GB377658A - Process for the preparation of acetylene, hydrogen and carbon-monoxide - Google Patents

Process for the preparation of acetylene, hydrogen and carbon-monoxide

Info

Publication number
GB377658A
GB377658A GB2086/31A GB208631A GB377658A GB 377658 A GB377658 A GB 377658A GB 2086/31 A GB2086/31 A GB 2086/31A GB 208631 A GB208631 A GB 208631A GB 377658 A GB377658 A GB 377658A
Authority
GB
United Kingdom
Prior art keywords
carbon
hydrogen
electrodes
methane
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2086/31A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Publication of GB377658A publication Critical patent/GB377658A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/342Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents with the aid of electrical means, electromagnetic or mechanical vibrations, or particle radiations
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/80Processes with the aid of electrical means

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electromagnetism (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Toxicology (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

A mixture of hydrogen, carbon monoxide and acetylene is obtained by submitting gaseous hydrocarbons, such as methane or gases containing it, in admixture with an oxygen-yielding compound or a mixture of such compounds, such as carbon dioxide or steam, to the action of the electric arc. If carbon electrodes and an excess of oxygen-yielding compound are used, the carbon of the electrodes reacts, thus providing a means of varying the proportions of carbon monoxide and hydrogen in the product. In an example, a methane-rich residue from the treatment of coke oven gas is mixed with carbon dioxide and treated in an electric arc between carbon electrodes.ALSO:A mixture of acetylene, hydrogen, and carbon monoxide is obtained by submitting gaseous hydrocarbons, such as methane or gases containing it, in admixture with an oxygen-yielding compound or a mixture of such compounds, such as carbon dioxide or steam, to the action of the electric arc. If carbon electrodes and an excess of oxygen-yielding compound are employed, the carbon of the electrodes reacts, thus providing a means of varying the proportions of carbon monoxide and hydrogen in the product, these being preferably adjusted to the correct proportions for the synthesis of, for example, methyl alcohol. When employing steam it may be advantageous to add carbon monoxide of foreign origin. In an example, a methane-rich residue from the treatment of coke oven gas is mixed with carbon dioxide and treated in an electric arc between carbon electrodes.
GB2086/31A 1930-03-17 1931-01-21 Process for the preparation of acetylene, hydrogen and carbon-monoxide Expired GB377658A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE377658X 1930-03-17

Publications (1)

Publication Number Publication Date
GB377658A true GB377658A (en) 1932-07-28

Family

ID=6344445

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2086/31A Expired GB377658A (en) 1930-03-17 1931-01-21 Process for the preparation of acetylene, hydrogen and carbon-monoxide

Country Status (1)

Country Link
GB (1) GB377658A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2802522A1 (en) * 1999-12-20 2001-06-22 Air Liquide Hydrogen production process from hydrocarbons comprises using a reactive element and a pressure of 1-10 bar

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2802522A1 (en) * 1999-12-20 2001-06-22 Air Liquide Hydrogen production process from hydrocarbons comprises using a reactive element and a pressure of 1-10 bar

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