GB569470A - Method of producing acetic acid esters of cyanohydrins - Google Patents
Method of producing acetic acid esters of cyanohydrinsInfo
- Publication number
- GB569470A GB569470A GB952442A GB952442A GB569470A GB 569470 A GB569470 A GB 569470A GB 952442 A GB952442 A GB 952442A GB 952442 A GB952442 A GB 952442A GB 569470 A GB569470 A GB 569470A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ketene
- acetic acid
- cyanohydrins
- acid esters
- cyanhydrins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Ketene is used to acetylate aliphatic cyanhydrins, e.g cyanhydrins of acetone, crotonaldehyde and trimethylacetaldehyde. In examples: (1) ketene is passed through three vessels in series charged with acetaldehydecyanhydrin; when the contents of the first vessel ceases to evolve heat, it is distilled to give the acetic acid derivative; (2) ketene obtained by the pyrolysis of acetone is passed into a benzene solution of acetonecyanhydrin; the product, a -acetoxyisobutyric acid nitrile is obtained by fractional distillation; (3) ethylene and propylenecyanhydrins are similarly treated with crude ketene. The acetylated products on heating to remove acetic acid give the corresponding unsaturated derivative.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB952442A GB569470A (en) | 1942-07-08 | 1942-07-08 | Method of producing acetic acid esters of cyanohydrins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB952442A GB569470A (en) | 1942-07-08 | 1942-07-08 | Method of producing acetic acid esters of cyanohydrins |
Publications (1)
Publication Number | Publication Date |
---|---|
GB569470A true GB569470A (en) | 1945-05-25 |
Family
ID=9873644
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB952442A Expired GB569470A (en) | 1942-07-08 | 1942-07-08 | Method of producing acetic acid esters of cyanohydrins |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB569470A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1000371B (en) * | 1952-03-07 | 1957-01-10 | Wacker Chemie Gmbh | Process for the preparation of ª ‡ -Acetoxycarbonsaeurenitrilen |
-
1942
- 1942-07-08 GB GB952442A patent/GB569470A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1000371B (en) * | 1952-03-07 | 1957-01-10 | Wacker Chemie Gmbh | Process for the preparation of ª ‡ -Acetoxycarbonsaeurenitrilen |
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