GB573788A - Improvements relating to the production of alcohols - Google Patents
Improvements relating to the production of alcoholsInfo
- Publication number
- GB573788A GB573788A GB407043A GB407043A GB573788A GB 573788 A GB573788 A GB 573788A GB 407043 A GB407043 A GB 407043A GB 407043 A GB407043 A GB 407043A GB 573788 A GB573788 A GB 573788A
- Authority
- GB
- United Kingdom
- Prior art keywords
- soaps
- chromium
- zinc
- fatty acids
- saturated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
In the process of reducing metallic carboxylates with hydrogen, without the addition of a catalyst, as described in Specifications 562,609 and 562,610, high yields of saturated primary alcohol are obtained by using mixtures of the corresponding soaps of zinc and chromium. Reaction conditions are as in the Specifications referred to. In an example, zinc and chromium soaps of coconut oil fatty acids are heated to about 240 DEG C. under a hydrogen pressure of 3500 p.s.i., the product acid washed and saponified, and the alcohol extracted. Soaps of other saturated or substantially saturated fatty acids of vegetable, animal, and marine fats and oils may be reacted similarly. The Specification as open to inspection under Sect. 91 comprises also the reduction of the soaps of unsaturated fatty acids to unsaturated alcohols, in an example, zinc and chromium oleates being converted to oleyl alcohol. This subject-matter does not appear in the Specification as accepted. Reference has been directed by the Comptroller to Specification 562,609 (as open to inspection under Sect. 91 of the Acts).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB407043A GB573788A (en) | 1943-03-12 | 1943-03-12 | Improvements relating to the production of alcohols |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB407043A GB573788A (en) | 1943-03-12 | 1943-03-12 | Improvements relating to the production of alcohols |
Publications (1)
Publication Number | Publication Date |
---|---|
GB573788A true GB573788A (en) | 1945-12-06 |
Family
ID=9770162
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB407043A Expired GB573788A (en) | 1943-03-12 | 1943-03-12 | Improvements relating to the production of alcohols |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB573788A (en) |
-
1943
- 1943-03-12 GB GB407043A patent/GB573788A/en not_active Expired
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