GB609648A - Improved resins and compositions containing the same - Google Patents

Improved resins and compositions containing the same

Info

Publication number
GB609648A
GB609648A GB8551/46A GB855146A GB609648A GB 609648 A GB609648 A GB 609648A GB 8551/46 A GB8551/46 A GB 8551/46A GB 855146 A GB855146 A GB 855146A GB 609648 A GB609648 A GB 609648A
Authority
GB
United Kingdom
Prior art keywords
isoprene
fumaric acid
glycerol
resins
acid adduct
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB8551/46A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wyeth Holdings LLC
Original Assignee
American Cyanamid Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by American Cyanamid Co filed Critical American Cyanamid Co
Publication of GB609648A publication Critical patent/GB609648A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C08G63/54Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/553Acids or hydroxy compounds containing cycloaliphatic rings, e.g. Diels-Alder adducts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

Synthetic resins for use in lacquers, varnishes and various coating compositions are prepared by reacting fumaric acid-conjugated acyclic diene adducts with at least one polyhydric organic compound containing two or more hydroxyl groups attached to different carbon atoms in an open chain. The conjugated acylic diene may be butadiene, piperylene, isoprene, or an isoprene-piperylene mixture, and examples of the polyhydric organic compound are ethylene glycol, butylene glycol, diethylene glycol, tetraethylene glycol, glycerol, polyglycerols, glycerol monomethyl ether, a -glycerol phenyl ether, glycerol furfuryl ether, pentaerythritol, sorbitol and mannitol. Modifiers may be added, such as fatty oil mono- and di-glycerides, saturated and unsaturated fatty acids, saturated and unsaturated polycarboxylic acids, natural or artificial resins such as ureaand melamine-formaldehyde resins and particularly alkylated urea and melamine resins, drying oils and non-drying oils. Catalysts such as benzene sulphuric acid, naphthylamine sulphuric acid, cobalt linoleate, lead oleate, aluminium stearate or silica gel or retarders such as naphthalene or boric acid may be employed. The resins are soluble in benzene, toluene, xylene, ethyl benzene, naphtha, carbon tetrachloride and other hydrocarbon solvents. The preparations of adducts of fumaric acid with an isoprene-piperylene mixture, isoprene, allo-ocimene and butadiene are described. In the examples, resins are made from (1) an isoprene-fumaric acid adduct, refined linseed monoglyceride and glycerol; (2) isoprene-fumaric acid adduct, refined linseed mono glyceride, glycerol and fumaric acid; (3) isoprene-fumaric acid adduct, linseed acids and pentaerythritol; (4) isoprene-fumaric acid adduct, refined castor oil, glycerine, soya fatty acids; (5) phthalic anhydride, isoprene-fumaric acid adduct, refined castor oil, soya fatty acids and glycerine; (6) the resin from example 1, butylated urea-formaldehyde resin and cobalt naphthenate.
GB8551/46A 1945-07-17 1946-03-19 Improved resins and compositions containing the same Expired GB609648A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US609648XA 1945-07-17 1945-07-17

Publications (1)

Publication Number Publication Date
GB609648A true GB609648A (en) 1948-10-05

Family

ID=22032842

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8551/46A Expired GB609648A (en) 1945-07-17 1946-03-19 Improved resins and compositions containing the same

Country Status (1)

Country Link
GB (1) GB609648A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3340327A (en) * 1961-03-13 1967-09-05 Desoto Inc Fumaric acid-polyoxyalkylene glycoldicyclopentadiene polyesters curable with vinyl monomer and mixtures thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3340327A (en) * 1961-03-13 1967-09-05 Desoto Inc Fumaric acid-polyoxyalkylene glycoldicyclopentadiene polyesters curable with vinyl monomer and mixtures thereof

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