GB651307A - Method of diminishing the formation of foam and preparations therefor - Google Patents
Method of diminishing the formation of foam and preparations thereforInfo
- Publication number
- GB651307A GB651307A GB14473/48A GB1447348A GB651307A GB 651307 A GB651307 A GB 651307A GB 14473/48 A GB14473/48 A GB 14473/48A GB 1447348 A GB1447348 A GB 1447348A GB 651307 A GB651307 A GB 651307A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tri
- butyl
- ethyl
- isoamyl
- chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000015572 biosynthetic process Effects 0.000 title abstract 4
- 239000006260 foam Substances 0.000 title abstract 4
- 238000005755 formation reaction Methods 0.000 title abstract 4
- 230000003467 diminishing Effects 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 4
- 125000004432 carbon atoms Chemical group C* 0.000 abstract 3
- -1 n-butyl- Chemical group 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-Chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 abstract 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N Diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- 150000001298 alcohols Chemical class 0.000 abstract 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- CZHLPWNZCJEPJB-UHFFFAOYSA-N 1-chloro-3-methylbutane Chemical group CC(C)CCCl CZHLPWNZCJEPJB-UHFFFAOYSA-N 0.000 abstract 1
- UNNGUFMVYQJGTD-UHFFFAOYSA-N 2-ethylbutanal Chemical compound CCC(CC)C=O UNNGUFMVYQJGTD-UHFFFAOYSA-N 0.000 abstract 1
- LGYNIFWIKSEESD-UHFFFAOYSA-N 2-ethylhexanal Chemical compound CCCCC(CC)C=O LGYNIFWIKSEESD-UHFFFAOYSA-N 0.000 abstract 1
- MEEKGULDSDXFCN-UHFFFAOYSA-N 2-pentylphenol Chemical class CCCCCC1=CC=CC=C1O MEEKGULDSDXFCN-UHFFFAOYSA-N 0.000 abstract 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N Oleyl alcohol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- YODZTKMDCQEPHD-UHFFFAOYSA-N Thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 abstract 1
- 229950006389 Thiodiglycol Drugs 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- RTCGUJFWSLMVSH-UHFFFAOYSA-N chloroform;silicon Chemical compound [Si].ClC(Cl)Cl RTCGUJFWSLMVSH-UHFFFAOYSA-N 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229940055577 oleyl alcohol Drugs 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 150000003014 phosphoric acid esters Chemical class 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- HRKAMJBPFPHCSD-UHFFFAOYSA-N tris(2-methylpropyl) phosphate Chemical compound CC(C)COP(=O)(OCC(C)C)OCC(C)C HRKAMJBPFPHCSD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003021 water soluble solvent Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
- B01D19/0409—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing Si-atoms
Abstract
Tri-n-butyl silicone is prepared by reacting n-butyl chloride with silicon chloroform in ether in the presence of sodium. Sodium chloride is removed by filtration, ether is removed, and the residue distilled. Similarly by substituting isoamyl chloride for n-butyl chloride tri-isoamyl silicane is obtained.ALSO:Tri and tetra-alkyl silicanes wherein the alkyl groups contain at least 2 carbon atoms are mixed with a solvent or another substance capable of lessening foam formation and added to liquids to diminish foam formation therein. In general, 0.01 to 0.5 per cent of the silicane suffices but the composition of the mixture itself can vary considerably. Specified silicanes are: tri-ethyl-; tri-(n-propyl)-; tri-isopropyl-; tri-(n-butyl)-; tri-isobutyl-; tri-isoamyl-; tri-(n-hexyl)-; tri-(2-ethyl butyl-1)-; tri-(n-octyl)-; tri-(2-ethyl-hexyl-1)-; tri-dodecyl-; tetra-ethyl-; and the tetra-isopropyl-; n-butyl-; isoamyl- and those containing a larger number of carbon atoms. Solvents soluble in water specified are isopropyl alcohol and polyhydric alcohols or their ethers, e.g. ethylene glycol; glycerine, diethylene glycol, ethylene glycol monoether and thiodiglycol; also ketones, e.g. acetone, whilst solvents sparingly soluble in water are aliphatic alcohols containing at least 5 carbon atoms especially branched chain ones, e.g. 2-ethyl-butanal, 2-ethyl-hexanal and also higher molecular weight alcohols, e.g. oleyl alcohol. Also phenols, e.g amyl phenols. Such sparingly water soluble solvents aid in diminishing foam formation as also do phosphoric acid esters, e.g. tri-(n-butyl) or tri-isobutyl-phosphate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH651307X | 1947-06-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB651307A true GB651307A (en) | 1951-03-14 |
Family
ID=4526133
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB14473/48A Expired GB651307A (en) | 1947-06-10 | 1948-05-28 | Method of diminishing the formation of foam and preparations therefor |
Country Status (4)
| Country | Link |
|---|---|
| CH (1) | CH257713A (en) |
| DE (1) | DE871287C (en) |
| FR (2) | FR966051A (en) |
| GB (1) | GB651307A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2777807A (en) * | 1952-11-22 | 1957-01-15 | Du Pont | Process of suppressing foam formation in distillation of acrylonitrile |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012117004A2 (en) * | 2011-03-01 | 2012-09-07 | Basf Se | Medium chain alkanols in additive concentrates for improving the reduction of foam in fuel oils |
-
0
- FR FR466051D patent/FR466051A/fr active Active
-
1947
- 1947-06-10 CH CH257713D patent/CH257713A/en unknown
-
1948
- 1948-05-05 FR FR966051D patent/FR966051A/en not_active Expired
- 1948-05-28 GB GB14473/48A patent/GB651307A/en not_active Expired
-
1949
- 1949-01-01 DE DEP30342D patent/DE871287C/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2777807A (en) * | 1952-11-22 | 1957-01-15 | Du Pont | Process of suppressing foam formation in distillation of acrylonitrile |
Also Published As
| Publication number | Publication date |
|---|---|
| DE871287C (en) | 1953-03-23 |
| CH257713A (en) | 1948-10-31 |
| FR466051A (en) | |
| FR966051A (en) | 1950-09-29 |
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