GB643730A - Production of hydroxy benzene resins and product thereof - Google Patents

Production of hydroxy benzene resins and product thereof

Info

Publication number
GB643730A
GB643730A GB21362/47A GB2136247A GB643730A GB 643730 A GB643730 A GB 643730A GB 21362/47 A GB21362/47 A GB 21362/47A GB 2136247 A GB2136247 A GB 2136247A GB 643730 A GB643730 A GB 643730A
Authority
GB
United Kingdom
Prior art keywords
methylol
phenol
specified
resorcinol
reacting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB21362/47A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beazer East Inc
Original Assignee
Koppers Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Koppers Co Inc filed Critical Koppers Co Inc
Publication of GB643730A publication Critical patent/GB643730A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G8/00Condensation polymers of aldehydes or ketones with phenols only
    • C08G8/04Condensation polymers of aldehydes or ketones with phenols only of aldehydes
    • C08G8/08Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
    • C08G8/24Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with mixtures of two or more phenols which are not covered by only one of the groups C08G8/10 - C08G8/20

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Phenolic Resins Or Amino Resins (AREA)

Abstract

Resinous adhesive masses are obtained by reacting at reflux temperatures a molten mixture of a methylol monohydric phenol and a polyhydric phenol having its hydroxyl groups on the same aromatic nucleous. The methylol phenol may be used in proportions sufficient to give a one-stage resin or a two-stage resin hardenable by addition of a setting agent. There are specified: polyhydric phenols: resorcinol, catechol, hydroquinone, pyrogallol, phloroglucinol; methylol monohydric phenols: phenol, cresol, cresylic acid, or xylenols substituted by one or more methylol groups. As setting agents for the two-stage resins are specified: hexa, oxymethylenes, paraform, paraldehydes, methylol compounds, e.g. dimethylol paracresol, methylol ureas or thioureas or methylol-melamines, with or without hexa, acetaldehyde, paraldehyde, propionaldehyde, butyl aldehydes, or furfuraldehydes. Catalysts for the reaction may be oxalic, hydrochloric, sulphuric, phosphoric, boric, citric, salicylic or acetic acids, or borax, sodium hydroxide, azoxy-toluidine, aniline, or ethanolamines. Alcohols and aliphatic and aromatic ketones are specified as solvents. The products may be used to bond laminates in forming aeroplanes, furniture, boats, and laminations of wood, metal, or alternate layers of wood and cloth or asbestos may be used. A polymethylol phenol for use as a setting agent is prepared by reacting phenol and formaldehyde at 20-25 DEG C. with a sodium hydroxide catalyst. The Specification as open to inspection under Sect. 91 describes the reaction of mono- and poly-hydric-phenols with other methylol compounds, e.g. resorcinol and dimethylol urea, nitromethane, or trimethylol amino methane; phenol and dimethylol urea. A fusible resin is obtained by reacting resorcinol at 100 DEG C. with part of the formaldehyde and adding the remainder while keeping the mixture boiling. Trimethylol methane is specified as hardener. This subject-matter does not appear in the Specification as accepted.
GB21362/47A 1942-12-03 1947-08-06 Production of hydroxy benzene resins and product thereof Expired GB643730A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US643730XA 1942-12-03 1942-12-03

Publications (1)

Publication Number Publication Date
GB643730A true GB643730A (en) 1950-09-27

Family

ID=22055489

Family Applications (1)

Application Number Title Priority Date Filing Date
GB21362/47A Expired GB643730A (en) 1942-12-03 1947-08-06 Production of hydroxy benzene resins and product thereof

Country Status (1)

Country Link
GB (1) GB643730A (en)

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