GB439890A - Improvements in dyeing animal fibres - Google Patents

Improvements in dyeing animal fibres

Info

Publication number
GB439890A
GB439890A GB17288/34A GB1728834A GB439890A GB 439890 A GB439890 A GB 439890A GB 17288/34 A GB17288/34 A GB 17288/34A GB 1728834 A GB1728834 A GB 1728834A GB 439890 A GB439890 A GB 439890A
Authority
GB
United Kingdom
Prior art keywords
acid
black
bath
dyeing
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB17288/34A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Gesellschaft fuer Chemische Industrie in Basel CIBA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gesellschaft fuer Chemische Industrie in Basel CIBA filed Critical Gesellschaft fuer Chemische Industrie in Basel CIBA
Publication of GB439890A publication Critical patent/GB439890A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/655Compounds containing ammonium groups
    • D06P1/66Compounds containing ammonium groups containing quaternary ammonium groups

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Abstract

Acid wool dyes, dyeing with.--The dyeing of animal fibres with dyes, containing one or more sulpho groups but no metal in complex combination, that dye in an acetic acid bath, is facilitated by adding to such a dyebath, an amount not exceeding 0,5 per cent of the weight of the goods to be dyed, a soluble salt of an organic water-insoluble nitrogenous base or of a quaternary ammonium compound, which base or compound contains at least one aliphatic or cycloaliphatic residue containing at least 8 carbon atoms but contains no polyethenoxy group. A preparation for addition to the dye-bath may contain the dyestuff together with the soluble salt in an amount not exceeding 5 per cent of the weight of the dyestuff. Specified soluble salts are the trimethylammonium-sulphomethylate of monostearoyl- or monooleyl - p - phenylenediamine or of monostearoyl-or monooleyl-ethylenediamine the hydrochloride of diethylcetylamine, dimethyloctodecylamine or pentadecyldihydroimidazole, octodecyltri-methylammonium sulphomethylate, cetylpyridinium chloride or bromide, the salts of unsulphonated cyclic amidines and their quaternary ammonium compounds as described in Specifications 403,977 and 419,010, the mixed ether of cetyl alcohol and N-oxymethylpyridinium chloride, the soluble salts of the stearic acid ester of dimethyl- or diethyl-aminoethanol, stearylcholine hydrochloride or the corresponding benzyl compound, the palmitic acid ester of 1 - oxyphenyl - 3 - trimethylammonium chloride, the stearic acid ester of oxyethyl-pyridinium chloride, the hydrochloride of diethylaminoethyloctodecyl carbonate, the stearic acid ester of the addition product from pyridine and glycerolmonochlorhydrin or a : a <1> glyceroldichlorhydrin, the corresponding compounds in which the stearic or palmitic acid residue is replaced by the residue of oleic, capric, lauric, myristic or ricinoleic acid or the cetyl alcoholic residue is replaced by that of oleyl or other higher alcohols; similar derivatives of diethylenetriamine or of triethylenetetramine may also be used. Specified dyestuffs, additional to those of the examples below, are Benzyl bordeaux B, Bordeaux B, Neutral blue R, Neutral blue B, Blue black N, Acid black HA, Acid black green G, Palatine black A, Cloth fast blue R, Naphthylamine black V, Jet black R, Cloth fast black BN, Nerol B, Biebrich patent black 4AN, Cloth fast black B, Acid black D, Naphthol black 6B and those dyeing in an acetic acid bath described in Specifications 25866/12, 30055/13, 114,339, and 211,742, [all in Class 2 (iii)]. The following examples are specified: (1) 10 Parts of wool are entered into a bath at 60 DEG C. containing sodium sulphate, acetic acid, 0.5 part of the dyestuff 1-naphthyl-amine --> 1 - naphthol - 3 : 6 - disulphonic acid, and 0.01 part of the trimethylammonium-sulphomethylate of monostearoylethylenediamine, the bath is heated during 1 hour to boiling and further boiled for 1 hour to obtain a pure deep red dyeing. (2) 10 Parts of wool are entered into a bath at 60 DEG C. containing sodium sulphate, acetic acid, 0.05 part of the dyestuff obtainable by condensing benzaldehyde (1 mol.) with ethylbenzylaniline (2 mols.), sulphonating and oxidizing and reacting the product with p-phenetidine, and 0.01 part of the product of reaction of m -heptadecylbenzimidazole with glycerol chlorhydrin, the bath is heated during \ba1/2\be hour to boiling and further boiled for 1 hour to obtain a vivid deep blue dyeing; the dyestuff may be replaced by the disulphonic acid of sym-1 : 4-di(4<1> : 4<11>-dimethyl) phenylaminoanthraquinone (green) or the 2 : 7-disulphonic acid of 3 : 6-diphenyl naphthophenosafranine (blue). (3) 100 Parts of a mixture of the dyestuffs, 4-nitraniline --> (acid) 1 : 8 : 3 : 6 - aminonaphtholsulphonic acid (alkaline) \sM aniline, Orange II and Benzyl bordeaux B are stirred at 100 DEG C. and 20 parts of a 10 per cent alcoholic solution of the mixture of hydrochlorides of N-dioxypropylimidazoles, obtainable by treating with glycerol chlorhydrin the benzimidazole product from o-phenylenediamine and hydrogenated fish oil, is sprayed on to the mixture. (4) 100 Parts of the dyestuff, 1 : 8 : 3 : 6-aminonaphthol-sulphonic acid --> 1-phenylaminonaphthalene-8-sulphonic acid, are pasted with alcohol and mixed with 15 parts of an alcoholic solution containing phosphoric acid and 10 per cent of the mixture of the hydrochlorides of N-dioxy-propylimidazoles referred to in (3) and the mixture is dried; the products of (3) and (4) with or without addition of a dispersing agent are suitable for incorporation in a bath for dyeing wool according to standard practice. (5) 10 Parts of wetted wool are entered into a bath at 60 DEG C. containing acetic acid, 0.4 part of Acid black green G and 0.01--0.015 part of the mixture of N-oxyalkylated imidazoles obtainable by treating with glycerol chlorhydrin and ethylene chlorhydrin the imidazole product from o-phenylenediamine and coconut oil, the bath is heated during \ba3/4\be hour and further boiled for 1 hour whereupon sulphuric acid is added and the boiling continued for 20 minutes to obtain a deep black dyeing. Specifications 306,116, [Class 2 (iii)], 364,104, 372,325, 436,790, and 436,863 also are referred to. The Specification as open to inspection under Sect. 91 comprises also the use of the soluble salts of the base or quaternary ammonium compounds in printing. This subject-matter does not appear in the Specification as accepted.
GB17288/34A 1933-06-09 1934-06-11 Improvements in dyeing animal fibres Expired GB439890A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH439890X 1933-06-09

Publications (1)

Publication Number Publication Date
GB439890A true GB439890A (en) 1935-12-11

Family

ID=4515164

Family Applications (1)

Application Number Title Priority Date Filing Date
GB17288/34A Expired GB439890A (en) 1933-06-09 1934-06-11 Improvements in dyeing animal fibres

Country Status (1)

Country Link
GB (1) GB439890A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2572741A1 (en) * 1984-11-05 1986-05-09 Ciba Geigy Ag PROCESS FOR IMPROVING THE TINCTORIAL YIELD AND HUMIDITY SOLIDITY OF DYES OR PRINTS PRODUCED WITH ANIONIC DYES ON CELLULOSE FIBER MATERIALS
CH669704GA3 (en) * 1985-11-06 1989-04-14 Increasing yield and wet fastness of dyeing or print on cellulose - using cationic fibre reactive cpd. prepd. from phenyl-imidazole and epihalohydrin

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2572741A1 (en) * 1984-11-05 1986-05-09 Ciba Geigy Ag PROCESS FOR IMPROVING THE TINCTORIAL YIELD AND HUMIDITY SOLIDITY OF DYES OR PRINTS PRODUCED WITH ANIONIC DYES ON CELLULOSE FIBER MATERIALS
CH669704GA3 (en) * 1985-11-06 1989-04-14 Increasing yield and wet fastness of dyeing or print on cellulose - using cationic fibre reactive cpd. prepd. from phenyl-imidazole and epihalohydrin

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