GB499742A - Manufacture of a 1-amino-2-hydroxynaphthalenesulphonic-3-carboxylic acid, or of a corresponding 2-hydroxynaphthalenesulphonic-3-carboxylic acid - Google Patents
Manufacture of a 1-amino-2-hydroxynaphthalenesulphonic-3-carboxylic acid, or of a corresponding 2-hydroxynaphthalenesulphonic-3-carboxylic acidInfo
- Publication number
- GB499742A GB499742A GB30505/38A GB3050538A GB499742A GB 499742 A GB499742 A GB 499742A GB 30505/38 A GB30505/38 A GB 30505/38A GB 3050538 A GB3050538 A GB 3050538A GB 499742 A GB499742 A GB 499742A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carboxylic acid
- hydroxynaphthalenesulphonic
- amino
- manufacture
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- VCJJAJXTFPNHON-UHFFFAOYSA-N 4-amino-3-hydroxynaphthalene-2-carboxylic acid Chemical compound C1=CC=C2C(N)=C(O)C(C(O)=O)=CC2=C1 VCJJAJXTFPNHON-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 abstract 1
- 150000008049 diazo compounds Chemical class 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C309/45—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing nitrogen atoms, not being part of nitro or nitroso groups, bound to the carbon skeleton
- C07C309/49—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing nitrogen atoms, not being part of nitro or nitroso groups, bound to the carbon skeleton the carbon skeleton being further substituted by singly-bound oxygen atoms
- C07C309/50—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing nitrogen atoms, not being part of nitro or nitroso groups, bound to the carbon skeleton the carbon skeleton being further substituted by singly-bound oxygen atoms having at least one of the sulfo groups bound to a carbon atom of a six-membered aromatic ring being part of a condensed ring system
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A 1-amino-2-hydroxynaphthalenesulphonic-3-carboxylic acid is prepared by sulphonating 1 - amino - 2 - hydroxynaphthalene - 3 - carboxylic acid. The corresponding 2-hydroxynaphthalenesulphonic-3-carboxylic acid is obtained by eliminating the amino group from the 1-amino-2-hydroxynaphthalenesulphonic - 3 - carboxylic acid, e.g. by diazotizing it in neutral solution, and heating the separated diazo compound with ethyl alcohol in the presence of copper and copper sulphate. The new compounds are useful as intermediates for dyes.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH499742X | 1937-10-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB499742A true GB499742A (en) | 1939-01-27 |
Family
ID=4516874
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB30505/38A Expired GB499742A (en) | 1937-10-22 | 1938-10-21 | Manufacture of a 1-amino-2-hydroxynaphthalenesulphonic-3-carboxylic acid, or of a corresponding 2-hydroxynaphthalenesulphonic-3-carboxylic acid |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB499742A (en) |
-
1938
- 1938-10-21 GB GB30505/38A patent/GB499742A/en not_active Expired
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