GB648955A - Improvements in electron-emitting electrodes for electric discharge tubes - Google Patents
Improvements in electron-emitting electrodes for electric discharge tubesInfo
- Publication number
- GB648955A GB648955A GB12657/46A GB1265746A GB648955A GB 648955 A GB648955 A GB 648955A GB 12657/46 A GB12657/46 A GB 12657/46A GB 1265746 A GB1265746 A GB 1265746A GB 648955 A GB648955 A GB 648955A
- Authority
- GB
- United Kingdom
- Prior art keywords
- per cent
- tungsten
- thorium
- mixture
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/04—Electrodes; Screens; Shields
- H01J61/06—Main electrodes
- H01J61/067—Main electrodes for low-pressure discharge lamps
- H01J61/0675—Main electrodes for low-pressure discharge lamps characterised by the material of the electrode
- H01J61/0677—Main electrodes for low-pressure discharge lamps characterised by the material of the electrode characterised by the electron emissive material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J1/00—Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
- H01J1/02—Main electrodes
- H01J1/13—Solid thermionic cathodes
- H01J1/14—Solid thermionic cathodes characterised by the material
Abstract
648,955. Cathode materials and processing. PHILIPS LAMPS, Ltd. April 26, 1946, No. 12657. Convention date, March 21, 1942. [Class 39 (i)] A thermionic cathode consists of or is coated with an electron emissive material comprising at least one ingredient from each of groups A, B and C, group A containing tungsten and molybdenum, group B containing thorium, tantalum, hafnium and zirconium, and group C containing barium, calcium and strontium oxide, and the percentage by weight of the element or elements from group B is above 10 per cent and preferably above 20 per cent. In a modification, a quantity of thorium oxide may be included as part of the percentage allocated to group C. The material may be used to coat a conductive core either of a directly or indirectly heated cathode or may be pressed and sintered to form a cathode body. In the latter case the body is placed on or in a holder in, say, a high pressure mercury vapour discharge tube. The invention is also applicable to other gas- or vapour-filled discharge tubes, e.g. gas discharge lamps, and also to high vacuum discharge tubes. A number of examples are given : (i) a pressed and sintered body of 65 per cent tungsten, 25 per cent thorium, 10 per cent of a mixture of the alkaline earth oxides in group C; (ii) a pressed and sintered body of 10 per cent thoria, 10 per cent barium and calcium oxides, 10 per cent tantalum, 15 per cent hafnium, 5 per cent zirconium, 50 per cent tungsten and/or molybdenum ; (iii) 90 gms. of a mixture of 75 parts tungsten to 25 parts of thorium are mixed with 10 gms. of a mixture of barium, strontium and calcium carbonate. The mixture so formed is made into a paste with a 10 per cent solution of nitro-cellulose in ethyl glycol as binder, and the paste is pressed through a die to give small cylinders 3-4 mm. long and 2 mm. in diameter. The cylinders are mounted on a current supply wire of diameter 500Á, and heated and sintered to convert the carbonates into oxides; (iv) 80 gms. tungsten, 20 gms. of thorium, and 18 gms. of a mixture of barium, strontium and calcium carbonate is mixed with 45 c.cs. of butyl acetate having 1.8 per cent nitro-cellulose dissolved therein, and the mixture is ground in a ball mill for 24 hours. The core consisting of a straight tungsten wire carrying a helix of tungsten is immersed in the resulting paste, dried, and the treatment is repeated two or three times. The cathode thus obtained is then sintered and sealed'into the lamp. Specifications 237,270, 334,460, [both in Class 39 (i)], and 536,221 are referred to. The Specification as open to inspection under Sect. 91 states that alkali metal oxides may be used instead of alkaline earth oxides. Those metallic constituents which have a work function less than that of molybdenum, e.g. thorium, hafnium, tantalum, or iron, are present in the proportion of at least 1 per cent, preferably more than 10 per cent or more than 20 per cent. The tungsten or molybdenum may be replaced partly or wholly by tantalum, nickel, or zirconium. This subject-matter does not appear in the Specification as accepted.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL249958X | 1942-03-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB648955A true GB648955A (en) | 1951-01-17 |
Family
ID=19781041
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB12657/46A Expired GB648955A (en) | 1942-03-21 | 1946-04-26 | Improvements in electron-emitting electrodes for electric discharge tubes |
Country Status (5)
Country | Link |
---|---|
US (1) | US2488731A (en) |
BE (1) | BE450151A (en) |
CH (1) | CH249958A (en) |
FR (1) | FR892748A (en) |
GB (1) | GB648955A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0010742A1 (en) * | 1978-11-06 | 1980-05-14 | Westinghouse Electric Corporation | H.I.D. lamp electrode comprising barium-calcium niobate or tantalate |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2755199A (en) * | 1951-02-19 | 1956-07-17 | Kellogg M W Co | Hard coated composite and method of forming |
US2743400A (en) * | 1951-05-29 | 1956-04-24 | Fansteel Metallurgical Corp | Electrolytic devices |
US2941281A (en) * | 1953-12-04 | 1960-06-21 | Int Nickel Co | Hot workable, heat resistant metal bodies |
US2828254A (en) * | 1954-01-05 | 1958-03-25 | Vitro Corp Of America | Method of forming a high friction element |
US2830017A (en) * | 1954-01-18 | 1958-04-08 | Vitro Corp Of America | Method of forming a sacrificial lubricating layer |
US2861935A (en) * | 1954-05-20 | 1958-11-25 | Vitro Corp Of America | Electrophoretic method of applying a lubricant coating |
US2826541A (en) * | 1954-06-15 | 1958-03-11 | Vitro Corp Of America | Method of making ceramic-clad metal structures |
US2881512A (en) * | 1954-06-16 | 1959-04-14 | Cie Generale De Telegraphite S | Composition for sintered barium cathodes |
US3082516A (en) * | 1957-12-03 | 1963-03-26 | Union Carbide Corp | Fabrication of metal shapes |
US3075066A (en) * | 1957-12-03 | 1963-01-22 | Union Carbide Corp | Article of manufacture and method of making same |
US3088195A (en) * | 1958-06-16 | 1963-05-07 | Copperweld Steel Co | Cladding with powdered metal to form bimetallic products |
DE1180435B (en) * | 1958-12-12 | 1964-10-29 | Varta Ag | Continuous process for the production of sintered frameworks for foil electrodes, in particular strip electrodes, for electric accumulators |
US3197847A (en) * | 1961-04-27 | 1965-08-03 | Sylvania Electric Prod | Clad materials and process of fabricating the same |
US3352694A (en) * | 1963-06-17 | 1967-11-14 | Varian Associates | Low temperature metallizing paint and method of making same |
US3323924A (en) * | 1964-03-27 | 1967-06-06 | Varian Associates | Low dielectric loss metallizing paint composition having a reduced sintering temperature |
US3489554A (en) * | 1969-03-13 | 1970-01-13 | Sylvania Electric Prod | Art of producing emitter-type electrode structures |
US5041041A (en) * | 1986-12-22 | 1991-08-20 | Gte Products Corporation | Method of fabricating a composite lamp filament |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1422019A (en) * | 1913-01-17 | 1922-07-04 | Yunck John Adam | Alloy of refractory metals and process of forming same |
AT91341B (en) * | 1914-07-15 | 1923-02-26 | Aeg | Electrical discharge vessel for pure electron discharge. |
US1997693A (en) * | 1929-11-16 | 1935-04-16 | Westinghouse Electric & Mfg Co | Electrical discharge device |
US2219590A (en) * | 1937-01-21 | 1940-10-29 | Henry E Fracker | Multiunit tube |
US2208920A (en) * | 1939-06-03 | 1940-07-23 | Rca Corp | Cathode for electron discharge devices |
-
0
- BE BE450151D patent/BE450151A/xx unknown
-
1943
- 1943-03-19 CH CH249958D patent/CH249958A/en unknown
- 1943-03-22 FR FR892748D patent/FR892748A/en not_active Expired
-
1946
- 1946-04-26 GB GB12657/46A patent/GB648955A/en not_active Expired
- 1946-04-27 US US665636A patent/US2488731A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0010742A1 (en) * | 1978-11-06 | 1980-05-14 | Westinghouse Electric Corporation | H.I.D. lamp electrode comprising barium-calcium niobate or tantalate |
Also Published As
Publication number | Publication date |
---|---|
CH249958A (en) | 1947-07-31 |
BE450151A (en) | |
FR892748A (en) | 1944-05-17 |
US2488731A (en) | 1949-11-22 |
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