GB1151287A - A Method of Continous Oxidation of Organic Compounds - Google Patents

A Method of Continous Oxidation of Organic Compounds

Info

Publication number
GB1151287A
GB1151287A GB11185/67A GB1118567A GB1151287A GB 1151287 A GB1151287 A GB 1151287A GB 11185/67 A GB11185/67 A GB 11185/67A GB 1118567 A GB1118567 A GB 1118567A GB 1151287 A GB1151287 A GB 1151287A
Authority
GB
United Kingdom
Prior art keywords
oxidation
polar solvent
oxidation products
reactor
solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB11185/67A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Charbonnages de France CDF
Original Assignee
Charbonnages de France CDF
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Charbonnages de France CDF filed Critical Charbonnages de France CDF
Publication of GB1151287A publication Critical patent/GB1151287A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C07C407/003—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C07C409/08—Compounds containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C07C409/08—Compounds containing six-membered aromatic rings
    • C07C409/10—Cumene hydroperoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/14—All rings being cycloaliphatic
    • C07C2602/26—All rings being cycloaliphatic the ring system containing ten carbon atoms
    • C07C2602/28—Hydrogenated naphthalenes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,151,287. Continuous oxidation of hydrocarbons. CHARBONNAGES DE FRANCE. 9 March, 1967 [11 March, 1966], No. 11185/67. Heading B1X [Also in Division C2] Hydrocarbons are oxidised by charging them continuously into a reactor 1 in the liquid phase, and oxidising them with a gas containing free oxygen; continuously removing a portion of the reaction medium such that there always remains in the reactor a quantity of oxidation product permitting the development of the reaction at a satisfactory rate; subjecting the removed fraction to at least one extraction in extractor 12 with a polar solvent which is a good solvent for the oxidation products and only slightly miscible or rendered slightly miscible with the starting hydrocarbon, with or without a purification by washing with an alkaline solution in washer 3 and with water in washer 7; separating the oxidation products from the polar solvent and re-cycling the hydrocarbon by line 14 to reactor 1. The extracted oxidation products pass by line 15 to evaporator 17 for removal of solvent. In Examples, methylcyclohexane, cyclohexane, decalin, a mixture of decalin and alkyl-decalins, cyclohexyl benzene, isopropyl-naphthalene, cumene and hexadecane are oxidised to give principally hydroperoxides or peroxides. Water or aqueous methanol is used as the) polar solvent. The oxidation products are preferably separated from the polar solvent by a rapid distillation.
GB11185/67A 1966-03-11 1967-03-09 A Method of Continous Oxidation of Organic Compounds Expired GB1151287A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR53182A FR1506296A (en) 1966-03-11 1966-03-11 Continuous oxidation process of organic compounds

Publications (1)

Publication Number Publication Date
GB1151287A true GB1151287A (en) 1969-05-07

Family

ID=8603604

Family Applications (1)

Application Number Title Priority Date Filing Date
GB11185/67A Expired GB1151287A (en) 1966-03-11 1967-03-09 A Method of Continous Oxidation of Organic Compounds

Country Status (7)

Country Link
BE (1) BE695372A (en)
CS (1) CS176107B2 (en)
DE (1) DE1618217B2 (en)
FR (1) FR1506296A (en)
GB (1) GB1151287A (en)
LU (1) LU53163A1 (en)
NL (1) NL6702847A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4120902A (en) * 1977-03-07 1978-10-17 Phillips Petroleum Company Oxidation product recovery
US4160000A (en) * 1978-03-13 1979-07-03 Phillips Petroleum Company Extraction of hydroperoxides
WO2020136335A1 (en) * 2018-12-26 2020-07-02 Arkema France Purification of alkyl hydroperoxide by distillation in the presence of methanol and water

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5343941B2 (en) * 1975-01-31 1978-11-24
NL9201269A (en) * 1992-07-15 1994-02-01 Dsm Nv PROCESS FOR THE PREPARATION OF CYCLOHEXYL HYDROPEROXIDE.

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4120902A (en) * 1977-03-07 1978-10-17 Phillips Petroleum Company Oxidation product recovery
US4160000A (en) * 1978-03-13 1979-07-03 Phillips Petroleum Company Extraction of hydroperoxides
WO2020136335A1 (en) * 2018-12-26 2020-07-02 Arkema France Purification of alkyl hydroperoxide by distillation in the presence of methanol and water
FR3091283A1 (en) * 2018-12-26 2020-07-03 Arkema France PURIFICATION OF ALKYL HYDROPEROXIDE BY DISTILLATION IN THE PRESENCE OF METHANOL AND WATER

Also Published As

Publication number Publication date
CS176107B2 (en) 1977-06-30
LU53163A1 (en) 1967-09-11
BE695372A (en) 1967-09-11
FR1506296A (en) 1967-12-22
DE1618217A1 (en) 1970-12-10
DE1618217B2 (en) 1977-09-08
NL6702847A (en) 1967-09-12

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Legal Events

Date Code Title Description
PS Patent sealed
435 Patent endorsed 'licences of right' on the date specified (sect. 35/1949)
PCNP Patent ceased through non-payment of renewal fee