GB610136A - Degradation of aromatic linear polyesters - Google Patents
Degradation of aromatic linear polyestersInfo
- Publication number
- GB610136A GB610136A GB963946A GB963946A GB610136A GB 610136 A GB610136 A GB 610136A GB 963946 A GB963946 A GB 963946A GB 963946 A GB963946 A GB 963946A GB 610136 A GB610136 A GB 610136A
- Authority
- GB
- United Kingdom
- Prior art keywords
- heating
- ester
- linear polyesters
- terephthalate
- degradation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Aromatic linear polyesters obtainable by heating glycols of the series HO(CH2)nOH, where n is greater than 1 but not greater than 10, with terephthalic acid or with an ester-forming derivative of the acid, for example an aliphatic or aryl ester or half-ester, an acid halide or an ammonium or amine salt, are p degraded by heating with the glycol used in the manufacture of the polyester or with a terephthalate of the glycol or a low molecular weight polyester formed from the terephthalate. The heating is continued until a homogeneous fluid results, preferably at a temperature about the boiling point of the glycol used, and at atmospheric or elevated pressures.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB963946A GB610136A (en) | 1946-03-28 | 1946-03-28 | Degradation of aromatic linear polyesters |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB963946A GB610136A (en) | 1946-03-28 | 1946-03-28 | Degradation of aromatic linear polyesters |
Publications (1)
Publication Number | Publication Date |
---|---|
GB610136A true GB610136A (en) | 1948-10-12 |
Family
ID=9875872
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB963946A Expired GB610136A (en) | 1946-03-28 | 1946-03-28 | Degradation of aromatic linear polyesters |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB610136A (en) |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2607656A (en) * | 1948-03-17 | 1952-08-19 | Ici Ltd | Production of close woven cellulose fabrics by dissolving terylene support yarn |
DE1052394B (en) * | 1956-05-26 | 1959-03-12 | Hoechst Ag | Process for the production of terephthalic acid-bis-ethylene glycol ester by degradation vo |
US2903477A (en) * | 1957-03-27 | 1959-09-08 | Exxon Research Engineering Co | Esterification process for producing purified plasticizer esters |
US2926189A (en) * | 1956-06-08 | 1960-02-23 | Distillers Co Yeast Ltd | Esterification of diammonium terephthalate with glycol |
US2933476A (en) * | 1955-09-30 | 1960-04-19 | Du Pont | Polymerization process |
US2968538A (en) * | 1956-11-15 | 1961-01-17 | Du Pont | Delustering of film |
US3222299A (en) * | 1961-10-16 | 1965-12-07 | Du Pont | Process of reclaiming linear terephthalate polyester |
DE1247291B (en) * | 1964-04-28 | 1967-08-17 | Schwarza Chemiefaser | Process and device for the production of dialkyl terephthalates by degradation of polyethylene glycol terephthalates |
JPS4978032A (en) * | 1972-12-04 | 1974-07-27 | ||
JPS4980320A (en) * | 1972-12-04 | 1974-08-02 | ||
US4609680A (en) * | 1984-05-25 | 1986-09-02 | Toray Industries, Inc. | Process for the depolymerization of polyester scrap |
EP0641366A1 (en) * | 1992-05-18 | 1995-03-08 | Swig Pty. Ltd. | Improved poly ethylene terephthalate decontamination |
US5602187A (en) * | 1992-05-18 | 1997-02-11 | Swig Pty Ltd. | Polyethylene terephthalate decontamination |
WO1997020886A1 (en) * | 1995-12-07 | 1997-06-12 | Eastman Chemical Company | Process including glycolysis and subsequent purification for recycling polyester materials |
US5869543A (en) * | 1996-10-22 | 1999-02-09 | Zimmer Aktiengesellschaft | Process for the synthesis of polyethylene carboxylate from polyethylene carboxylate waste |
US9234074B2 (en) | 2012-04-20 | 2016-01-12 | Perpetual Global Technologies Limited | Flakes of ester mixtures and methods for their production |
US9255194B2 (en) | 2013-10-15 | 2016-02-09 | International Business Machines Corporation | Methods and materials for depolymerizing polyesters |
US9714334B2 (en) | 2015-01-30 | 2017-07-25 | Resinate Materials Group, Inc. | Integrated process for treating recycled PET and PTT materials |
US9732026B2 (en) | 2012-12-14 | 2017-08-15 | Resinate Technologies, Inc. | Reaction products containing hydroxyalkylterephthalates and methods of making and using same |
DE102021212695A1 (en) | 2021-11-11 | 2023-05-11 | Thyssenkrupp Ag | DEVICE AND PROCESS FOR THE PRODUCTION OF A POLYESTER DEPOLYMER, AND DEVICE AND PROCESS FOR THE PRODUCTION OF A POLYESTER |
EP4276132A1 (en) | 2022-05-10 | 2023-11-15 | Polymetrix AG | Monomer recycling of polyesters |
-
1946
- 1946-03-28 GB GB963946A patent/GB610136A/en not_active Expired
Cited By (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2607656A (en) * | 1948-03-17 | 1952-08-19 | Ici Ltd | Production of close woven cellulose fabrics by dissolving terylene support yarn |
US2933476A (en) * | 1955-09-30 | 1960-04-19 | Du Pont | Polymerization process |
DE1052394B (en) * | 1956-05-26 | 1959-03-12 | Hoechst Ag | Process for the production of terephthalic acid-bis-ethylene glycol ester by degradation vo |
US2926189A (en) * | 1956-06-08 | 1960-02-23 | Distillers Co Yeast Ltd | Esterification of diammonium terephthalate with glycol |
US2968538A (en) * | 1956-11-15 | 1961-01-17 | Du Pont | Delustering of film |
US2903477A (en) * | 1957-03-27 | 1959-09-08 | Exxon Research Engineering Co | Esterification process for producing purified plasticizer esters |
US3222299A (en) * | 1961-10-16 | 1965-12-07 | Du Pont | Process of reclaiming linear terephthalate polyester |
DE1247291B (en) * | 1964-04-28 | 1967-08-17 | Schwarza Chemiefaser | Process and device for the production of dialkyl terephthalates by degradation of polyethylene glycol terephthalates |
JPS4978032A (en) * | 1972-12-04 | 1974-07-27 | ||
JPS4980320A (en) * | 1972-12-04 | 1974-08-02 | ||
JPS553443B2 (en) * | 1972-12-04 | 1980-01-25 | ||
JPS5619464B2 (en) * | 1972-12-04 | 1981-05-07 | ||
US4609680A (en) * | 1984-05-25 | 1986-09-02 | Toray Industries, Inc. | Process for the depolymerization of polyester scrap |
EP0641366A4 (en) * | 1992-05-18 | 1995-05-31 | Petwest Pty Ltd | Improved poly ethylene terephthalate decontamination. |
US5602187A (en) * | 1992-05-18 | 1997-02-11 | Swig Pty Ltd. | Polyethylene terephthalate decontamination |
EP0641366A1 (en) * | 1992-05-18 | 1995-03-08 | Swig Pty. Ltd. | Improved poly ethylene terephthalate decontamination |
WO1997020886A1 (en) * | 1995-12-07 | 1997-06-12 | Eastman Chemical Company | Process including glycolysis and subsequent purification for recycling polyester materials |
US5869543A (en) * | 1996-10-22 | 1999-02-09 | Zimmer Aktiengesellschaft | Process for the synthesis of polyethylene carboxylate from polyethylene carboxylate waste |
US9234074B2 (en) | 2012-04-20 | 2016-01-12 | Perpetual Global Technologies Limited | Flakes of ester mixtures and methods for their production |
EP2838941B1 (en) * | 2012-04-20 | 2019-11-06 | Perpetual Global Technologies Limited | Flakes of ester mixtures and methods for their production |
US9732026B2 (en) | 2012-12-14 | 2017-08-15 | Resinate Technologies, Inc. | Reaction products containing hydroxyalkylterephthalates and methods of making and using same |
US9914816B2 (en) | 2013-10-15 | 2018-03-13 | International Business Machines Corporation | Methods and materials for depolymerizing polyesters |
US9255194B2 (en) | 2013-10-15 | 2016-02-09 | International Business Machines Corporation | Methods and materials for depolymerizing polyesters |
US9752005B2 (en) | 2015-01-30 | 2017-09-05 | Resinate Materials Group, Inc. | Integrated process for treating recycled streams of PET and PTT |
US9714334B2 (en) | 2015-01-30 | 2017-07-25 | Resinate Materials Group, Inc. | Integrated process for treating recycled PET and PTT materials |
US10119006B2 (en) | 2015-01-30 | 2018-11-06 | Resinate Materials Group, Inc. | Integrated process for treating recycled streams of PET and PTT |
DE102021212695A1 (en) | 2021-11-11 | 2023-05-11 | Thyssenkrupp Ag | DEVICE AND PROCESS FOR THE PRODUCTION OF A POLYESTER DEPOLYMER, AND DEVICE AND PROCESS FOR THE PRODUCTION OF A POLYESTER |
WO2023083692A2 (en) | 2021-11-11 | 2023-05-19 | Uhde Inventa-Fischer Gmbh | Device and method for producing a polyester depolymerizate, and device and method for producing a polyester |
EP4276132A1 (en) | 2022-05-10 | 2023-11-15 | Polymetrix AG | Monomer recycling of polyesters |
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