GB385488A - A process for the production of alcohols - Google Patents
A process for the production of alcoholsInfo
- Publication number
- GB385488A GB385488A GB8004/32A GB800432A GB385488A GB 385488 A GB385488 A GB 385488A GB 8004/32 A GB8004/32 A GB 8004/32A GB 800432 A GB800432 A GB 800432A GB 385488 A GB385488 A GB 385488A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fatty acid
- alcohols
- choh
- salt
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001298 alcohols Chemical class 0.000 title abstract 2
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 4
- 229930195729 fatty acid Natural products 0.000 abstract 4
- 239000000194 fatty acid Substances 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical class CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- 150000004665 fatty acids Chemical class 0.000 abstract 3
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 229940044172 calcium formate Drugs 0.000 abstract 2
- 239000004281 calcium formate Substances 0.000 abstract 2
- 235000019255 calcium formate Nutrition 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- 159000000007 calcium salts Chemical class 0.000 abstract 1
- 150000001728 carbonyl compounds Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 235000019864 coconut oil Nutrition 0.000 abstract 1
- 239000003240 coconut oil Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 229940116318 copper carbonate Drugs 0.000 abstract 1
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 abstract 1
- -1 fatty acid salts Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910001385 heavy metal Inorganic materials 0.000 abstract 1
- JYVHOGDBFNJNMR-UHFFFAOYSA-N hexane;hydrate Chemical compound O.CCCCCC JYVHOGDBFNJNMR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 150000003333 secondary alcohols Chemical class 0.000 abstract 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Alcohols are prepared by heating any salt of a fatty acid in a solvent with calcium formate or the salt of another fatty acid and simultaneously reducing the carbonyl compound formed by means of hydrogen under pressure in the presence of a hydrogenating catalyst. The fatty acid salts may be those of barium, strontium, magnesium, the alkali metals, and the heavy metals, e.g. zinc, nickel and copper. According to the examples, octodecyl alcohol is obtained by forcing hydrogen into an autoclave containing a solution of sodium stearate and calcium formate in water or cyclohexane to which copper carbonate precipitated on kieselguhr has been added and maintaining the autoclave at an elevated temperature for some time; similar treatment of a mixture of the calcium salts of acetic acid and the fatty acids of coconut oil yields a mixture of the secondary alcohols C11H21.CHOH.CH3 and C13H25.CHOH.CH3.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB151072D DE574834C (en) | 1931-07-16 | 1931-07-16 | Process for the production of alcohols |
| DE385488X | 1931-11-14 | ||
| DEB157269D DE586067C (en) | 1931-07-16 | 1932-09-04 | Process for the production of alcohols |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB385488A true GB385488A (en) | 1932-12-29 |
Family
ID=34068642
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8004/32A Expired GB385488A (en) | 1931-07-16 | 1932-03-17 | A process for the production of alcohols |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB385488A (en) |
-
1932
- 1932-03-17 GB GB8004/32A patent/GB385488A/en not_active Expired
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB385488A (en) | A process for the production of alcohols | |
| US1877991A (en) | Production of hydroaromatic carboxylic acids | |
| GB412766A (en) | Improved process for manufacturing fatty esters | |
| US2340688A (en) | Process of forming alcohols | |
| GB385551A (en) | A process for the production of carbonyl compounds | |
| GB718779A (en) | Process for manufacturing pentachlorophenol and alkali pentachlorophenates | |
| GB381476A (en) | A process for the production of primary alcohols | |
| GB418723A (en) | A manufacture of primary diterpene-alcohols | |
| GB415472A (en) | Improvements in or relating to the manufacture of oxalic acid and esters thereof | |
| GB672349A (en) | Improvements in or relating to the synthesis of alcohols | |
| GB263311A (en) | Process for the production of camphene from pinene hydrochloride | |
| GB570957A (en) | Improvements relating to the production of unsaturated alcohols | |
| GB455018A (en) | Process for the manufacture of esters of polycyclic alcohols | |
| GB468025A (en) | Process for the manufacture of reduction products derived from dehydroandrosterone | |
| SU118129A1 (en) | The method of obtaining 0-4-xylidine | |
| GB573788A (en) | Improvements relating to the production of alcohols | |
| GB736074A (en) | Process for the manufacture of butyraldehyde | |
| GB494666A (en) | Process of preparing monohydric alcohols | |
| GB455020A (en) | Process for the production of derivatives of androstenols | |
| SU88639A1 (en) | The method of obtaining citronellal | |
| GB119249A (en) | Process of Producing Alcohols. | |
| GB562610A (en) | Improved production of unsaturated alcohols and/or unsaturated esters | |
| GB465233A (en) | A process for the manufacture of alcohols | |
| GB358869A (en) | Process for the production of higher aliphatic alcohols | |
| GB139419A (en) | A process for the preparation of gallic acid |