GB620320A - Manufacture and use of dehydrated lactic acid - Google Patents
Manufacture and use of dehydrated lactic acidInfo
- Publication number
- GB620320A GB620320A GB2923246A GB2923246A GB620320A GB 620320 A GB620320 A GB 620320A GB 2923246 A GB2923246 A GB 2923246A GB 2923246 A GB2923246 A GB 2923246A GB 620320 A GB620320 A GB 620320A
- Authority
- GB
- United Kingdom
- Prior art keywords
- lactic acid
- solution
- xylene
- vessel
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
- C08G63/065—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids the hydroxy and carboxylic ester groups being bound to aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
Abstract
A solution of anhydro-condensation products of lactic acid free from sugars, gums and inorganic salts is obtained from commercial aqueous lactic acid by removing water from it until the dehydrated acid is soluble in an aromatic, hydroaromatic or paraffin hydrocarbon solvent, dissolving it in the solvent as it is formed or after its formation, and separating the resulting solution from insoluble material. Benzene, toluene, xylene, cyclohexane, white spirit, or petroleum ether may be used as solvent. The water may be removed by distillation under reduced pressure, or in the presence of an entrainer. In the latter case the hydrocarbon solvent may be used as entrainer. In an example, "fermentation" aqueous lactic acid containing 7.7 parts by weight of C3H6O3 was boiled with excess xylene in a vessel fitted with a condenser and separator from which the xylene layer was returned to the vessel. Boiling was continued until the xylene contained in solution 7.42 parts of dehydrated lactic acid (calculated as C3H6O3). The solution was decanted from insoluble matter, and the xylene removed by evaporation. In another example, 75 per cent lactic acid was concentrated by evaporation under reduced pressure until it contained 106.2 per cent C3H6O3. The solution was then boiled under reflux for 30 minutes with about 4 parts of xylene. The solution was decanted off and the residue refluxed with a further quantity of xylene. The extraction was repeated 4 more times. In a further example, the aqueous lactic acid was boiled with benzene in a vessel fitted with a condenser and separator. The supernatent benzene solution in the vessel was continuously withdrawn and transferred to a second vessel from which the benzene was removed by distillation and returned to the first vessel. After several hours nearly all the original lactic acid was in the second vessel in the dehydrated state, while the insoluble impurities remained in the first vessel.ALSO:A solution of anhydro-condensation products of lactic acid free from sugars, gums and inorganic salts is obtained from commercial aqueous lactic acid by removing water from it until the dehydrated acid is soluble in an aromatic, hydroaromatic or paraffin hydrocarbon solvent, dissolving it in the solvent as it is formed or after its formation, and separating the resulting solution p from insoluble material. Benzene, toluene, xylene, cyclohexane, white spirit, or petroleum ether may be used as solvent. The water may be removed by distillation under reduced pressure, or in the presence of an entrainer. In the latter case the hydrocarbon solvent may be used as entrainer. Examples are given (see Group III). The purified dehydrated lactic acid may be used for various purposes, either in solution or after being freed from the solvent. Thus it may be used for the preparation of lactic acid esters, or for producing purified lactic acid by hydrolysis. The dehydrated lactic acid may be reacted with formaldehyde, lactose, furfuraldehyde, or monohydric or polyhydric alcohols, to produce resinous products.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2923246A GB620320A (en) | 1946-10-01 | 1946-10-01 | Manufacture and use of dehydrated lactic acid |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2923246A GB620320A (en) | 1946-10-01 | 1946-10-01 | Manufacture and use of dehydrated lactic acid |
Publications (1)
Publication Number | Publication Date |
---|---|
GB620320A true GB620320A (en) | 1949-03-23 |
Family
ID=10288227
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2923246A Expired GB620320A (en) | 1946-10-01 | 1946-10-01 | Manufacture and use of dehydrated lactic acid |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB620320A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2017347A1 (en) * | 2006-03-29 | 2009-01-21 | Bio-Energy Corporation | Method for separation of lactic acid component from lactic acid fermentation liquor, and separation apparatus |
-
1946
- 1946-10-01 GB GB2923246A patent/GB620320A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2017347A1 (en) * | 2006-03-29 | 2009-01-21 | Bio-Energy Corporation | Method for separation of lactic acid component from lactic acid fermentation liquor, and separation apparatus |
JP5083775B2 (en) * | 2006-03-29 | 2012-11-28 | Bio−energy株式会社 | Method and apparatus for separating lactic acid components from lactic acid fermentation broth |
EP2017347B1 (en) * | 2006-03-29 | 2014-05-07 | Bio-Energy Corporation | Method for separation of lactic acid component from lactic acid fermentation liquor, and separation apparatus |
US8859245B2 (en) | 2006-03-29 | 2014-10-14 | Bio-Energy Corporation | Method for separation of lactic acid component from lactic acid fermentation liquor, and separation apparatus |
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