GB577955A - Improvements in lubricating oil compositions by the addition of compounds having oxidation-inhibiting and like qualities - Google Patents

Improvements in lubricating oil compositions by the addition of compounds having oxidation-inhibiting and like qualities

Info

Publication number
GB577955A
GB577955A GB869/43A GB86943A GB577955A GB 577955 A GB577955 A GB 577955A GB 869/43 A GB869/43 A GB 869/43A GB 86943 A GB86943 A GB 86943A GB 577955 A GB577955 A GB 577955A
Authority
GB
United Kingdom
Prior art keywords
phenol
hydroxy
alkyl
compounds
benzyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB869/43A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Development Co
Original Assignee
Standard Oil Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Development Co filed Critical Standard Oil Development Co
Publication of GB577955A publication Critical patent/GB577955A/en
Expired legal-status Critical Current

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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
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    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108Residual fractions, e.g. bright stocks
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026Butene
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16Paraffin waxes; Petrolatum, e.g. slack wax
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/18Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2207/02Hydroxy compounds
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    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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    • C10M2207/146Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings having carboxyl groups bound to carbon atoms of six-membeered aromatic rings having a hydrocarbon substituent of thirty or more carbon atoms
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    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/04Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
    • C10M2211/042Alcohols; Ethers; Aldehydes; Ketones
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    • C10M2211/04Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
    • C10M2211/044Acids; Salts or esters thereof
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    • C10M2211/06Perfluorinated compounds
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    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
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    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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    • C10M2215/202Containing nitrogen-to-oxygen bonds containing nitro groups
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/12Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
    • C10M2223/121Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy of alcohols or phenols
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    • C10M2227/08Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having metal-to-carbon bonds
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    • C10N2010/00Metal present as such or in compounds
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    • C10N2010/04Groups 2 or 12
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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    • C10N2040/02Bearings
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
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    • C10N2040/044Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for manual transmissions
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
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    • C10N2040/046Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/135Steam engines or turbines
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    • C10N2040/25Internal-combustion engines
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    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Semi-solids; greasy
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    • C10N2060/00Chemical after-treatment of the constituents of the lubricating composition
    • C10N2060/04Oxidation, e.g. ozonisation

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Addition agents for lubricating oils are of the general formula <FORM:0577955/IV/1> where "T" represents a negative element of group VI such as O or S, "X" represents H, an organic radicle, an onium base residue or a metal equivalent, "Y" represents H, or an organic group such as alkyl or aryl, "Z" represents an inorganic negative element or radical such as halogen, -CN or -SCN, or a radical which is linked to "R" by a negative element of groups V and VI such as O, S, P or N, and "R" represents a divalent alkyl linkage <FORM:0577955/IV/2> , "R1" being H, alkyl, or aryl. The type of compound emphasized comprises hydroxy-benzyl chloride, hydroxy-benzyl sulphide, hydroxy-benzyl xanthate, hydroxy-benzyl-alkyl thioether as well as metal salts of each of these. Specific examples comprise chlormethyl di-isobutyl phenol and complex derivatives thereof, bis-(amyl thiomethyl) di-isobutyl phenol, and its Ba salt, and xanthates of chlormethyl di-isobutyl phenols and their Ca salts. The compounds are generally prepared by the normal alkyl phenol-formaldehydehydrogen halide condensation reaction and in the case of sulphur derivatives, metal salts and more complex compounds these are then prepared from the above condensation products. The details are given of the preparation of compounds of the hydroxy benzyl chloride type from HCl, paraformaldehyde and diisobutyl phenol and also complex derivatives starting from these condensates. In some cases, the primary reactants are varied, e.g. using diisobutyl phenol sulphide instead of the phenol.
GB869/43A 1942-01-01 1943-01-18 Improvements in lubricating oil compositions by the addition of compounds having oxidation-inhibiting and like qualities Expired GB577955A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US425383A US2415833A (en) 1942-01-01 1942-01-01 Lubricant

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GB577955A true GB577955A (en) 1946-06-06

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US (1) US2415833A (en)
FR (1) FR917266A (en)
GB (1) GB577955A (en)

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US2526755A (en) * 1946-03-15 1950-10-24 Texas Co Turbine oil composition
US2506900A (en) * 1947-02-19 1950-05-09 Gulf Oil Corp Process for preparing addition agents for mineral oil lubricants, the agents so obtained, and mineral oil lubricants containing them
US2497132A (en) * 1947-03-14 1950-02-14 Standard Oil Dev Co Lubricating oil composition
US2506901A (en) * 1947-05-26 1950-05-09 Gulf Oil Corp Addition agents for mineral oil lubricants and compositions containing the same
US2506902A (en) * 1947-05-26 1950-05-09 Gulf Oil Corp Addition agents for mineral oil lubricants and compositions containing the same
US2472552A (en) * 1947-06-12 1949-06-07 Gulf Oil Corp Addition agents for mineral oil lubricants
US2497099A (en) * 1947-06-12 1950-02-14 Gulf Oil Corp Addition agents for mineral oil lubricants and compositions containing the same
US2472517A (en) * 1947-06-20 1949-06-07 Gulf Oil Corp Addition agents for mineral oil lubricants
US2472518A (en) * 1947-07-08 1949-06-07 Gulf Oil Corp Addition agents for mineral oil lubricants
US2609305A (en) * 1947-07-24 1952-09-02 Standard Oil Dev Co Process for preparing asphalt coated aggregate
US2570402A (en) * 1947-12-22 1951-10-09 Gulf Research Development Co Antioxidants for oils and oil compositions containing the same
US2614988A (en) * 1948-03-26 1952-10-21 American Cyanamid Co Hydrocarbon oils containing salkoxymethyl - o,o' - dialkyldithiophosphates
US2841551A (en) * 1956-12-24 1958-07-01 Standard Oil Co Lubricating oil additive and oil containing the same having improved water tolerance
NL252465A (en) * 1959-06-10
US3061586A (en) * 1959-12-30 1962-10-30 Universal Oil Prod Co Stabilization of rubber
US3951830A (en) * 1973-05-02 1976-04-20 The Lubrizol Corporation Basic metal salts of sulfur- and methylene-bridged polyphenol compositions, and epoxide-reacted derivatives thereof, and lubricants containing them
US4612341A (en) * 1984-02-03 1986-09-16 Ciba-Geigy Corporation Tri- and tetra-(substituted hydroxyphenylthio) alkane and cycloalkane stabilizers
EP0273013B2 (en) * 1986-12-24 1996-07-24 Ciba-Geigy Ag Substituted phenols as stabilizers
WO2006095894A1 (en) * 2005-03-08 2006-09-14 Tokuyama Corporation Lubricant composition for bonded-abrasive polishing of magnetic head
US9574149B2 (en) * 2011-11-11 2017-02-21 Afton Chemical Corporation Fuel additive for improved performance of direct fuel injected engines

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US2020021A (en) * 1933-11-20 1935-11-05 Standard Oil Co California Extreme pressure lubricating composition
US2204620A (en) * 1934-07-26 1940-06-18 Lubri Zol Dev Corp Lubricating composition
NL52401C (en) * 1936-08-01
US2161566A (en) * 1936-08-01 1939-06-06 Socony Vacuum Oil Co Inc Lubricating oil and method of protecting same
US2211972A (en) * 1938-10-04 1940-08-20 Standard Oil Co California Compounded mineral oil
USRE22189E (en) * 1938-11-21 1942-09-29 Lubricating composition
US2208161A (en) * 1939-10-19 1940-07-16 Lubri Zol Dev Corp Lubricating composition
US2208162A (en) * 1940-02-12 1940-07-16 Lubri Zol Dev Corp Lubricating composition
US2330722A (en) * 1940-08-24 1943-09-28 Standard Oil Dev Co Condensation product and method of preparing and using same
US2249626A (en) * 1941-03-13 1941-07-15 American Cyanamid Co Lubricating composition
US2270183A (en) * 1941-03-13 1942-01-13 American Cyanamid Co Dialkylphenol sulphides
US2322376A (en) * 1941-05-13 1943-06-22 Texas Co Lubricating oil

Also Published As

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US2415833A (en) 1947-02-18
FR917266A (en) 1946-12-31

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