GB587831A - Improvements relating to the manufacture of phenolic resins suitable for use as cation exchange materials - Google Patents

Improvements relating to the manufacture of phenolic resins suitable for use as cation exchange materials

Info

Publication number
GB587831A
GB587831A GB1574/45A GB157445A GB587831A GB 587831 A GB587831 A GB 587831A GB 1574/45 A GB1574/45 A GB 1574/45A GB 157445 A GB157445 A GB 157445A GB 587831 A GB587831 A GB 587831A
Authority
GB
United Kingdom
Prior art keywords
mol
product
water
per cent
phenol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1574/45A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DAVID AUBREY FRASER
OCEAN SALTS PRODUCTS Ltd
Original Assignee
DAVID AUBREY FRASER
OCEAN SALTS PRODUCTS Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DAVID AUBREY FRASER, OCEAN SALTS PRODUCTS Ltd filed Critical DAVID AUBREY FRASER
Priority to GB1574/45A priority Critical patent/GB587831A/en
Publication of GB587831A publication Critical patent/GB587831A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G8/00Condensation polymers of aldehydes or ketones with phenols only
    • C08G8/04Condensation polymers of aldehydes or ketones with phenols only of aldehydes
    • C08G8/08Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
    • C08G8/18Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with phenols substituted by carboxylic or sulfonic acid groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/16Organic material
    • B01J39/18Macromolecular compounds
    • B01J39/19Macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds

Abstract

Synthetic resins having cation-exchange properties are obtained by partially condensing a monohydric phenol and an aldehyde or ketone, sulphonating the partially condensed product and then reacting the sulphonated product with a further amount of aldehyde or ketone until a water-soluble gel is obtained. One mol. phenol was refluxed for one hour with one half-mol. formaldehyde in presence of sodium bicarbonate and the product distilled up to 160 DEG C., the residue was cooled and 107 gs. 98 per cent H2SO4 added, the temperature being kept below 98 DEG C. The sulphonated product was diluted with water and 0.75 mol. formaldehyde added; the resulting gel granulated on washing with water, the grains being dried and ground to the required size. A resin made from crude carbolic acid containing 17.5 m-cresol, 5 per cent p-cresol and 52.5 per cent phenol is also described.
GB1574/45A 1945-01-19 1945-01-19 Improvements relating to the manufacture of phenolic resins suitable for use as cation exchange materials Expired GB587831A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1574/45A GB587831A (en) 1945-01-19 1945-01-19 Improvements relating to the manufacture of phenolic resins suitable for use as cation exchange materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1574/45A GB587831A (en) 1945-01-19 1945-01-19 Improvements relating to the manufacture of phenolic resins suitable for use as cation exchange materials

Publications (1)

Publication Number Publication Date
GB587831A true GB587831A (en) 1947-05-07

Family

ID=9724318

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1574/45A Expired GB587831A (en) 1945-01-19 1945-01-19 Improvements relating to the manufacture of phenolic resins suitable for use as cation exchange materials

Country Status (1)

Country Link
GB (1) GB587831A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104107639A (en) * 2014-04-01 2014-10-22 杭州埃尔环保科技有限公司 Method for making continuous homogeneous cation exchange membrane through impregnation technology

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104107639A (en) * 2014-04-01 2014-10-22 杭州埃尔环保科技有限公司 Method for making continuous homogeneous cation exchange membrane through impregnation technology

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