GB686570A - Production of finely divided titanium dioxide - Google Patents
Production of finely divided titanium dioxideInfo
- Publication number
- GB686570A GB686570A GB24337/50A GB2433750A GB686570A GB 686570 A GB686570 A GB 686570A GB 24337/50 A GB24337/50 A GB 24337/50A GB 2433750 A GB2433750 A GB 2433750A GB 686570 A GB686570 A GB 686570A
- Authority
- GB
- United Kingdom
- Prior art keywords
- chloride
- aluminium
- mixture
- titanium
- vapours
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title abstract 5
- 239000004408 titanium dioxide Substances 0.000 title abstract 2
- 239000007789 gas Substances 0.000 abstract 6
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 5
- 239000000203 mixture Substances 0.000 abstract 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 3
- 235000010210 aluminium Nutrition 0.000 abstract 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- 229910052801 chlorine Inorganic materials 0.000 abstract 3
- 239000000460 chlorine Substances 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 2
- 239000004411 aluminium Substances 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- 150000001399 aluminium compounds Chemical class 0.000 abstract 2
- -1 aluminium halides Chemical class 0.000 abstract 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 2
- 229960004424 carbon dioxide Drugs 0.000 abstract 2
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 abstract 1
- 235000011941 Tilia x europaea Nutrition 0.000 abstract 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229940077746 antacid containing aluminium compound Drugs 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 229910002090 carbon oxide Inorganic materials 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 238000007599 discharging Methods 0.000 abstract 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 239000004571 lime Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 230000002459 sustained effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
- C01G23/07—Producing by vapour phase processes, e.g. halide oxidation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Pigmentary titanium dioxide of which at least 90 per cent consists of rutile, is produced by discharging a uniform premixture of titanium tetrachloride vapours, gases containing free oxygen, and a volatile aluminium compound in amount sufficient to yield a product containing 0.01-10 per cent alumina, into a combustion zone, suitably at a linear flow rate of 1-50 metres per second, the mixture being at a temperature of 135-500 DEG C., and continuously contacting the premixture with an auxiliary flame sustained by a separate inflow of combustible gas to ignite the mixture and maintain it in a flaming state. Suitable aluminium compounds are aluminium halides, e.g. chloride, trimethyl aluminiums &c. The aluminium chloride may be mixed with the titanium chloride to be vaporized, by passing the oxygen-containing gas therethrough or it may be separately sublimed, e.g. by passing chlorine, with or without a diluent gas, over aluminium shavings or a mixture of alumina and carbon, or carbon monoxide and chlorine, or phosgene, over alumina, the vapours being added to the titanium chloride vapours. The premixture should contain at least 50 per cent, up to a surplus, of oxygen for the decomposition of the titanium tetrachloride. Inert gas such as carbon dioxide or nitrogen may also be present. Methane, acetylene, hydrogen &c. or, preferably, carbon monoxide are employed as combustible gases. Temperatures of 1000-1600 DEG C immediately ambient to the auxiliary flame are specified. Examples disclose burners consisting of concentric tubes, the titanium chloride mixture supply tube being surrounded by, and in some cases also surrounding, the supply tubes for the auxiliary flame-producing gases. The product may evacuated to remove chlorine and hydrogen chloride, and neutralized with a small amount of lime. Specification 673,782 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH686570X | 1949-10-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB686570A true GB686570A (en) | 1953-01-28 |
Family
ID=4528907
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB24337/50A Expired GB686570A (en) | 1949-10-08 | 1950-10-05 | Production of finely divided titanium dioxide |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB686570A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2957753A (en) * | 1958-11-05 | 1960-10-25 | American Cyanamid Co | Titanium dioxide from titanium tetrachloride |
| US3174873A (en) * | 1960-04-25 | 1965-03-23 | British Titan Products | Entrainment of vapours in gases |
| FR2160371A1 (en) * | 1971-11-17 | 1973-06-29 | Sir Soc Italiana Resine Spa | |
| US5824146A (en) * | 1997-07-03 | 1998-10-20 | E. I. Du Pont De Nemours And Company | Method for making a photodurable aqueous titanium dioxide pigment slurry using a high level of aluminum co-oxidant |
-
1950
- 1950-10-05 GB GB24337/50A patent/GB686570A/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2957753A (en) * | 1958-11-05 | 1960-10-25 | American Cyanamid Co | Titanium dioxide from titanium tetrachloride |
| US3174873A (en) * | 1960-04-25 | 1965-03-23 | British Titan Products | Entrainment of vapours in gases |
| FR2160371A1 (en) * | 1971-11-17 | 1973-06-29 | Sir Soc Italiana Resine Spa | |
| US5824146A (en) * | 1997-07-03 | 1998-10-20 | E. I. Du Pont De Nemours And Company | Method for making a photodurable aqueous titanium dioxide pigment slurry using a high level of aluminum co-oxidant |
| WO1999001518A1 (en) * | 1997-07-03 | 1999-01-14 | E.I. Du Pont De Nemours And Company | Method for making a photodurable aqueous titanium dioxide pigment slurry |
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