GB660408A - Improvements in or relating to cyanine dyes - Google Patents
Improvements in or relating to cyanine dyesInfo
- Publication number
- GB660408A GB660408A GB1063149A GB1063149A GB660408A GB 660408 A GB660408 A GB 660408A GB 1063149 A GB1063149 A GB 1063149A GB 1063149 A GB1063149 A GB 1063149A GB 660408 A GB660408 A GB 660408A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- prepared
- aralkyl
- cyanine dyes
- methiodide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000975 dye Substances 0.000 title abstract 2
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 title abstract 2
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 abstract 6
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 abstract 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 2
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 abstract 2
- 150000003839 salts Chemical group 0.000 abstract 2
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 abstract 2
- CVULGJIRGZVJHQ-UHFFFAOYSA-N 2-ethylbenzothiazole Chemical compound C1=CC=C2SC(CC)=NC2=C1 CVULGJIRGZVJHQ-UHFFFAOYSA-N 0.000 abstract 1
- UTBVIMLZIRIFFR-UHFFFAOYSA-N 2-methylthio-1,3-benzothiazole Chemical compound C1=CC=C2SC(SC)=NC2=C1 UTBVIMLZIRIFFR-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 125000002496 methyl group Chemical class [H]C([H])([H])* 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/02—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups
- C09B23/04—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups one >CH- group, e.g. cyanines, isocyanines, pseudocyanines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Thiazole And Isothizaole Compounds (AREA)
- Cosmetics (AREA)
Abstract
Meso-substituted cyanine dyes are prepared by reacting an alkyl or aralkyl quaternary salt of a benzthiazole containing a thioether grouping in the 2-position with an alkyl or aralkyl quaternary salt of a benzthiazole containing an alkyl-or aralkyl-substituted methyl group in the 2-position, in the presence of a strong base, which is substantially stronger than pyridine and should be at least as strong as triethylamine. Sodium ethoxide may be used. 3 : 31 : 8-Trimethylcyanine iodide is prepared by boiling together in alcohol 2-ethylbenzthiazole methiodide, 2-methylthiobenzthiazole methiodide, and sodium ethoxide or triethylamine. 3 : 31 - Diethyl - 8 - methylthiacyanine iodide is similarly prepared. Specification 424,559 is referred to.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1063149A GB660408A (en) | 1949-04-21 | 1949-04-21 | Improvements in or relating to cyanine dyes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1063149A GB660408A (en) | 1949-04-21 | 1949-04-21 | Improvements in or relating to cyanine dyes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB660408A true GB660408A (en) | 1951-11-07 |
Family
ID=9971435
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1063149A Expired GB660408A (en) | 1949-04-21 | 1949-04-21 | Improvements in or relating to cyanine dyes |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB660408A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4232118A (en) * | 1978-03-10 | 1980-11-04 | Konishiroku Photo Industry Co., Ltd. | Light-sensitive silver halide photographic material |
| US5082765A (en) * | 1986-04-04 | 1992-01-21 | Konica Corporation | Method of processing light-sensitive silver halide photographic material |
| US6593172B2 (en) * | 2001-05-10 | 2003-07-15 | International Rectifier Corporation | Design and processing of antifuse structure |
-
1949
- 1949-04-21 GB GB1063149A patent/GB660408A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4232118A (en) * | 1978-03-10 | 1980-11-04 | Konishiroku Photo Industry Co., Ltd. | Light-sensitive silver halide photographic material |
| US5082765A (en) * | 1986-04-04 | 1992-01-21 | Konica Corporation | Method of processing light-sensitive silver halide photographic material |
| US6593172B2 (en) * | 2001-05-10 | 2003-07-15 | International Rectifier Corporation | Design and processing of antifuse structure |
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