GB622642A - Dehydrochlorination of chlorinated hydrocarbons and distillation of resulting compounds - Google Patents
Dehydrochlorination of chlorinated hydrocarbons and distillation of resulting compoundsInfo
- Publication number
- GB622642A GB622642A GB3063/46A GB306346A GB622642A GB 622642 A GB622642 A GB 622642A GB 3063/46 A GB3063/46 A GB 3063/46A GB 306346 A GB306346 A GB 306346A GB 622642 A GB622642 A GB 622642A
- Authority
- GB
- United Kingdom
- Prior art keywords
- reaction
- corrosion
- chlorethanes
- resistant
- column
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
- B01D3/143—Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/02—Apparatus characterised by being constructed of material selected for its chemically-resistant properties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/02—Apparatus characterised by their chemically-resistant properties
- B01J2219/025—Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper
- B01J2219/0259—Enamel
Abstract
<PICT:0622642/III/1> In the dehydrochlorination of chlorinated hydrocarbons by reaction with a hydroxide and distillation of the resulting products, the start of the reaction is effected in an apparatus resistant to corrosion and then the liquid and vapour products are introduced into a distillation column non-resistant to corrosion where the reaction is continued and the products rectified. The process is exemplified by the conversion of chlorethanes to chlorethylenes as given by the reactions <FORM:0622642/III/1> A distillation column A having cast iron plates is connected by conduits 4, 5 for vapours and liquids respectively to a preliminary reaction column B made of stone ware or enamelled metal into which the chlorethanes, milk of lime and water are injected continuously through lines 1, 2, 3. Chlorethylene and undecomposed chlorethanes pass through line 9 to a column C from which chlorethylenes are recovered through line 10, while chlorethanes are recovered through line 11 and passed to a secondary corrosion resistant reactor D to which further supplies of lime and water are admitted at 12, 13. In the Specification as open to inspection under Sect. 91, the described procedure is stated to be applicable to any chemical reaction in which the reactants used produce corrosion of the reactor and fractionating columns, e.g. the direct chlorination of benzene, the treatment of chlorides of benzene and organometallic compounds with caustic soda &c. This subject-matter does not appear in the Specification as accepted.ALSO:<PICT:0622642/IV (b)/1> In the dehydrochlorination of chlorinated hydrocarbons by reaction with a hydroxide and distillation of the resulting products, the start of the reaction is effected in an apparatus resistant to corrosion and then the liquid and vapour products are introduced into a distillation column non-resistant to corrosion where the reaction is continued and the products rectified. The process is exemplified by the conversion of chlorethanes to chlorethylenes as given by the reactions. <FORM:0622642/IV (b)/1> A distillation column A having cast-iron plates is connected by conduits 4, 5 for vapours and liquids respectively to a preliminary reaction column B made of stone-ware or enamelled metal into which the chlorethanes, milk of lime and water are injected continuously through lines 1, 2, 3. Chlorethylene and undecomposed chlorethanes pass through line 9 to a column C from which chlorethylenes are recovered through line 11 and passed to a secondary corrosion-resistant reactor D to which further supplies of lime and water are admitted at 12, 13. In the Specification as open to inspection under Sect. 91, the described procedure, using the apparatus specified, is stated to be applicable to any chemical reaction in which the reactant used produces corrosion of the reactor and fractionating columns, e.g. the direct chlorination of benzene and treatment of the product with caustic soda. This subject-matter does not appear in the Specification as accepted.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE246249X | 1943-10-13 | ||
BE622642X | 1943-10-13 | ||
BE906772X | 1943-10-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB622642A true GB622642A (en) | 1949-05-05 |
Family
ID=27159631
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3063/46A Expired GB622642A (en) | 1943-10-13 | 1946-01-30 | Dehydrochlorination of chlorinated hydrocarbons and distillation of resulting compounds |
Country Status (3)
Country | Link |
---|---|
CH (1) | CH246249A (en) |
GB (1) | GB622642A (en) |
NL (1) | NL118988C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3290398A (en) * | 1961-01-18 | 1966-12-06 | Feldmuehle Ag | Process of continuously producing vinylidene chloride |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2475414A1 (en) * | 1980-02-08 | 1981-08-14 | Chimie Dev Internal | METHOD AND APPARATUS FOR SEPARATING, BY DISTILLATION, A MIXTURE OF PRODUCTS CONTAINING AN ELEMENT WHICH MAY PRECIPITATE AT A NORMAL DISTILLATION OF THE MIXTURE |
-
0
- NL NL118988D patent/NL118988C/xx active
-
1944
- 1944-09-02 CH CH246249D patent/CH246249A/en unknown
-
1946
- 1946-01-30 GB GB3063/46A patent/GB622642A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3290398A (en) * | 1961-01-18 | 1966-12-06 | Feldmuehle Ag | Process of continuously producing vinylidene chloride |
Also Published As
Publication number | Publication date |
---|---|
CH246249A (en) | 1946-12-31 |
NL118988C (en) |
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