GB461614A - Improvements in the treatment of textile and other fibrous materials - Google Patents

Improvements in the treatment of textile and other fibrous materials

Info

Publication number
GB461614A
GB461614A GB2021635A GB2021635A GB461614A GB 461614 A GB461614 A GB 461614A GB 2021635 A GB2021635 A GB 2021635A GB 2021635 A GB2021635 A GB 2021635A GB 461614 A GB461614 A GB 461614A
Authority
GB
United Kingdom
Prior art keywords
thionyl
group
octodecyl
ethanesulphonate
sodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2021635A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to GB2021635A priority Critical patent/GB461614A/en
Priority to FR809373D priority patent/FR809373A/en
Publication of GB461614A publication Critical patent/GB461614A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/002Surface-active compounds containing sulfur

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)
  • Paper (AREA)

Abstract

Textiles, leather, paper, wood and other fibrous materials are treated with compounds having the formul RSOR1Y or RSO2R1Y in which R is an aliphatic radicle with at least 6 carbon atoms or an isocyclic or heterocyclic radicle, R1 is an aliphatic radicle containing at the most 7 carbon atoms and Y is a carboxylic acid group, a polybasic mineral acid group, a polyether group, an amino group or a quaternary ammonium group. The polybasic mineral acid group may be attached to R1 by means of carbon, oxygen, sulphur or nitrogen atoms, but in the case of sulphones containing a sulphonic group, the latter must always be attached directly to carbon. The sulphoxides and sulphones have wetting, cleansing, foaming, dispersing, penetrating, levelling and softening properties. They cause a deepening of the shades when used in printing, especially with acid dyestuffs and they have a high levelling action with viscose. Dispersions of oils, fats, waxes, e.g. tallow, carnauba or paraffin wax containing the said compounds are useful in the textile industry. Dispersions of rubber and dyestuffs are mentioned. The compounds may be used in association with sodium carbonate, Glauber's salt, perborates, ortho, pyro and meta phosphates, sodium acetate, sodium formate, aluminium formate, acids, mucilages, gums, glue, cyclohexanone, trichlorethylene, benzylalcohol, and glycol mono alkyl and arylethers. In examples: (1) cross spools are treated in a bath containing sodium carbonate and the sodium salt of octodecyl-18-thionyl-2-ethanesulphonic acid; (2) the salt of the corresponding oleyl thionyl sulphonic acid is used in dyeing wool with Anthraquinone blue SR, wool fast yellow 3G or Supramine red B; (3) sodium octodecyl- and oleyl-18-thionyl-2-ethanesulphonate, octodecyl - 18 - sulphuryl - 2 - ethanesulphonate, octodecyl - 18 - sulphuryl - 2 - ethylamino - 2<1> - ethanesulphonate, octodecyl-18-thionyl-2-ethylamino-2<1>-ethanesulphonate and octodecyl - 18 - thionyl - 2 - ethylamino - N - methyl-2<1>-ethanesulphonate are used for softening viscose piece goods; (4) sodium octadecyl-18-thionyl (or sulphuryl)-2-ethanesulphonate, oleyl - 18 - thionyl - 2 - ethylamino - 2<1> - ethane - N - methyl-1<1>-sulphonate and oleyl-18-thionyl-2-ethyl-1-mercapto propionate are used for washing white goods. Sulphones and sulphoxides containing the phenyl, naphthyl, benzyl, ethylphenyl, cyclohexyl, tetrahydronaphthyl, methylnaphthyl, benzthiazole, benzimidazole, pyridine, quinoline and piperidine radicles are specified and halogen atoms and hydroxyl, hydroxyalkyl, nitro, amino, nitrile and sulphamide groups may be present. The group Y may be a residue obtained by treating a reactive hydrogen atom of R1, e.g. a hydroxy, carboxylic, amino or mercapto hydrogen, with ethylene oxide. When the sulphoxides or sulphones contain halogen, the group Y may be introduced by treating with alkali sulphites, mono or diamines, aminocarboxylic acids, hydroxy or mercaptocarboxylic acids or amino, hydroxy or mercaptosulphonic acids. Specifications 380,431, 380,851, 404,931, 422,937, 444,501, 446,992; 450,559, [Group III], 453,443, and 454,675 are referred to. According to the Provisional Specification, the radicle R1 may contain eight carbon atoms. Specifications 442,525, 453,780, and 454,728 also are referred to.ALSO:Sulphoxides and sulphones having the following formulae are stated to have dispersing properties: RSOR1Y or RSO2R1Y in which R is an aliphatic radicle with at least 6 carbon atoms or an isocyclic or heterocyclic radicle, R1 is an aliphatic radicle containing at the most 7 carbon atoms and Y is carboxylic acid group, a polybasic mineral acid group, a polyether group, an amino group or a quaternary ammonium group. The polybasic mineral acid group may be attached to R1 by means of carbon, oxygen, sulphur or nitrogen atoms, but in the case of sulphones containing a sulphonic group, the latter must be attached to carbon. Dispersions of oils, fats, waxes, e.g. tallow, carnauba or paraffin wax containing the said compounds are useful in the textile industry. Dispersions of rubber and dyestuffs are mentioned. The compounds may be used in association with sodium carbonate, Glauber's salt, perborates, ortho pyro and meta phosphates, sodium acetate, sodium formate, aluminium formate, acids, mucilages, gums, glue, cyclohexanone, trichlorethylene, benzyl alcohol, and glycolmonoalkyl and aryl ethers. In examples, sodium octodecyl-18-thionyl-2-ethane sulphonate, the corresponding oleyl thionyl-sulphonate, sodium octodecyl and oleyl-18-thionyl-2-ethanesulphonate, octodecyl-18-sul-phuryl-2-ethanesulphonate, octodecyl-18-sul-phuryl - 2 - ethylamino - 2<1> - ethanesulphonate, octodecyl - 18 - thionyl - 2 - ethylamino - 2<1>-ethanesulphonate, octodecyl - 18 - thionyl-2 - ethylamino-N - methyl - 2<1> - ethanesul-phonate, sodium octadecyl-18-thionyl (or sulphuryl) - 2 - ethanesulphonate, oleyl - 18 - thionyl-2-ethylamino-2<1>-ethane-N-methyl-1<1> -sulphonate and oleyl-18-thionyl-2-ethyl-1-mercaptopropionate are used. Sulphones and sulphoxides containing the phenyl, naphthyl, benzyl, ethylphenyl, cyclohexyl, tetrahydronaphthyl, methylnaphthyl, benzthiazole, benzimidazole, pyridine, quinoline and piperidine radicles are specified, and halogen atoms and hydroxyl, hydroxyalkyl, nitro, amino, nitrile and sulphamide groups may be present. The group Y may be a residue obtained by treating a reactive hydrogen atom of R1, e.g. a hydroxy, carboxylic, amino or mercapto hydrogen, with ethylene oxide. When the sulphoxides or sulphones contain halogen, the group Y may be introduced by treating with alkali sulphites, mono or diamines, aminocarboxylic acids, hydroxy or mercaptocarboxylic acids or amino, hydroxy or mercaptosulphonic acids. Specifications 380,431, 380,851, 404,931, 422,937, 442,525, 444,501, 446,992, [all in Group IV], 450,559; 453,443 and 454,675, [both in Group IV], are referred to.
GB2021635A 1935-07-15 1935-07-15 Improvements in the treatment of textile and other fibrous materials Expired GB461614A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB2021635A GB461614A (en) 1935-07-15 1935-07-15 Improvements in the treatment of textile and other fibrous materials
FR809373D FR809373A (en) 1935-07-15 1936-06-26 Wetting agents, detergents, dispersants and others

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2021635A GB461614A (en) 1935-07-15 1935-07-15 Improvements in the treatment of textile and other fibrous materials

Publications (1)

Publication Number Publication Date
GB461614A true GB461614A (en) 1937-02-15

Family

ID=10142312

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2021635A Expired GB461614A (en) 1935-07-15 1935-07-15 Improvements in the treatment of textile and other fibrous materials

Country Status (2)

Country Link
FR (1) FR809373A (en)
GB (1) GB461614A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2864866A (en) * 1956-12-28 1958-12-16 Phillips Petroleum Co Process for preparing surface-active materials
CA1057654A (en) * 1975-03-18 1979-07-03 Pharma-Vertrieb Ag Germicidal agent

Also Published As

Publication number Publication date
FR809373A (en) 1937-03-02

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