GB540370A - A process for carrying out oxidation reactions - Google Patents

A process for carrying out oxidation reactions

Info

Publication number
GB540370A
GB540370A GB2503/40A GB250340A GB540370A GB 540370 A GB540370 A GB 540370A GB 2503/40 A GB2503/40 A GB 2503/40A GB 250340 A GB250340 A GB 250340A GB 540370 A GB540370 A GB 540370A
Authority
GB
United Kingdom
Prior art keywords
peroxides
peroxide
oxidation reactions
hydrocarbons
cetene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2503/40A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Priority to GB2503/40A priority Critical patent/GB540370A/en
Publication of GB540370A publication Critical patent/GB540370A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/20—Peroxy compounds the —O—O— group being bound to a carbon atom further substituted by singly—bound oxygen atoms
    • C07C409/22—Peroxy compounds the —O—O— group being bound to a carbon atom further substituted by singly—bound oxygen atoms having two —O—O— groups bound to the carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/24—Peroxy compounds the —O—O— group being bound between a >C=O group and hydrogen, i.e. peroxy acids
    • C07C409/30—Peroxy compounds the —O—O— group being bound between a >C=O group and hydrogen, i.e. peroxy acids a >C=O group being bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/32—Peroxy compounds the —O—O— group being bound between two >C=O groups
    • C07C409/34—Peroxy compounds the —O—O— group being bound between two >C=O groups both belonging to carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

540,370. Oxidation reactions; hydrocarbon peroxides. FIFE, J. G. (Naamlooze Vennootschap de Bataafsche Petroleum Maatschappij). Feb. 9, 1940, No. 2503. [Classes 1 (i) and 1 (iii)] [Also in Group IV] A product containing hydrocarbon peroxides, obtained by the partial combustion of hydrocarbons is used as an oxidizing agent. Suitable hydrocarbons are aliphatic or cycloaliphatic with not more than 10 carbon atoms. They may be oxidized in vapour phase in admixture with a limited amount of oxygen (8-45 per cent. of the mixture) with or without a catalyst, at temperatures of 250-500‹ C. with a contact time of 3-50 seconds, and usually at atmospheric pressure. Oxidation reactions for which the products may be employed include the conversions of alkenes to oxides, glycols, aldehydes etc.; of aldehydes to acids, of ketones to ketone peroxides, of acyl chlorides to acyl peroxides, of aromatic hydrocarbons to phenols, of borates to perborates, of magnesium, barium, and zinc oxides into peroxides. Examples illustrate the application of the invention to the following conversions:- ethylene to ethylene glycol, cetene to cetene glycol, cyclopentene to glutaric dialdehyde, benzene to tribromphenol and pyrocatechin, allyl alcohol to glycerine, acetone to acetone peroxide, butanone to butanone peroxide, benzoyl chloride to benzoyl peroxide, sodium borate to perborate, and zinc sulphate to peroxide.
GB2503/40A 1940-02-09 1940-02-09 A process for carrying out oxidation reactions Expired GB540370A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2503/40A GB540370A (en) 1940-02-09 1940-02-09 A process for carrying out oxidation reactions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2503/40A GB540370A (en) 1940-02-09 1940-02-09 A process for carrying out oxidation reactions

Publications (1)

Publication Number Publication Date
GB540370A true GB540370A (en) 1941-10-15

Family

ID=9740708

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2503/40A Expired GB540370A (en) 1940-02-09 1940-02-09 A process for carrying out oxidation reactions

Country Status (1)

Country Link
GB (1) GB540370A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2634294A (en) * 1950-04-08 1953-04-07 Monsanto Chemicals Preparation of aromatic keto alcohols
DE890943C (en) * 1943-01-30 1953-09-24 Basf Ag Process for the production of polyhydric alcohols
US2671111A (en) * 1950-04-08 1954-03-02 Monsanto Chemicals Preparation of styrene derivatives
DE921446C (en) * 1944-07-16 1954-12-20 Basf Ag Process for the production of saturated polyhydric alcohols
US3076852A (en) * 1958-08-04 1963-02-05 Wacker Chemie Gmbh Process for manufacturing organic peroxide compounds
EP0331590A1 (en) * 1988-03-03 1989-09-06 Rhone-Poulenc Chimie Process for the catalytic oxidation of alkanes and aralkyl hydrocarbons into a mixture of alcohols and ketones

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE890943C (en) * 1943-01-30 1953-09-24 Basf Ag Process for the production of polyhydric alcohols
DE921446C (en) * 1944-07-16 1954-12-20 Basf Ag Process for the production of saturated polyhydric alcohols
US2634294A (en) * 1950-04-08 1953-04-07 Monsanto Chemicals Preparation of aromatic keto alcohols
US2671111A (en) * 1950-04-08 1954-03-02 Monsanto Chemicals Preparation of styrene derivatives
US3076852A (en) * 1958-08-04 1963-02-05 Wacker Chemie Gmbh Process for manufacturing organic peroxide compounds
EP0331590A1 (en) * 1988-03-03 1989-09-06 Rhone-Poulenc Chimie Process for the catalytic oxidation of alkanes and aralkyl hydrocarbons into a mixture of alcohols and ketones
FR2628101A1 (en) * 1988-03-03 1989-09-08 Rhone Poulenc Chimie PROCESS FOR THE CATALYTIC OXIDATION OF ALKANES IN MIXTURES OF ALCOHOLS AND KETONES
US4918238A (en) * 1988-03-03 1990-04-17 Rhone-Poulenc Chimie Catalytic oxidation of alkanes into alcohol/ketone mixtures

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