GB456565A - Process for the manufacture of organic chlorine and bromine derivatives - Google Patents
Process for the manufacture of organic chlorine and bromine derivativesInfo
- Publication number
- GB456565A GB456565A GB10161/36A GB1016136A GB456565A GB 456565 A GB456565 A GB 456565A GB 10161/36 A GB10161/36 A GB 10161/36A GB 1016136 A GB1016136 A GB 1016136A GB 456565 A GB456565 A GB 456565A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acids
- yield
- bromine
- bromide
- yielding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Organic chlorine or bromine compounds are produced by reacting chlorine or bromine with salts of organic carboxylic acids with metals, particularly with metals of the first, second, and third groups of the periodic system. Thus, simple acids yield alkyl halides; a -hydroxy acids yield hydrohalogen compounds of the aldehydes; hydroxy acids in which the hydroxyl is not in the a -position yield hydroxyalkyl halides; polyhydroxy acids with one hydroxyl in the a -position yield hydrohalogen compounds of hydroxy-aldehydes; a -halogen fatty acids yield 1,1-dihalogen hydrocarbons; dicarboxylic acids yield dihalogen hydrocarbons; ester acids yield halogen fatty acid esters; a -keto acids yield acid halides; cycloalkane mono- and polycarboxylic acids yield cycloalkyl halides; and amino acids (other than a -amino-acids) yield halogen alkylamines; in each case with the liberation of carbon dioxide. In examples, bromine is reacted with the silver salts of palmitic, lauric, acetic, coconut fatty acids, hydroxy-palmitic, a -brom-stearic, 9--10 dichlor octadecanic (from chlorinated oleic acid) sebacic, sebacic monoethyl ester, pyroracemic and mandelic acids, yielding pentadecyl, undecyl, methyl and mixed alkyl bromides, an aldehyde hydrobromide, dibromheptadecane, 1-brom-8,9-dichlor heptadecane, 1 - 8 - dibrom octane, 9-brom-nonylic acid ethyl ester, acetyl bromide, and benzaldehyde hydrobromide respectively; chlorine is reacted with silver stearate yielding heptadecyl chloride; bromine is reacted with mercurous caprylate and with mercuric palmitate yielding heptyl bromide and pentadecyl bromide (as pentadecyl pyridinium bromide) respectively; and chlorine or bromine is reacted with thallium oenanthate yielding hexyl chloride or bromide. Diluents such as air, carbon tetrachloride, chloroform or ether may be employed.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE456565X | 1935-04-08 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB456565A true GB456565A (en) | 1936-11-11 |
Family
ID=6539192
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB10161/36A Expired GB456565A (en) | 1935-04-08 | 1936-04-06 | Process for the manufacture of organic chlorine and bromine derivatives |
Country Status (4)
Country | Link |
---|---|
US (1) | US2176181A (en) |
FR (1) | FR803941A (en) |
GB (1) | GB456565A (en) |
NL (1) | NL43016C (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2590247A (en) * | 1948-08-28 | 1952-03-25 | Celanese Corp | Method of brominating 1-amino-2-sulfo-anthraquinone |
US2554219A (en) * | 1949-08-22 | 1951-05-22 | Minnesota Mining & Mfg | Method of making fluorocarbon mono-iodides |
US2678953A (en) * | 1950-10-14 | 1954-05-18 | Douglas Aircraft Co Inc | Method of making fluorinated organic bromides and resulting new chemical compounds |
US2858341A (en) * | 1951-03-31 | 1958-10-28 | Monsanto Chemicals | Producing bis-(dichlormethyl) sulfone |
US3012072A (en) * | 1957-07-02 | 1961-12-05 | Pennsalt Chemicals Corp | Substitution products of polyfluorolefins and processes for the preparation thereof |
US2833831A (en) * | 1954-07-26 | 1958-05-06 | Haszeldine Robert Neville | Preparation of perfluorodienes |
US2935536A (en) * | 1956-01-20 | 1960-05-03 | Goodrich Gulf Chem Inc | Production of organo-halides |
US3399179A (en) * | 1963-01-03 | 1968-08-27 | Aerojet General Co | Decarboxylation of organic carboxylic acids and acid salts with fluorine to form organic fluorine compounds |
US4222968A (en) * | 1979-06-08 | 1980-09-16 | Schack Carl J | Method for synthesizing fluorocarbon halides |
US10923723B1 (en) | 2017-05-11 | 2021-02-16 | Richard Carl Auchterlonie | Electro-conductive polymers of halogenated para-aminophenol, and electrochemical cells employing same |
-
0
- NL NL43016D patent/NL43016C/xx active
-
1936
- 1936-04-02 US US72446A patent/US2176181A/en not_active Expired - Lifetime
- 1936-04-02 FR FR803941D patent/FR803941A/en not_active Expired
- 1936-04-06 GB GB10161/36A patent/GB456565A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
NL43016C (en) | 1900-01-01 |
US2176181A (en) | 1939-10-17 |
FR803941A (en) | 1936-10-12 |
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