GB600218A - Improvements in or relating to interlining materials and method of producing same - Google Patents

Improvements in or relating to interlining materials and method of producing same

Info

Publication number
GB600218A
GB600218A GB22081/45A GB2208145A GB600218A GB 600218 A GB600218 A GB 600218A GB 22081/45 A GB22081/45 A GB 22081/45A GB 2208145 A GB2208145 A GB 2208145A GB 600218 A GB600218 A GB 600218A
Authority
GB
United Kingdom
Prior art keywords
water
resins
soluble
resin
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB22081/45A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wyeth Holdings LLC
Original Assignee
American Cyanamid Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by American Cyanamid Co filed Critical American Cyanamid Co
Publication of GB600218A publication Critical patent/GB600218A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D27/00—Details of garments or of their making
    • A41D27/02—Linings
    • A41D27/06—Stiffening-pieces
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters
    • D06M15/51—Unsaturated polymerisable polyesters

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Treatment of cloth for interlining garments comprises impregnation with a composition of an aqueous solution of a heat-curable water-soluble methylated methylol melamine resin and a heat-curable water-insoluble mixture of a phthalic anhydride-polyhydric alcohol resin and a member of the group consisting of organic solvent - soluble urea - formaldehyde resins or organic solvent-soluble melamineformaldehyde resins, followed by the application of heat to cure the said resins on the cloth. Suitable amounts of the resins are 2-20 per cent by weight of the water-soluble resin and 1-25 per cent by weight of the mixture of water-insoluble resins, the said mixture comprising 30-85 per cent phthalic-anhydridepolyhydric alcohol resin and 70-15 per cent organic solvent-soluble urea- (or melamine) formaldehyde resin. The resins are most satisfactorily applied in the form of an oil-in-water type emulsion in which the water-soluble resin is dissolved in the continuous aqueous phase and the water-insoluble resins form the dispersed phase. Glue, ammonium caseinate or other water-soluble emulsifying agent may be used to enable the water-insoluble resins to be dispersed. Small amounts of wetting agents (e.g. sodium dioctyl sulphosuccinate) and curing accelerators (e.g. a mixture of equal parts of di-ammonium hydrogen phosphate and hexamethylene tetramine) may be incorporated. The treated fabric is useful for interlining lapels and foundation garments and the like. In an example a butylated urea-formaldehyde resin is blended with a mixture of equal parts of phthalic anhydride-glycerine-cotton seed fatty acid resin and phthalic anhydride-glycerine-castor oil resin by warming to 40 DEG C. to obtain a homogeneous mixture. A dilute solution of ammonium caseinate is added slowly to the blended resins at 30 DEG C. with vigorous agitation until a uniform stable emulsion is formed. To this emulsion there is added a water-soluble methylated methylol melamine resin of 80 per cent resin solids and the agitation continued until solution is complete. The solution is diluted with warm water, and sodium dioctyl sulphosuccinate and a mixture of equal parts of di-ammonium hydrogen phosphate and hexamethylene tetramine are added. Interlining cloth having a cotton warp and a waft of rayon threads and goat's hair is run through the bath and passed through squeeze rolls set to retain a quantity of the emulsion on the cloth equal to the weight of the cloth. The treated cloth is run directly into a loop dry box at 110 DEG C. and cured in an air-lay dry box for 6 minutes at 143-140 DEG C. The finished fabric is shrink-proof and crease-resistant yet flexible and resilient. Preparation of resins used: (a) Water-soluble methylated methylol melamine is prepared by the action of methanol on dry methylol melamine in the presence of oxalic acid. (b) Water-insoluble organic solvent-soluble phthalic anhydride-polyhydric alcohol resins are prepared as usual from phthalic anhydride and glycerine and modified with cotton seed fatty acids, castor oil or soya bean fatty acids. (c) Water-insoluble organic solvent-soluble urea-formaldehyde (or melamine-formaldehyde) resins are prepared by the action of butanol on a mixture of urea (or melamine) and formaldehyde in the presence of a small amount of phosphoric acid.ALSO:Treatment of cloth for interlining garments comprises impregnation with a composition of an aqueous solution of heat-curable water-soluble methylated methylol melamine resin and a heat-curable water-insoluble mixture of a phthalic anhydride-polyhydric alcohol resin and a member of the group consisting of organic solvent-soluble urea-formaldehyde resins or organic solvent-soluble melamine-formaldehyde resins, followed by the application of heat to cure the said resins on the cloth. Suitable amounts of the resins are 2-20 per cent by weight of the water-soluble resin and 1-25 per cent by weight of the mixture of water-insoluble resins, the said mixture comprising 30-85 per cent phthalic - anhydride - polyhydric alcohol resin and 70-15 per cent organic solvent-soluble urea- (or melamine) formaldehyde resin. The resins are most satisfactorily applied in the form of an oil-in-water type emulsion in which the water-soluble resin is dissolved in the continuous aqueous phase and the water-insoluble resins form the dispersed phase. Glue, ammonium caseinate or other water-soluble emulsifying agent may be used to enable the water-insoluble resins to be dispersed. Small amounts of wetting agents (e.g. sodium dioctyl sulphosuccinate) and curing accelerators (e.g. a mixture of equal parts of di - ammonium hydrogen phosphate and hexamethylene tetramine) may be incorporated. The treated fabric is useful for interlining lapels and foundation garments and the like. In an example, a butylated urea-formaldehyde resin is blended with a mixture of equal parts of phthalic anhydride-glycerine-cotton seed fatty acid resin and phthalic anhydride-glycerine-castor oil resin by warming to 40 DEG C. to obtain a homogeneous mixture. A dilute solution of ammonium caseinate is added slowly to the blended resins at 30 DEG C. with vigorous agitation until a uniform stable emulsion is formed. To this emulsion there is added a water-soluble methylated methylol melamine resin of 80 per cent resin solids and the agitation continued until solution is complete. The solution is diluted with warm water, and sodium dioctyl sulphosuccinate and a mixture of equal parts of di-ammonium hydrogen phosphate and hexamethylene tetramine are added. Interlining cloth having a cotton warp and a weft of rayon threads and goats' hair is run through the bath and passed through squeeze rolls set to retain a quantity of the emulsion on the cloth equal to the weight of the cloth. The treated cloth is run directly into a loop dry box at 110 DEG C. and cured in an air-lay dry box for 6 minutes at 143-149 DEG C. The finished fabric is shrink-proof and crease-resistant yet flexible and resilient. Preparation of resins used.-(a) Water-soluble methylated methylol melamine is prepared by the action of methanol on dry methylol melamine in the presence of oxalic acid. (b) Water-insoluble organic solvent-soluble phthalic anhydride-polyhydric alcohol resins are prepared as usual from phthalic anhydride and glycerine and modified with cottonseed fatty acids, castor oil or soya bean fatty acids. (c) Water-insoluble organic solvent-soluble urea-formaldehyde (or melamine-formaldehyde) resins are prepared by the action of butanol on a mixture of urea (or melamine) and formaldehyde in the presence of a small amount of phosphoric acid.
GB22081/45A 1944-08-03 1945-08-28 Improvements in or relating to interlining materials and method of producing same Expired GB600218A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US547965A US2402032A (en) 1944-08-03 1944-08-03 Treatment of interlining materials

Publications (1)

Publication Number Publication Date
GB600218A true GB600218A (en) 1948-04-02

Family

ID=24186876

Family Applications (2)

Application Number Title Priority Date Filing Date
GB22081/45A Expired GB600218A (en) 1944-08-03 1945-08-28 Improvements in or relating to interlining materials and method of producing same
GB23373/45A Expired GB600222A (en) 1944-08-03 1945-09-11 Improvements in or relating to the finishing of lace and net fabrics and the like

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB23373/45A Expired GB600222A (en) 1944-08-03 1945-09-11 Improvements in or relating to the finishing of lace and net fabrics and the like

Country Status (2)

Country Link
US (1) US2402032A (en)
GB (2) GB600218A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE950991C (en) * 1954-09-12 1956-10-18 Karl L Meinhardt Roll flaps on items of clothing and insert for these roll flaps

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB628882A (en) * 1945-11-28 1949-09-07 Ciba Ltd Manufacture of emulsions serving as binding agents for the fixation of pigments on fibrous materials
US2600681A (en) * 1948-03-05 1952-06-17 Monsanto Chemicals Self-supporting films from polyvinyl halide latex
US2589567A (en) * 1948-09-10 1952-03-18 Bell & Richardson Inc De Melamine formaldehyde scratch resistant coating composition, method of applying, and article produced thereby
US2686315A (en) * 1950-04-05 1954-08-17 Shirtcraft Co Inc Zipper shirt
US2704750A (en) * 1951-07-03 1955-03-22 Sherwin Williams Co Aminoplast resins
BE601598A (en) * 1960-03-22 1961-09-21
US3939107A (en) * 1974-09-06 1976-02-17 Monsanto Company Fire-retardant particle board and binder therefor from aminoplast with ammonium polyphosphate-formaldehyde product
US4357714A (en) * 1980-05-02 1982-11-09 Mitsuru Ito Fabric articles and the manufacture thereof
CN104480708A (en) * 2014-11-28 2015-04-01 何庆堃 Real silk fabric finishing agent with anti-static function
CN105369611A (en) * 2015-12-16 2016-03-02 常熟绣珀纤维有限公司 Preparation method of ultrahigh molecular weight polyethylene fine-denier fiber

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE950991C (en) * 1954-09-12 1956-10-18 Karl L Meinhardt Roll flaps on items of clothing and insert for these roll flaps

Also Published As

Publication number Publication date
US2402032A (en) 1946-06-11
GB600222A (en) 1948-04-02

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