GB357543A - Manufacture of metalliferous dyestuffs - Google Patents

Manufacture of metalliferous dyestuffs

Info

Publication number
GB357543A
GB357543A GB18926/30A GB1892630A GB357543A GB 357543 A GB357543 A GB 357543A GB 18926/30 A GB18926/30 A GB 18926/30A GB 1892630 A GB1892630 A GB 1892630A GB 357543 A GB357543 A GB 357543A
Authority
GB
United Kingdom
Prior art keywords
acid
grey
aminophenol
dyestuff
tints
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB18926/30A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Gesellschaft fuer Chemische Industrie in Basel CIBA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gesellschaft fuer Chemische Industrie in Basel CIBA filed Critical Gesellschaft fuer Chemische Industrie in Basel CIBA
Publication of GB357543A publication Critical patent/GB357543A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B33/00Disazo and polyazo dyes of the types A->K<-B, A->B->K<-C, or the like, prepared by diazotising and coupling
    • C09B33/02Disazo dyes
    • C09B33/08Disazo dyes in which the coupling component is a hydroxy-amino compound
    • C09B33/10Disazo dyes in which the coupling component is a hydroxy-amino compound in which the coupling component is an amino naphthol

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Abstract

Azo dyes, soluble metal compounds of; regenerated celluloses, dyeing.-Azo dyestuffs containing metal and capable of dyeing stripy viscose uniform fast grey tints are obtained by treating with one or more agents yielding metal disazo dyestuffs of the general formula <FORM:0357543/IV/1> in which R1 is an aryl residue carrying a hydroxyl group in o-position to the azo bridge and R2 is an aryl residue carrying a carboxyl group. The metallization may be effected in acid, neutral, or alkaline media, with or without application of pressure and with or without the presence of alkali metal salts such as sodium formate, acetate, phosphate or chloride. The dyeings of the products on cotton are stated to be faster than those obtainable with the dyestuffs containing chromium specifically referred to in Specification 271,897, [Class 2 (iii), Dyes &c.]. The following examples are specified. (1) The dyestuff, anthranilic acid --> (acid) 2 : 5 : 7-acid (alkaline) \sM 5-nitro-2-aminophenol, is boiled under reflux with a solution of chromium fluoride containing sodium acetate; the product dyes viscose uniform grey blue tints; when the o-oxydiazo component is replaced by 4-nitro-2-aminophenol-6-sulphonic acid and 4-chloro-5-nitro-2-aminophenol, the dyeings are blue grey and greenish grey respectively; the use as o-oxydiazo component of 4-chloro-2-aminophenol or of its 6-sulphonic acid yields similar dyeings. (2) The sodium salt of the dyestuff, anthranilic acid --> (acid) 2 : 5 : 7-acid (alkaline) \sM 6-nitro-2-aminophenol-4-sulphonic acid or 4-nitro-2-aminophenol-6-sulphonic acid, is boiled under reflux with a solution of chromium fluoride; the products dye viscose p uniform grey blue tints. (3) The sodium salt of the dyestuff, m-aminobenzoic acid --> (acid) 2 : 5 : 7-acid (alkaline) \sM 6-nitro-2-aminophenol-4-sulphonic acid or 4-nitro-2-aminophenol-6-sulphonic acid, is boiled under reflux with a solution of chromium fluoride; the products dye viscose neutral grey and red grey tints respectively; when the o-oxydiazo component is 4-chloro-2-aminophenol-6-sulphonic acid or 5-nitro-2-aminophneol the dyeings are grey to blue grey. (4) The sodium salt of the dyestuff, anthranilic acid --> (acid) 2 : 5 : 7-acid (alkaline) \sM 4-chloro-2-aminophneol-6-sulphonic acid, is boiled under reflux with a solution of nickel chloride (NiCl2) and boiling is continued with addition of chromium fluoride; the product dyes viscose uniform grey tints. (5) The sodium salt of the first dyestuff of (2) above is treated with an ammoniacal solution of copper oxide and the copper compound separated by addition of acetic acid is boiled under reflux with a solution of chromium fluoride; the product dyes viscose uniform grey violet tints. (6) The sodium salt of the dyestuff, anthranilic acid --> (acid) 2 : 5 : 7-acid (alkaline) \sM 4-chloro-2-aminophenol-5-sulphonic acid, is treated with an ammoniacal solution of copper oxide and the copper compound is chromed as in (5); the product dyes viscose grey tints. (7) The first dyestuff of (1) above is boiled under reflux with a solution of chromium fluoride containing sodium acetate and the resulting chromium compound is coppered by means of copper sulphate; the product dyes viscose grey tints; when the proportion of chromium to copper is increased a product yielding grey violet tints is obtained; alternatively the copper may be introduced before, instead of after, the chromium. (8) Cotton is dyed by boiling for 1/2 -\ba3/4 hr. in a bath containing the metalliferous dyestuff, Glauber's salt, and common salt, or a feebly alkaline or feebly acid bath may be used. (9) Regenerated cellulose artificial silk is dyed by treatment at 60-80 DEG C. for 1 hr. in a neutral, feebly alkaline, or feebly acid bath containing the metalliferous dyestuff with or without an addition of salt. The manufacture of the copper compounds by coupling to form the azo dyestuff in presence of a water-soluble complex nitrogenous copper compound and the subject-matter claimed in Specification 351,400 are disclaimed. Specifications 26460/12, 16803/15, 116,530, 271,897, 297,003, 300,916, and 306,908, [all in Class 2 (iii), Dyes &c.], also are referred to.
GB18926/30A 1929-06-20 1930-06-20 Manufacture of metalliferous dyestuffs Expired GB357543A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH357543X 1929-06-20

Publications (1)

Publication Number Publication Date
GB357543A true GB357543A (en) 1931-09-21

Family

ID=4511602

Family Applications (1)

Application Number Title Priority Date Filing Date
GB18926/30A Expired GB357543A (en) 1929-06-20 1930-06-20 Manufacture of metalliferous dyestuffs

Country Status (1)

Country Link
GB (1) GB357543A (en)

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