GB443559A - Improvements in the manufacture and production of valuable watersoluble condensationproducts suitable as assistants in the textile and related industries - Google Patents

Improvements in the manufacture and production of valuable watersoluble condensationproducts suitable as assistants in the textile and related industries

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Publication number
GB443559A
GB443559A GB1775934A GB1775934A GB443559A GB 443559 A GB443559 A GB 443559A GB 1775934 A GB1775934 A GB 1775934A GB 1775934 A GB1775934 A GB 1775934A GB 443559 A GB443559 A GB 443559A
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United Kingdom
Prior art keywords
treated
products
starting materials
carbon atoms
alkylene oxides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1775934A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to GB1775934A priority Critical patent/GB443559A/en
Publication of GB443559A publication Critical patent/GB443559A/en
Expired legal-status Critical Current

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  • Paper (AREA)

Abstract

Products stated to be useful in the textile, leather, paper, lacquer, cosmetic, pharmaceutical, and rubber industries as wetting, washing, dispersing, levelling and softening agents are obtained by treating aliphatic compounds containing at least five carbon atoms and at least one hydroxy group with (a) dihydric alcohols free from ether linkages and containing at least three carbon atoms or their corresponding alkylene oxides, and (b) polyhydric alcohols containing from 2--4 carbon atoms and having one hydroxy group attached to each carbon atom or their corresponding alkylene oxides, in either sequence. The solubility of the products may be increased, if necessary by treatment with oxygen containing polybasic mineral acids. In a modification, the same starting materials are treated with at least three molecular proportions of the said dihydric alcohols or alkylene oxides and the condensation products then treated with polybasic mineral acids, e.g. sulphuric acid, sulphur trioxide or chlorsulphonic acid. In examples : (1) cetyl alcohol is treated first with propylene oxide and then with large excess of ethylene oxide ; (2) a product similar to that obtained according to example 1 is sulphonated ; (3) dodecyl alcohol is treated first with propylene oxide and then with ethylene oxide ; the product may be used for the preparation of pastes and creams containing petroleum jelly, soft paraffin wax, paraffin oil and wool fat ; (4) a condensation product obtained from coconut oil and monoethanolamine is treated with propylene oxide and ethylene oxide. The use of epichlorhydrin and 1 : 2-propylene-oxide is mentioned and the following starting materials : amyl, octyl and oleyl alcohols, montanol and 7 : 18-octodecanediol. Halogen atoms and nitro groups may be present in the starting materials. The products may be used in association with soap, turkey red oil, alkylated aromatic sulphonic acids, organic solvents, cyclohexanol, cyclohexanone, benzylalcohol, carbon tetrachloride, Glauber's salt, alkali phosphates, water glass, borates, sodium hypochlorite, sodium hydrosulphite, mucilage, glue, starch and ethyleneoxide polymerization products. According to the Provisional Specification, low molecular alcohols, cyclohexanol, benzylalcohol and aromatic hydroxy compounds may be used as starting materials, e.g. propyl alcohol, cresols, naphthols and hydroxyanthracenes. Instead of the dihydric alcohols, alkylene oxides containing at least three carbon atoms and compounds acting in the same manner, e.g. glycide may be used. Specification 443,632 is referred to.ALSO:Products stated to be useful in the textile, leather, paper, lacquer, cosmetic, pharmaceutical, and rubber industries as dispersing agents are obtained by treating aliphatic compounds containing at least five carbon atoms and at least one hydroxy group with (a) dihydric alcohols free from ether linkages and containing at least three carbon atoms or their corresponding alkylene oxides and (b) polyhydric alcohols containing from 2--4 carbon atoms and having one hydroxy group attached to each carbon atom or their corresponding alkylene oxides, in either sequence. The solubility of the products may be increased, if necessary by treatment with oxygen containing polybasic mineral acids. In a modification, the same starting materials are treated with three molecular proportions of the said dihydric alcohols or alkylene oxides and the condensation products then treated with polybasic mineral acids, e.g. sulphuric acid, sulphur trioxide or chlorsulphonic acid. In examples: (1) cetyl alcohol is treated first with propylene oxide and then with large excess of ethylene oxide; (2) a product similar to that obtained according to example 1 is sulphonated; (3) dodecyl alcohol is treated first with propylene oxide and then with ethylene oxide; the product may be used for the preparation of pastes and creams containing petroleum jelly, soft paraffin wax, paraffin oil and woolfat; (4) a condensation product obtained from coconut oil and monoethanolamine is treated with propylene oxide and ethylene oxide. The use of epichlorhydrin and 1 : 2-propylene-oxide is mentioned and the following starting materials: amyl, octyl and oleyl alcohols, montanol and 7 : 18-octodecanediol. Halogen atoms and nitro groups may be present in the starting materials. The products may be used in association with soap, turkey red oil, alkylated aromatic sulphonic acids, organic solvents, cyclohexanol, cyclohexanone, benzylalcohol, carbon tetrachloride, Glauber's salt, alkali phosphates, water glass, borates, sodium hypochlorite, sodium hydrosulphite, mucilage, glue, starch and ethylene oxide polymerization products. According to the Provisional Specification, low molecular alcohols, cyclohexanol, benzylalcohol and aromatic hydroxy compounds may be used as starting materials, e.g. propyl alcohol, cresols, naphthols and hydroxyanthracenes. Instead of the dihydric alcohols, alkylene oxides containing at least three carbon atoms and compounds acting in the same manner, e.g. glycide may be used. Specification 443,632 is referred to.
GB1775934A 1934-06-15 1934-06-15 Improvements in the manufacture and production of valuable watersoluble condensationproducts suitable as assistants in the textile and related industries Expired GB443559A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1775934A GB443559A (en) 1934-06-15 1934-06-15 Improvements in the manufacture and production of valuable watersoluble condensationproducts suitable as assistants in the textile and related industries

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1775934A GB443559A (en) 1934-06-15 1934-06-15 Improvements in the manufacture and production of valuable watersoluble condensationproducts suitable as assistants in the textile and related industries

Publications (1)

Publication Number Publication Date
GB443559A true GB443559A (en) 1936-02-17

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Family Applications (1)

Application Number Title Priority Date Filing Date
GB1775934A Expired GB443559A (en) 1934-06-15 1934-06-15 Improvements in the manufacture and production of valuable watersoluble condensationproducts suitable as assistants in the textile and related industries

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GB (1) GB443559A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2988511A (en) * 1955-03-31 1961-06-13 Mills Victor Nonsmearing detergent bar
GB2221683A (en) * 1985-06-14 1990-02-14 Oreal New alcohol compounds

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2988511A (en) * 1955-03-31 1961-06-13 Mills Victor Nonsmearing detergent bar
GB2221683A (en) * 1985-06-14 1990-02-14 Oreal New alcohol compounds
US5008406A (en) * 1985-06-14 1991-04-16 L'oreal Hemiacetal compounds and the applications thereof
US5164488A (en) * 1985-06-14 1992-11-17 L'oreal New hemiacetal compounds and the applications thereof

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