GB493293A - Manufacture of chromable dyestuffs of the triarylmethane series - Google Patents
Manufacture of chromable dyestuffs of the triarylmethane seriesInfo
- Publication number
- GB493293A GB493293A GB959737A GB959737A GB493293A GB 493293 A GB493293 A GB 493293A GB 959737 A GB959737 A GB 959737A GB 959737 A GB959737 A GB 959737A GB 493293 A GB493293 A GB 493293A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- condensing
- pyrogallol
- hydroxytrimellitic
- condensed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B11/00—Diaryl- or thriarylmethane dyes
- C09B11/04—Diaryl- or thriarylmethane dyes derived from triarylmethanes, i.e. central C-atom is substituted by amino, cyano, alkyl
- C09B11/10—Amino derivatives of triarylmethanes
- C09B11/24—Phthaleins containing amino groups ; Phthalanes; Fluoranes; Phthalides; Rhodamine dyes; Phthaleins having heterocyclic aryl rings; Lactone or lactame forms of triarylmethane dyes
- C09B11/245—Phthaleins having both OH and amino substituent(s) on aryl ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Triarylmethane dyes capable of being chromed are made by condensing a benzoylbenzoic acid, obtainable by condensing 1 mol. of a hydroxytrimellitic acid or the anhydride thereof with 1 mol. of an N-substituted m-aminophenol, with an aromatic m-dihydroxy compound containing, in a position ortho to one hydroxyl group and para to the other, a hydrogen atom or a sulpho group, or with a monoalkylether thereof, with the exception of resorcylic acid. The products may be halogenated. In examples: (a) 41-diethylamino - 21 - hydroxy - 1 - benzoyl - o - hydroxy-carboxy-2-benzoic acid (obtainable by condensing m-diethylaminophenol and 5-hydroxytrimellitic anhydride) is dissolved in sulphuric acid and condensed with (1) pyrogallol, (b) 2-nitroresorcinol, (c) potassium resorcinol-4 : 6-disulphonate, or (d) resorcinol, (2) the corresponding dimethyl compound is condensed with pyrogallol or 4-chlorresorcinol; (3) the corresponding o-xylidino compound (made by condensing 3 - hydroxy - 21 : 31 - dimethyldiphenylamine with 5-hydroxytrimellitic anhydride) is condensed with pyrogallol, and (4) the product of example 1(d) is brominated in alcohol. The products dye animal fibres in an acid bath yellowish and bluish red and brown tints, which when after-chromed have good properties of fastness. They may also be used for chrome printing on cotton or artificial silk.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB959737A GB493293A (en) | 1937-04-05 | 1937-04-05 | Manufacture of chromable dyestuffs of the triarylmethane series |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB959737A GB493293A (en) | 1937-04-05 | 1937-04-05 | Manufacture of chromable dyestuffs of the triarylmethane series |
Publications (1)
Publication Number | Publication Date |
---|---|
GB493293A true GB493293A (en) | 1938-10-05 |
Family
ID=9875047
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB959737A Expired GB493293A (en) | 1937-04-05 | 1937-04-05 | Manufacture of chromable dyestuffs of the triarylmethane series |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB493293A (en) |
-
1937
- 1937-04-05 GB GB959737A patent/GB493293A/en not_active Expired
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