GB647530A - Improvements in or relating to the manufacture of organo-halosilanes - Google Patents

Improvements in or relating to the manufacture of organo-halosilanes

Info

Publication number
GB647530A
GB647530A GB19657/47A GB1965747A GB647530A GB 647530 A GB647530 A GB 647530A GB 19657/47 A GB19657/47 A GB 19657/47A GB 1965747 A GB1965747 A GB 1965747A GB 647530 A GB647530 A GB 647530A
Authority
GB
United Kingdom
Prior art keywords
carbon atoms
alkyl
mentioned
halosilanes
organo
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB19657/47A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Silicones Corp
Original Assignee
Dow Corning Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Corning Corp filed Critical Dow Corning Corp
Publication of GB647530A publication Critical patent/GB647530A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/12Organo silicon halides
    • C07F7/121Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
    • C07F7/122Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20 by reactions involving the formation of Si-C linkages

Abstract

An alkyldihalosilane of the general formula <FORM:0647530/IV (b)/1> wherein R represents an alkyl radical containing more than 12 carbon atoms and X represents a halogen atom, is prepared by reacting an alkyl magnesium halide having more than 12 carbon atoms with its molecular equivalent or more of a trihalosilane in the presence of an ether. The product may be separated from the reaction product by fractional distillation. The reaction may be carried out at below room temperature during the addition of the Grignard reagent. Alkyl magnesium chlorides or bromides may be used, while those containing from 14 to 20 carbon atoms are preferred. Specific alkyl groups mentioned are the tetradecyl, hexadecyl, stearyl, eicosyl and myricyl groups. Trichloro-, trifluoro- and tribromo-silanes are mentioned as suitable trihalosilanes.
GB19657/47A 1946-08-15 1947-07-22 Improvements in or relating to the manufacture of organo-halosilanes Expired GB647530A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US647530XA 1946-08-15 1946-08-15

Publications (1)

Publication Number Publication Date
GB647530A true GB647530A (en) 1950-12-13

Family

ID=22058055

Family Applications (1)

Application Number Title Priority Date Filing Date
GB19657/47A Expired GB647530A (en) 1946-08-15 1947-07-22 Improvements in or relating to the manufacture of organo-halosilanes

Country Status (1)

Country Link
GB (1) GB647530A (en)

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