dye Corp Production of dialkyl hydrogen phosphites
DE1026749B (en) * 1953-04-20 1958-03-27 Dow Chemical Co Process for the preparation of pyrophosphoric acid alkylamides
DE1112852B (en) * 1958-03-18 1961-08-17 Bayer Ag Pest repellants
DE1153373B (en) * 1960-09-17 1963-08-29 Shell Int Research Process for the production of pyrophosphoric acid esters, phosphoric acid esters, phosphoric amides or carboxylic acid anhydrides

Also Published As

Publication number Publication date
FR59698E (en) 1954-06-29
DE855567C (en) 1952-11-13
NL142805B (en)
BE500243A (en) 1951-01-15
GB690385A (en) 1953-04-22
DE889898C (en) 1953-09-14
DE836192C (en) 1952-04-10
BE485264A (en) 1948-10-30
CH287762A (en) 1952-12-15
GB631549A (en) 1949-11-04
FR62320E (en) 1955-06-13
FR973517A (en) 1951-02-12
GB652981A (en) 1951-05-02
BE500172A (en) 1951-01-15
CH292710A (en) 1953-08-31
CH275704A (en) 1951-06-15
DE814294C (en) 1951-09-20
NL70079C (en) 1950-01-16
FR62319E (en) 1955-06-13

Similar Documents

Publication Publication Date Title
GB1145758A (en) Process for the preparation of cyclic esters of phosphorous acid and novel such esters
GB1362011A (en) Phosphorous esters stable to hydrolysis and processes for producing the same
KR840006994A (en) Tris (piperidylaminotriazilamino) compound and preparation method of acid addition salt thereof
GB690386A (en) A process for the manufacture of organic phosphorus-containing compounds
US2865948A (en) New phosphorylated heterocyclic compounds and processes for preparing same
US2488449A (en) Organo-silicon-phosphorus condensation products
Dubeck et al. The Addition of Dicyclopentadienylrhenium Hydride to Some Acetylenes
GB1036578A (en) Tertiary amine salts of phosphoric acid esters
GB857882A (en) Compounds containing boron and silicon
GB870425A (en) Improvements in and relating to organic phosphorus compounds
GB983663A (en) Tertiary phosphine oxides
GB977071A (en) Hydroxylamine derivatives and process for making them
GB698093A (en) Improvements in or relating to phosphorus-containing organic compounds
GB1353196A (en) C1-c4 alkyl 2,3-dibromopropyl acid phosphates
GB1047061A (en) Polymers and a process for the preparation thereof
GB1050554A (en)
GB1256180A (en) Organophosphorus compounds
GB978550A (en) Acylacetylaminobenzene compounds containing sulphonic acid groups and process for their manufacture
GB1305547A (en)
GB645458A (en) Insecticidal compositions
GB1170212A (en) Tris-(Organosilylmethyl)-Amines and Process for their Production
GB806772A (en) Diaminoquinazolines and method of preparing
KR950011360B1 (en) Method of preparating triarylphosphate
GB1036277A (en) Insecticidal compositions
GB915751A (en) Substituted alanines