GB379587A - Improved process for the hydrogenation of carbonaceous materials and catalysts therefor - Google Patents
Improved process for the hydrogenation of carbonaceous materials and catalysts thereforInfo
- Publication number
- GB379587A GB379587A GB34935/31A GB3493531A GB379587A GB 379587 A GB379587 A GB 379587A GB 34935/31 A GB34935/31 A GB 34935/31A GB 3493531 A GB3493531 A GB 3493531A GB 379587 A GB379587 A GB 379587A
- Authority
- GB
- United Kingdom
- Prior art keywords
- compounds
- hydrogen
- yield
- metal compound
- sulphur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Catalysts for production of hydrocarbon by reaction of hydrogen upon carbonaceous materials, such as naphthalene, coal, wood, oils, &c., and for the refining of crude benzol &c. and conversion of oxygen and sulphur compounds into the corresponding hydrocarbons are prepared by mixing a solution in water, alcohol, &c. of a metal compound with an adsorbent such as active carbon, pumice, broken pottery, silica gel, alumina gel, Fuller's earth, bleaching earth, burnt fire clay, adsorption clay, coke, &c. and treating the mixture so as to yield a metal or metal compound which is insoluble and becomes adsorbed. Preferably metal compounds are used which yield catalysts immune to sulphur poisoning, such as compounds of metals of the 6th group, particularly molybdenum and tungsten. Compounds of chromium, uranium, tin, vanadium, manganese, rhenium, zinc, cadmium, aluminium or cobalt may be used. The conversion of the metal compound may be effected (1) by reduction with hydrogen, hydrogen sulphide, sulphur dioxide, &c. which may be used under pressures up to 200 atmospheres or with liquid reagents such as hydrazine, or formic acid; (2) by treatment with hydrogen sulphide or ammonia to yield compounds of colloidal nature, precipitation being avoided by adjusting the pH concentration or by use of buffer solutions; or (3) by heating the solutions. The reducing action of the adsorbent may be utilized, and enhanced by a previous treatment with hydrogen or hydrogen sulphide. Specifications 29049/12, 208,656, 255,884, 286,309, [all in Class 1 (i), Chemical processes &c.], 328,992 and 332,336, [both in Class 32, Distilling &c.], are referred to.ALSO:Catalysts for the production of hydrocarbons by the conversion of oxygen and sulphur compounds with the aid of hydrogen, e.g. the production of aromatic and hydroaromatic hydrocarbons from phenol and cresols, are prepared by mixing a solution in water, alcohol &c. of a metal compound with an absorbent such as active carbon, pumice, broken pottery, silica gel, alumina gel, fullers earth, bleaching earth, burnt fire clay, adsorption clay, coke, &c., and treating the mixture so as to yield a metal or metal compound which is insoluble and becomes adsorbed. Preferably metal compounds are used which yield catalysts immune to sulphur poisoning such as compounds of metals of the 6th group, particularly molybdenum and tungsten. Compounds of chromium, uranium, tin vanadium, manganese, rhenium, zinc, cadmium, aluminium or cobalt may be used. The conversion of the metal compound may be effected (1) by reduction with hydrogen, hydrogen p sulphide, sulphur dioxide &c. which may be used under pressures up to 200 atmospheres or with liquid reagents such as hydrazine, or formic acid; (2) by treatment with hydrogen sulphide or ammonia to yield compounds of colloidal nature, precipitation being avoided by adjusting the pH concentration or by the use of buffer solutions; or (3) by heating the solutions. The reducing action of the adsorbent may be utilized, and enhanced by a previous treatment with hydrogen or hydrogen sulphide. Specifications 29049/12, 208,656, 255,884, 286,309, [all in Class 1 (i), Chemical processes &c.], 328,992, and 332,336, [both in Class 32, Distilling &c.], are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL379587X | 1930-12-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB379587A true GB379587A (en) | 1932-09-01 |
Family
ID=19785638
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB34935/31A Expired GB379587A (en) | 1930-12-18 | 1931-12-17 | Improved process for the hydrogenation of carbonaceous materials and catalysts therefor |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB379587A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE926664C (en) * | 1937-03-11 | 1955-04-21 | Degussa | Process for the pressure hydrogenation of coals, tars, mineral oils or their distillation or conversion products |
DE3212389A1 (en) * | 1981-04-08 | 1982-11-04 | Deutsche Bp Ag, 2000 Hamburg | Process for preparing a mixture of coal-based materials, and catalysts for use in hydrogenation processes |
-
1931
- 1931-12-17 GB GB34935/31A patent/GB379587A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE926664C (en) * | 1937-03-11 | 1955-04-21 | Degussa | Process for the pressure hydrogenation of coals, tars, mineral oils or their distillation or conversion products |
DE3212389A1 (en) * | 1981-04-08 | 1982-11-04 | Deutsche Bp Ag, 2000 Hamburg | Process for preparing a mixture of coal-based materials, and catalysts for use in hydrogenation processes |
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