GB674728A - Improvements in or relating to the production of interpolymers and of moistureproof sheet wrapping material coated therewith - Google Patents

Improvements in or relating to the production of interpolymers and of moistureproof sheet wrapping material coated therewith

Info

Publication number
GB674728A
GB674728A GB8537/49A GB853749A GB674728A GB 674728 A GB674728 A GB 674728A GB 8537/49 A GB8537/49 A GB 8537/49A GB 853749 A GB853749 A GB 853749A GB 674728 A GB674728 A GB 674728A
Authority
GB
United Kingdom
Prior art keywords
sulphate
mixture
acid
per cent
sodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB8537/49A
Inventor
William Berry
John Kay
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
British Cellophane Ltd
Original Assignee
British Cellophane Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Cellophane Ltd filed Critical British Cellophane Ltd
Priority to GB8537/49A priority Critical patent/GB674728A/en
Publication of GB674728A publication Critical patent/GB674728A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/02—Monomers containing chlorine
    • C08F214/04—Monomers containing two carbon atoms
    • C08F214/08—Vinylidene chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/08—Homopolymers or copolymers of vinylidene chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2301/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
    • C08J2301/06—Cellulose hydrate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Aqueous dispersions of terpolymers are made by emulsifying a mixture of 80 per cent of vinylidene chloride, between 0.1 and 2.5 per cent of an acidic ethylenic compound and acrylonitrile in an aqueous medium containing a modifying compound of the formula <FORM:0674728/IV (a)/1> wherein R and R1 are hydrogen or a hydrocarbon radical, e.g. methyl isobutyl ketone, and, as dispersing agent, 3 to 6 per cent, based on the mixture of monomers, of a water-dispersible alkyl sulphate, containing 8 to 18 carbon atoms in the alkyl group, e.g. sodium lauryl sulphate, sodium cetyl sulphate, sodium octadecyl sulphate and "Teepol" (Registered Trade Mark) and subjecting to polymerizing temperatures, e.g. 40 DEG C. The acidic ethylenic compound may be citraconic or itaconic acid or anhydrides thereof, mesaconic acid, acrylic acid or a mixture of acid anhydrides comprising citraconic and itaconic anhydrides formed by distilling citric acid. Catalysts, e.g. ammonium persulphate and activators, e.g. sodium metabisulphite, may be present. The product may be isolated by coagulation, e.g. by addition of alkali metal or ammonium sulphate, evaporation or electrophoresis. Films of regenerated cellulose, polyvinyl alcohol, cellulose esters or ethers, gelatin and casein may be coated with the terpolymer in aqueous dispersion or in solution in methyl ethyl ketone or a mixture thereof with toluene or tetrahydrofurane. Specifications 633,645, 649,719 and 654,342, [Group VIII], are referred to.
GB8537/49A 1949-03-29 1949-03-29 Improvements in or relating to the production of interpolymers and of moistureproof sheet wrapping material coated therewith Expired GB674728A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB8537/49A GB674728A (en) 1949-03-29 1949-03-29 Improvements in or relating to the production of interpolymers and of moistureproof sheet wrapping material coated therewith

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB8537/49A GB674728A (en) 1949-03-29 1949-03-29 Improvements in or relating to the production of interpolymers and of moistureproof sheet wrapping material coated therewith

Publications (1)

Publication Number Publication Date
GB674728A true GB674728A (en) 1952-07-02

Family

ID=9854347

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8537/49A Expired GB674728A (en) 1949-03-29 1949-03-29 Improvements in or relating to the production of interpolymers and of moistureproof sheet wrapping material coated therewith

Country Status (1)

Country Link
GB (1) GB674728A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2873211A (en) * 1955-10-26 1959-02-10 American Marietta Company Ston Carboxylic-nitrile-acrylate ester coating composition, process and coated product
US3236818A (en) * 1961-06-12 1966-02-22 Du Pont Terpolymers of vinylidene chloride, a mono-olefinic material and a terpene
US3248374A (en) * 1961-06-14 1966-04-26 Du Pont Terpolymers containing vinylidene chloride, a cyclomonoolefine and another olefinic material
DE1221116B (en) * 1954-11-22 1966-07-14 Du Pont Packaging film made of cellulose hydrate with an organic base layer and a top layer made of vinylidene chloride copolymers

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1221116B (en) * 1954-11-22 1966-07-14 Du Pont Packaging film made of cellulose hydrate with an organic base layer and a top layer made of vinylidene chloride copolymers
US2873211A (en) * 1955-10-26 1959-02-10 American Marietta Company Ston Carboxylic-nitrile-acrylate ester coating composition, process and coated product
US3236818A (en) * 1961-06-12 1966-02-22 Du Pont Terpolymers of vinylidene chloride, a mono-olefinic material and a terpene
US3248374A (en) * 1961-06-14 1966-04-26 Du Pont Terpolymers containing vinylidene chloride, a cyclomonoolefine and another olefinic material

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