GB663691A - A process for the manufacture of methylchlorosilanes - Google Patents
A process for the manufacture of methylchlorosilanesInfo
- Publication number
- GB663691A GB663691A GB30753/49A GB3075349A GB663691A GB 663691 A GB663691 A GB 663691A GB 30753/49 A GB30753/49 A GB 30753/49A GB 3075349 A GB3075349 A GB 3075349A GB 663691 A GB663691 A GB 663691A
- Authority
- GB
- United Kingdom
- Prior art keywords
- weight
- methylchlorosilanes
- phenyldimethylchlorosilane
- chlorosilanes
- per cent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- YGZSVWMBUCGDCV-UHFFFAOYSA-N chloro(methyl)silane Chemical class C[SiH2]Cl YGZSVWMBUCGDCV-UHFFFAOYSA-N 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 4
- 239000005046 Chlorosilane Substances 0.000 abstract 2
- KWYZNESIGBQHJK-UHFFFAOYSA-N chloro-dimethyl-phenylsilane Chemical compound C[Si](C)(Cl)C1=CC=CC=C1 KWYZNESIGBQHJK-UHFFFAOYSA-N 0.000 abstract 2
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical class Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 abstract 2
- NBWIIOQJUKRLKW-UHFFFAOYSA-N chloro(phenyl)silane Chemical class Cl[SiH2]C1=CC=CC=C1 NBWIIOQJUKRLKW-UHFFFAOYSA-N 0.000 abstract 1
- MNKYQPOFRKPUAE-UHFFFAOYSA-N chloro(triphenyl)silane Chemical class C=1C=CC=CC=1[Si](C=1C=CC=CC=1)(Cl)C1=CC=CC=C1 MNKYQPOFRKPUAE-UHFFFAOYSA-N 0.000 abstract 1
- OSXYHAQZDCICNX-UHFFFAOYSA-N dichloro(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](Cl)(Cl)C1=CC=CC=C1 OSXYHAQZDCICNX-UHFFFAOYSA-N 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000005054 phenyltrichlorosilane Substances 0.000 abstract 1
- ORVMIVQULIKXCP-UHFFFAOYSA-N trichloro(phenyl)silane Chemical compound Cl[Si](Cl)(Cl)C1=CC=CC=C1 ORVMIVQULIKXCP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
- C07F7/121—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
- C07F7/125—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20 by reactions involving both Si-C and Si-halogen linkages, the Si-C and Si-halogen linkages can be to the same or to different Si atoms, e.g. redistribution reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
Abstract
Methylchlorosilanes of the general formula (CH3)xSiCl4-x, where x is 2 or 3, are prepared by heating a mixture of phenyldimethylchlorosilane and diphenyldichlorosilane and/or phenyltrichlorosilane in the presence of less than 50 per cent by weight of aluminium chloride based on the weight of chlorosilanes at a temperature of from 180 DEG to 250 DEG C. The preferred proportion of aluminium chloride is from 0.001 to 10 per cent by weight based on the weight of the total chlorosilanes. The phenyldimethylchlorosilane and the phenylchlorosilanes may be reacted in equimolecular proportions. Diphenyldichloro- and triphenylchlorosilanes are also obtained. A number of examples are given.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US663691XA | 1949-02-23 | 1949-02-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB663691A true GB663691A (en) | 1951-12-27 |
Family
ID=22069062
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB30753/49A Expired GB663691A (en) | 1949-02-23 | 1949-11-30 | A process for the manufacture of methylchlorosilanes |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE842057C (en) |
| FR (1) | FR999729A (en) |
| GB (1) | GB663691A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2717257A (en) * | 1952-09-09 | 1955-09-06 | Gen Electric | Redistribution of organosilanes |
| WO2005092903A1 (en) * | 2004-03-23 | 2005-10-06 | Wacker Chemie Ag | Method for separating aluminium chloride from organochlorosilanes |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE953080C (en) * | 1952-09-09 | 1956-11-29 | Gen Electric | Process for the disproportionation of organohalosilanes |
-
1949
- 1949-11-19 FR FR999729D patent/FR999729A/en not_active Expired
- 1949-11-30 GB GB30753/49A patent/GB663691A/en not_active Expired
-
1950
- 1950-09-23 DE DED6049A patent/DE842057C/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2717257A (en) * | 1952-09-09 | 1955-09-06 | Gen Electric | Redistribution of organosilanes |
| WO2005092903A1 (en) * | 2004-03-23 | 2005-10-06 | Wacker Chemie Ag | Method for separating aluminium chloride from organochlorosilanes |
Also Published As
| Publication number | Publication date |
|---|---|
| DE842057C (en) | 1952-06-23 |
| FR999729A (en) | 1952-02-04 |
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