GB381476A - A process for the production of primary alcohols - Google Patents
A process for the production of primary alcoholsInfo
- Publication number
- GB381476A GB381476A GB7911/32A GB791132A GB381476A GB 381476 A GB381476 A GB 381476A GB 7911/32 A GB7911/32 A GB 7911/32A GB 791132 A GB791132 A GB 791132A GB 381476 A GB381476 A GB 381476A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alcohol
- calcium
- lauryl alcohol
- solvent
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003138 primary alcohols Chemical class 0.000 title abstract 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 229940044172 calcium formate Drugs 0.000 abstract 2
- 235000019255 calcium formate Nutrition 0.000 abstract 2
- 239000004281 calcium formate Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 abstract 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003568 Sodium, potassium and calcium salts of fatty acids Substances 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 235000013969 calcium salts of fatty acid Nutrition 0.000 abstract 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 abstract 1
- 235000013539 calcium stearate Nutrition 0.000 abstract 1
- 239000008116 calcium stearate Substances 0.000 abstract 1
- HIAAVKYLDRCDFQ-UHFFFAOYSA-L calcium;dodecanoate Chemical compound [Ca+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O HIAAVKYLDRCDFQ-UHFFFAOYSA-L 0.000 abstract 1
- NDWWLJQHOLSEHX-UHFFFAOYSA-L calcium;octanoate Chemical compound [Ca+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O NDWWLJQHOLSEHX-UHFFFAOYSA-L 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 150000001845 chromium compounds Chemical class 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 229940116318 copper carbonate Drugs 0.000 abstract 1
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Primary alcohols are prepared by heating calcium formate in a solvent with the calcium salts of fatty acids and simultaneously reducing the aldehydes formed by means of hydrogen at elevated pressures in the presence of hydrogenating catalysts. Solvents specified are tetraline (a registered Trade Mark), dodecane, butyl alcohol, and the alcohol which comprises the reaction product in any particular case. Copper, nickel, cobalt, and chromium compounds, with or without previous reduction, are mentioned as catalysts. According to the example, calcium formate and calcium octoate are dissolved in lauryl alcohol, copper carbonate precipitated on kieselguhr added, and the mixture then heated in an autoclave whilst hydrogen is forced in; the resulting octyl alcohol is separated by distillation from the lauryl alcohol employed as solvent. In a similar manner, lauryl alcohol can be obtained from calcium laurate and stearic alcohol from calcium stearate.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEB151072D DE574834C (en) | 1931-07-16 | 1931-07-16 | Process for the production of alcohols |
DEB157269D DE586067C (en) | 1931-07-16 | 1932-09-04 | Process for the production of alcohols |
Publications (1)
Publication Number | Publication Date |
---|---|
GB381476A true GB381476A (en) | 1932-10-06 |
Family
ID=34066197
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB7911/32A Expired GB381476A (en) | 1931-07-16 | 1932-03-17 | A process for the production of primary alcohols |
GB22313/33A Expired GB406714A (en) | 1931-07-16 | 1933-08-09 | A process for the production of alcohols |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB22313/33A Expired GB406714A (en) | 1931-07-16 | 1933-08-09 | A process for the production of alcohols |
Country Status (5)
Country | Link |
---|---|
AT (2) | AT135004B (en) |
CH (1) | CH159405A (en) |
DE (2) | DE574834C (en) |
DK (1) | DK48939C (en) |
GB (2) | GB381476A (en) |
-
1931
- 1931-07-16 DE DEB151072D patent/DE574834C/en not_active Expired
-
1932
- 1932-03-17 GB GB7911/32A patent/GB381476A/en not_active Expired
- 1932-03-18 CH CH159405D patent/CH159405A/en unknown
- 1932-03-23 DK DK48939D patent/DK48939C/en active
- 1932-04-09 AT AT135004D patent/AT135004B/en active
- 1932-09-04 DE DEB157269D patent/DE586067C/en not_active Expired
-
1933
- 1933-08-09 GB GB22313/33A patent/GB406714A/en not_active Expired
- 1933-08-10 AT AT141160D patent/AT141160B/en active
Also Published As
Publication number | Publication date |
---|---|
DE574834C (en) | 1933-04-20 |
AT141160B (en) | 1935-03-25 |
CH159405A (en) | 1933-01-15 |
DK48939C (en) | 1934-07-02 |
GB406714A (en) | 1934-03-08 |
AT135004B (en) | 1933-10-25 |
DE586067C (en) | 1933-10-18 |
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