GB363823A - Improvements in the manufacture and production of valuable lubricating oils - Google Patents

Improvements in the manufacture and production of valuable lubricating oils

Info

Publication number
GB363823A
GB363823A GB3808230A GB3808230A GB363823A GB 363823 A GB363823 A GB 363823A GB 3808230 A GB3808230 A GB 3808230A GB 3808230 A GB3808230 A GB 3808230A GB 363823 A GB363823 A GB 363823A
Authority
GB
United Kingdom
Prior art keywords
oil
oils
hydrogen
chloride
lbs
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3808230A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to GB3808230A priority Critical patent/GB363823A/en
Publication of GB363823A publication Critical patent/GB363823A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M3/00Liquid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single liquid substances
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/22Alkylation reaction products with aromatic type compounds, e.g. Friedel-crafts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

Lubricating oils are obtained by dehydrogenating hydrocarbon oils having a substantial content, e.g. 20-80 per cent of paraffin wax, separating the products by solvents into a fraction containing more than 14,5 parts by weight of hydrogen to 100 parts of carbon, and a fraction poorer in hydrogen, and subjecting the fraction richer in hydrogen, maybe mixed with hydrocarbon which is liquid at a temperature between 50 and 300 DEG C., to catalytic condensation or/and polymerization. The products may be used to improve inferior oils, and the fractions poorer in hydrogen may be hydrogenated and fractioned to produce motor fuels. Initial materials specified are brown coal tar oils, mineral oils, petrolatum or other refining or distillation residue of petroleum, petroleum jelly, crude paraffin wax, crude lubricating oils, or wax-containing products of the destructive hydrogenation of coals, tars, and mineral oils. The dehydrogenation may be effected by: (1) introducing substituents, e.g. chlorine or other halogen or sulphur, and removing hydrogen compounds thereof, e.g. in the case of halogens by heating to 200-400 DEG C. in presence of catalysts such as alumina, bauxite, zinc chloride, barium chloride, or titanium oxide; or (2) treating with oxidizing gases, e.g. air or oxygen, and splitting off water or water and carbon dioxide in presence of phosphorus pentoxide or caustic alkalis; or (3) cracking, preferably mildly, at 450-600 DEG C. in presence of catalysts such as metals of the 6th group or their oxides or compounds alone or mixed with each other or copper or other splitting catalysts, maybe with an addition of hydrogen. Solvents specified are liquid sulphur dioxide, aniline, liquid phenols, alcohols, or ketones. Condensation is effected at 20-150 DEG C. in presence of condensing agents, e.g. aluminium chloride, zinc chloride, iron chloride, boron fluoride, phosphorus oxychloride, activated aluminium, sodium, or zinc dust; bleaching earths may be present, or the products of condensation may be treated with bleaching earths. Added hydrocarbons which may be present are naphthalene, coal tar fractions, e.g. crude benzene, aromatic middle oil, and anthracene oil, aromatic oils obtained by the destructive hydrogenation of coals or their tars or by condensation at elevated temperatures of cracking gases or other olefines, brown coal tars, mineral oils, distillation, extraction, or destructive hydrogenation products thereof, and liquid olefines obtained by cracking solid paraffin waxes. In examples (1) 100 lb. of petrolatum is cracked several times at 490-530 DEG C., and the 72 lb. of oil boiling up to 300 DEG C. is treated with liquid sulphur dioxide; the 60 lb. undissolved is condensed at 30-110 DEG C. in presence of 3 lb. of aluminium chloride; there results 25 lb. of lubricating oil and 35 lb. of benzine and middle oil. (2) The 200-280 DEG C. fraction of a hydrogenated German crude oil is treated with chlorine until 18 per cent is absorbed; hydrogen chloride is split off by heating to 350 DEG C. in presence of bauxite, and the product treated with liquid sulphur dioxide; 100 lb. of the insoluble oil is condensed at 30-100 DEG C. in presence of 7 lb. of aluminium chloride; 30 lb. of lubricating oil, and unchanged oil are obtained.ALSO:Lubricating oils are obtained by dehydrogenating hydrocarbon oils having a substantial content, e.g. 20-80 per cent of paraffin wax, separating the products by solvents into a fraction containing more than 14,5 parts by weight of hydrogen to 100 parts of carbon, and a fraction poorer in hydrogen, and subjecting the fraction richer in hydrogen, may be mixed with hydrocarbon which is liquid at a temperature between 50 DEG and 300 DEG C., to catalytic condensation or/and polymerization. The products maybe used to improve inferior oils, and the fractions poorer in hydrogen may be hydrogenated and fractioned to produce motor fuels. Initial materials specified are brown coal tar oils, mineral oils, petrolatum or other refining or distillation residue of petroleum, petroleum jelly, crude paraffin wax, crude lubricating oils, or wax-containing products of the destructive hydrogenation of coals, tars, and mineral oils. The dehydrogenation may be effected by (1) introducing substituents, e.g. chlorine or other halogen or sulphur, and removing hydrogen compounds thereof, e.g. in the case of halogens by heating to 200-400 DEG C. in presence of catalysts such as alumina, bauxite, zinc chloride, barium chloride, or titanium oxide; or (2) treating with oxidizing gases, e.g. air or oxygen, and splitting off water or water and carbon dioxide in presence of phosphorus pentoxide or caustic alkalis; or (3) cracking, preferably mildly, at 450-600 DEG C. in presence of catalysts such as metals of the 6th group or their oxides or compounds alone or mixed with each other or copper or other splitting catalysts, maybe with an addition of hydrogen. Solvents specified are liquid sulphur dioxide, aniline, liquid phenols, alcohols, or k ketones. Condensation is effected p at 20-150 DEG C. in presence of condensing agents, e.g. aluminium chloride, zinc chloride, iron chloride, boron fluoride, phosphorus oxychloride, activated aluminium, sodium, or zinc dust; bleaching earths maybe present, or the products of condensation may be treated with bleaching earths. Added hydrocarbons which may be present are naphthalene, coal tar fractions, e.g. crude benzene, aromatic middle oil, and anthracene oil, aromatic oils obtained by the destructive hydrogenation of coals or their tars or by condensation at elevated temperatures of cracking gases or other olefines, brown coal tars, mineral oils, distillation, extraction, or destructive hydrogenation products thereof, and liquid olefines obtained by cracking solid paraffin waxes. In examples (1) 100 lbs. of petrolatum is cracked several times at 490-530 DEG C., and the 72 lbs. of oil boiling up to 300 DEG C. is treated with liquid sulphur dioxide; the 60 lbs. undissolved is condensed at 30-110 DEG C. in presence of 3 lbs. of aluminium chloride; there results 25 lbs. of lubricating oil and 35 lbs. of benzine and middle oil. (2) The 200-280 DEG C. fraction of a hydrogenated German crude oil is treated with chlorine until 18 per cent is absorbed; hydrogen chloride is split off by heating to 350 DEG C. in presence of bauxite, and the product treated with liquid sulphur dioxide; 100 lbs. of the insoluble oil is condensed at 30-100 DEG C. in presence of 7 lbs. of aluminium chloride; 30 lbs. of lubricating oil, and unchanged oil are obtained.
GB3808230A 1930-12-17 1930-12-17 Improvements in the manufacture and production of valuable lubricating oils Expired GB363823A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3808230A GB363823A (en) 1930-12-17 1930-12-17 Improvements in the manufacture and production of valuable lubricating oils

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3808230A GB363823A (en) 1930-12-17 1930-12-17 Improvements in the manufacture and production of valuable lubricating oils

Publications (1)

Publication Number Publication Date
GB363823A true GB363823A (en) 1931-12-31

Family

ID=10401049

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3808230A Expired GB363823A (en) 1930-12-17 1930-12-17 Improvements in the manufacture and production of valuable lubricating oils

Country Status (1)

Country Link
GB (1) GB363823A (en)

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