GB643730A - Production of hydroxy benzene resins and product thereof - Google Patents
Production of hydroxy benzene resins and product thereofInfo
- Publication number
- GB643730A GB643730A GB21362/47A GB2136247A GB643730A GB 643730 A GB643730 A GB 643730A GB 21362/47 A GB21362/47 A GB 21362/47A GB 2136247 A GB2136247 A GB 2136247A GB 643730 A GB643730 A GB 643730A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methylol
- phenol
- specified
- resorcinol
- reacting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
- C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
- C08G8/24—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with mixtures of two or more phenols which are not covered by only one of the groups C08G8/10 - C08G8/20
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
Resinous adhesive masses are obtained by reacting at reflux temperatures a molten mixture of a methylol monohydric phenol and a polyhydric phenol having its hydroxyl groups on the same aromatic nucleous. The methylol phenol may be used in proportions sufficient to give a one-stage resin or a two-stage resin hardenable by addition of a setting agent. There are specified: polyhydric phenols: resorcinol, catechol, hydroquinone, pyrogallol, phloroglucinol; methylol monohydric phenols: phenol, cresol, cresylic acid, or xylenols substituted by one or more methylol groups. As setting agents for the two-stage resins are specified: hexa, oxymethylenes, paraform, paraldehydes, methylol compounds, e.g. dimethylol paracresol, methylol ureas or thioureas or methylol-melamines, with or without hexa, acetaldehyde, paraldehyde, propionaldehyde, butyl aldehydes, or furfuraldehydes. Catalysts for the reaction may be oxalic, hydrochloric, sulphuric, phosphoric, boric, citric, salicylic or acetic acids, or borax, sodium hydroxide, azoxy-toluidine, aniline, or ethanolamines. Alcohols and aliphatic and aromatic ketones are specified as solvents. The products may be used to bond laminates in forming aeroplanes, furniture, boats, and laminations of wood, metal, or alternate layers of wood and cloth or asbestos may be used. A polymethylol phenol for use as a setting agent is prepared by reacting phenol and formaldehyde at 20-25 DEG C. with a sodium hydroxide catalyst. The Specification as open to inspection under Sect. 91 describes the reaction of mono- and poly-hydric-phenols with other methylol compounds, e.g. resorcinol and dimethylol urea, nitromethane, or trimethylol amino methane; phenol and dimethylol urea. A fusible resin is obtained by reacting resorcinol at 100 DEG C. with part of the formaldehyde and adding the remainder while keeping the mixture boiling. Trimethylol methane is specified as hardener. This subject-matter does not appear in the Specification as accepted.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US643730XA | 1942-12-03 | 1942-12-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB643730A true GB643730A (en) | 1950-09-27 |
Family
ID=22055489
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB21362/47A Expired GB643730A (en) | 1942-12-03 | 1947-08-06 | Production of hydroxy benzene resins and product thereof |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB643730A (en) |
-
1947
- 1947-08-06 GB GB21362/47A patent/GB643730A/en not_active Expired
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