GB378324A - Improvements in or relating to fluoration - Google Patents
Improvements in or relating to fluorationInfo
- Publication number
- GB378324A GB378324A GB2265/32A GB226532A GB378324A GB 378324 A GB378324 A GB 378324A GB 2265/32 A GB2265/32 A GB 2265/32A GB 226532 A GB226532 A GB 226532A GB 378324 A GB378324 A GB 378324A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fluoration
- antimony
- antimony pentachloride
- relating
- points
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/208—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being MX
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Halogen derivatives of aliphatic hydrocarbons having relatively high melting-points have their melting points reduced before treatment with a fluorating agent. For example, hexachloroethane, hexabromoethane, or tetrabromodichloroethane is mixed with antimony pentachloride, and then treated with a fluorating agent such as hydrogen fluoride or antimony trifluoride. The antimony pentachloride may be prepared in situ from the trichloride and chlorine. By varying the temperature of the dephlegmator during the fluoration, the degree of fluoration is also varied. Specification 359,997 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US378324XA | 1931-01-30 | 1931-01-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB378324A true GB378324A (en) | 1932-08-11 |
Family
ID=21896607
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2265/32A Expired GB378324A (en) | 1931-01-30 | 1932-01-25 | Improvements in or relating to fluoration |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE594751C (en) |
FR (1) | FR730370A (en) |
GB (1) | GB378324A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2870224A (en) * | 1956-06-05 | 1959-01-20 | Hoechst Ag | Production of 1, 1-difluoro-1, 2, 2-trichloroethane |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2678953A (en) * | 1950-10-14 | 1954-05-18 | Douglas Aircraft Co Inc | Method of making fluorinated organic bromides and resulting new chemical compounds |
DE949821C (en) * | 1952-08-13 | 1956-09-27 | Hoechst Ag | Process for the production of 1, 2, 3, 4-tetrachlorohexafluorobutane |
-
1932
- 1932-01-23 FR FR730370D patent/FR730370A/en not_active Expired
- 1932-01-25 GB GB2265/32A patent/GB378324A/en not_active Expired
- 1932-01-26 DE DEF72652D patent/DE594751C/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2870224A (en) * | 1956-06-05 | 1959-01-20 | Hoechst Ag | Production of 1, 1-difluoro-1, 2, 2-trichloroethane |
Also Published As
Publication number | Publication date |
---|---|
FR730370A (en) | 1932-08-11 |
DE594751C (en) | 1934-03-21 |
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