GB663810A - A process for the manufacture of phenyldichlorosilane - Google Patents
A process for the manufacture of phenyldichlorosilaneInfo
- Publication number
- GB663810A GB663810A GB30751/49A GB3075149A GB663810A GB 663810 A GB663810 A GB 663810A GB 30751/49 A GB30751/49 A GB 30751/49A GB 3075149 A GB3075149 A GB 3075149A GB 663810 A GB663810 A GB 663810A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phenyldichlorosilane
- weight
- per cent
- less
- reaction mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XNAFLNBULDHNJS-UHFFFAOYSA-N dichloro(phenyl)silicon Chemical compound Cl[Si](Cl)C1=CC=CC=C1 XNAFLNBULDHNJS-UHFFFAOYSA-N 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- 239000005046 Chlorosilane Substances 0.000 abstract 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- YCITZMJNBYYMJO-UHFFFAOYSA-N chloro(diphenyl)silicon Chemical compound C=1C=CC=CC=1[Si](Cl)C1=CC=CC=C1 YCITZMJNBYYMJO-UHFFFAOYSA-N 0.000 abstract 1
- NBWIIOQJUKRLKW-UHFFFAOYSA-N chloro(phenyl)silane Chemical compound Cl[SiH2]C1=CC=CC=C1 NBWIIOQJUKRLKW-UHFFFAOYSA-N 0.000 abstract 1
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical class Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 abstract 1
- OSXYHAQZDCICNX-UHFFFAOYSA-N dichloro(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](Cl)(Cl)C1=CC=CC=C1 OSXYHAQZDCICNX-UHFFFAOYSA-N 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 229910000077 silane Inorganic materials 0.000 abstract 1
- AKQNYQDSIDKVJZ-UHFFFAOYSA-N triphenylsilane Chemical compound C1=CC=CC=C1[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 AKQNYQDSIDKVJZ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
- C07F7/121—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
- C07F7/123—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20 by reactions involving the formation of Si-halogen linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
Abstract
Phenyldichlorosilane is prepared by heating from 150 DEG to 250 DEG C. diphenylchlorosilane in the presence of less than 50 per cent by weight of aluminium chloride based on the total weight of chlorosilanes employed and at a pressure sufficiently low that the phenyldichlorosilane distills from the reaction mixture. The preferred proportion of aluminium catalyst is from 0.001 to 10 per cent by weight based upon the weight of silane. Diphenyldichlorosilane may also be present in the reaction mixture, e.g. in an equimolecular proportion with the phenyldichlorosilane. The reaction temperature may be from 150 DEG to 210 DEG C. and the reaction pressure may be less than 60 mms. mercury. A number of examples are given. Some triphenylsilane and phenylmonochlorosilane are also formed.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US663810XA | 1949-02-23 | 1949-02-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB663810A true GB663810A (en) | 1951-12-27 |
Family
ID=22069140
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB30751/49A Expired GB663810A (en) | 1949-02-23 | 1949-11-30 | A process for the manufacture of phenyldichlorosilane |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB663810A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2732282A (en) * | 1956-01-24 | Cjhssihclj | ||
| US2732280A (en) * | 1956-01-24 | Disproportionation of chlorosilanes | ||
| US2732281A (en) * | 1956-01-24 | Disproportionation of chlorosilanes | ||
| US2746981A (en) * | 1952-09-26 | 1956-05-22 | Union Carbide & Carbon Corp | Disproportionation of aryldichlorosilanes |
| US2834648A (en) * | 1953-03-25 | 1958-05-13 | Union Carbide Corp | Disproportionation of chlorosilanes employing amine-type catalysts |
| CN112920214A (en) * | 2019-12-05 | 2021-06-08 | 新特能源股份有限公司 | Phenyl chlorosilane, preparation method and device |
-
1949
- 1949-11-30 GB GB30751/49A patent/GB663810A/en not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2732282A (en) * | 1956-01-24 | Cjhssihclj | ||
| US2732280A (en) * | 1956-01-24 | Disproportionation of chlorosilanes | ||
| US2732281A (en) * | 1956-01-24 | Disproportionation of chlorosilanes | ||
| US2746981A (en) * | 1952-09-26 | 1956-05-22 | Union Carbide & Carbon Corp | Disproportionation of aryldichlorosilanes |
| US2834648A (en) * | 1953-03-25 | 1958-05-13 | Union Carbide Corp | Disproportionation of chlorosilanes employing amine-type catalysts |
| CN112920214A (en) * | 2019-12-05 | 2021-06-08 | 新特能源股份有限公司 | Phenyl chlorosilane, preparation method and device |
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