GB573175A - Improvements in or relating to the manufacture of unsaturated organic compounds - Google Patents

Improvements in or relating to the manufacture of unsaturated organic compounds

Info

Publication number
GB573175A
GB573175A GB112443A GB112443A GB573175A GB 573175 A GB573175 A GB 573175A GB 112443 A GB112443 A GB 112443A GB 112443 A GB112443 A GB 112443A GB 573175 A GB573175 A GB 573175A
Authority
GB
United Kingdom
Prior art keywords
oxygen
polymerization
relating
manufacture
organic compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB112443A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB112443A priority Critical patent/GB573175A/en
Publication of GB573175A publication Critical patent/GB573175A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/40Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents

Abstract

Methacrylic acid and its derivatives such as the esters, amide and nitrile are protected against polymerization during their production or distillation by intimate contact with air or oxygen while at temperatures at which polymerization would otherwise occur. Air or oxygen may be bubbled through the liquid or introduced into the vapour. A known inhibitor such as pyrogallol or hydroquinone may be added in small quantity. Examples describe the production from acetone cyanhydrin of methacrylic esters and methacrylic acid. The Provisional Specification states that oxygen is effective for preventing the polymerization at ordinary temperature.
GB112443A 1943-01-22 1943-01-22 Improvements in or relating to the manufacture of unsaturated organic compounds Expired GB573175A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB112443A GB573175A (en) 1943-01-22 1943-01-22 Improvements in or relating to the manufacture of unsaturated organic compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB112443A GB573175A (en) 1943-01-22 1943-01-22 Improvements in or relating to the manufacture of unsaturated organic compounds

Publications (1)

Publication Number Publication Date
GB573175A true GB573175A (en) 1945-11-09

Family

ID=9716570

Family Applications (1)

Application Number Title Priority Date Filing Date
GB112443A Expired GB573175A (en) 1943-01-22 1943-01-22 Improvements in or relating to the manufacture of unsaturated organic compounds

Country Status (1)

Country Link
GB (1) GB573175A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2810744A (en) * 1955-03-25 1957-10-22 Exxon Research Engineering Co Polymerization process for preparing lubricant additives and products
GB2179403A (en) * 1985-08-12 1987-03-04 Alh Syst Ltd Sealant delivery system
US4675436A (en) * 1985-05-23 1987-06-23 Basf Aktiengesellschaft Preparation of alkyl esters of α,β-monoolefinically unsaturated monocarboxylic acids
US4745214A (en) * 1986-06-20 1988-05-17 Norsolor Process for the preparation of an aqueous solution of unsaturated quaternary ammonium salts
EP2325166A4 (en) * 2008-08-08 2015-05-06 Showa Denko Kk Method for inhibiting polymerization of ethylenically unsaturated carboxylic acid ester compound containing isocyanate group and method for producing ethylenically unsaturated carboxylic acid ester compound containing isocyanate group

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2810744A (en) * 1955-03-25 1957-10-22 Exxon Research Engineering Co Polymerization process for preparing lubricant additives and products
US4675436A (en) * 1985-05-23 1987-06-23 Basf Aktiengesellschaft Preparation of alkyl esters of α,β-monoolefinically unsaturated monocarboxylic acids
GB2179403A (en) * 1985-08-12 1987-03-04 Alh Syst Ltd Sealant delivery system
US4745214A (en) * 1986-06-20 1988-05-17 Norsolor Process for the preparation of an aqueous solution of unsaturated quaternary ammonium salts
EP2325166A4 (en) * 2008-08-08 2015-05-06 Showa Denko Kk Method for inhibiting polymerization of ethylenically unsaturated carboxylic acid ester compound containing isocyanate group and method for producing ethylenically unsaturated carboxylic acid ester compound containing isocyanate group

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