GB584307A - Manufacture of preparations containing cupric oxychloride in a state of colloidal dispersion - Google Patents
Manufacture of preparations containing cupric oxychloride in a state of colloidal dispersionInfo
- Publication number
- GB584307A GB584307A GB14872/43A GB1487243A GB584307A GB 584307 A GB584307 A GB 584307A GB 14872/43 A GB14872/43 A GB 14872/43A GB 1487243 A GB1487243 A GB 1487243A GB 584307 A GB584307 A GB 584307A
- Authority
- GB
- United Kingdom
- Prior art keywords
- per cent
- hrs
- cupric
- stirred
- stirring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G3/00—Compounds of copper
- C01G3/04—Halides
- C01G3/06—Oxychlorides
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Catalysts (AREA)
Abstract
Cupric oxychloride preparations having a high content of colloidally-dispersed cupric oxychloride are produced by treating cupric chloride solution below 20 DEG C., advantageously between 0 DEG C. and 10 DEG C., with cupric oxide containing at least 4 per cent. water, a stabilizer, e.g., gelatine, glue or especially sulphite cellulose waste liquor optionally being incorporated in the resulting solution. In examples: (1) cupric chloride solution of 14.5 per cent. copper content is introduced during 3/4 hr. into dilute aqueous sodium hydroxide at 6-11 DEG C., the mixture being stirred thus for a further 1/2 hr. prior to heating at 85 DEG C. for 1/2 hr., maintaining the resultant precipitated copper oxide at 89 DEG C. for 5 mins. and washing, followed by addition, whilst moist, to a stirred aqueous cupric chloride solution kept at 2-7 DEG C. for 2 hrs. and stirred at room temperature for a further 18 hrs.; the product may be diluted with water to any extent to yield colloidal solutions. Alternatively, the copper chloride may be added to the cupric oxide, or the latter prepared from cupric sulphate, or the concentrations may be varied; (2) cupric chloride solution, containing 18 per cent. copper is introduced during approximately 1 hour into 30 per cent. sodium hydroxide solution maintained at 0-5 DEG C. and the resulting mixture is steam-heated to 83-85 DEG C. during 20-30 mins. and thus maintained for 25 mins., followed by rapid cooling to 70 DEG C. with added ice neutralization with hydrochloric acid, washing of the precipitated copper oxide at 50-60 DEG C. and subsequent addition, with ice, to a stirred cupric chloride solution kept below 7 DEG C., stirring being continued for 7 hrs. at 2-7 DEG C. and ultimately raising the temperature to 20-25 DEG C. during 5-6 hrs. and stirring for a further 6 hrs. to yield a product containing about 86 per cent. colloidal cupric oxychloride; (3) the product obtained as in (1) or (2) advantageously cooled to below 10 DEG C., is stirred with 47 per cent. sulphite cellulose liquor, stirring thus for an additional hour and for 2-3 hrs. at room temperature. The product may be diluted with hard water and is very insensitive to solutions of salt, e.g., sodium sulphate; (4) the aged product of (2) and a mixture of 47 per cent. sulphite cellulose liquor, 30 per cent. sodium hydroxide solution and water are simultaneously charged at room temperature into a stirring vessel when further similar charges are added uniformly, stirring being continued for 2-3 hrs. to yield a preparation having a degree of dispersion of about 64 per cent; (5) the preparation obtained as in (4) is stirred with a 5 per cent. methyl cellulose solution; (6) crystalline cupric chloride is introduced into a stirred mixture of cupric oxide, obtained as in (2), and ice-water; after stirring in an ice-bath for 6-7 hrs. stirring is continued for 18 hrs. at 10-15 DEG C. to yield a homogeneous green mass containing about 50 per cent. colloidal oxychloride. Specification 392,556 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH584307X | 1942-09-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB584307A true GB584307A (en) | 1947-01-13 |
Family
ID=4521709
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB14872/43A Expired GB584307A (en) | 1942-09-16 | 1943-09-10 | Manufacture of preparations containing cupric oxychloride in a state of colloidal dispersion |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB584307A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110342567A (en) * | 2019-07-09 | 2019-10-18 | 深圳市深投环保科技有限公司 | Type B basic copper chloride, preparation method and its application of anti-caking |
-
1943
- 1943-09-10 GB GB14872/43A patent/GB584307A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110342567A (en) * | 2019-07-09 | 2019-10-18 | 深圳市深投环保科技有限公司 | Type B basic copper chloride, preparation method and its application of anti-caking |
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