GB583474A - Improvements in or relating to the production of vinylidene chloride copolymers - Google Patents
Improvements in or relating to the production of vinylidene chloride copolymersInfo
- Publication number
- GB583474A GB583474A GB1215943A GB1215943A GB583474A GB 583474 A GB583474 A GB 583474A GB 1215943 A GB1215943 A GB 1215943A GB 1215943 A GB1215943 A GB 1215943A GB 583474 A GB583474 A GB 583474A
- Authority
- GB
- United Kingdom
- Prior art keywords
- esters
- sodium
- vinylidene chloride
- mixture
- per cent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/02—Monomers containing chlorine
- C08F214/04—Monomers containing two carbon atoms
- C08F214/08—Vinylidene chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A mixture of vinylidene chloride and an ester or esters of maleic and/or fumaric acid derived from alcohols not containing aliphatic unsaturation is polymerized by heating in the presence of a catalytic per-compound. The ester comprises 1 per cent to 50 per cent of the mixture. Esters specified are the dimethyl, diethyl, dibutyl, dihexyl, dioctyl and dibenzyl esters or the esters from ethylene glycol monoalkyl ethers. Copolymerization may be effected in bulk, in the presence or absence of a diluent or in emulsion. Suitable emulsifying agents are potassium oleate, the sodium salt of sulphated lauryl alcohol or sodium isobutyl naphthalene sulphonate. Catalysts specified are hydrogen, benzoyl and crotonyl peroxides and ammonium, sodium and potassium persulphates. The products are soluble in cyclohexanone and dibutyl phthalate. Specifications 466,898 and 476,727 are referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1215943A GB583474A (en) | 1943-07-26 | 1943-07-26 | Improvements in or relating to the production of vinylidene chloride copolymers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1215943A GB583474A (en) | 1943-07-26 | 1943-07-26 | Improvements in or relating to the production of vinylidene chloride copolymers |
Publications (1)
Publication Number | Publication Date |
---|---|
GB583474A true GB583474A (en) | 1946-12-19 |
Family
ID=9999422
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1215943A Expired GB583474A (en) | 1943-07-26 | 1943-07-26 | Improvements in or relating to the production of vinylidene chloride copolymers |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB583474A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1004373B (en) * | 1951-08-23 | 1957-03-14 | Distillers Co Yeast Ltd | Plastic mass |
-
1943
- 1943-07-26 GB GB1215943A patent/GB583474A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1004373B (en) * | 1951-08-23 | 1957-03-14 | Distillers Co Yeast Ltd | Plastic mass |
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