GB349304A - Manufacture of metalliferous dyestuffs - Google Patents
Manufacture of metalliferous dyestuffsInfo
- Publication number
- GB349304A GB349304A GB16201/30A GB1620130A GB349304A GB 349304 A GB349304 A GB 349304A GB 16201/30 A GB16201/30 A GB 16201/30A GB 1620130 A GB1620130 A GB 1620130A GB 349304 A GB349304 A GB 349304A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dyestuff
- alkaline
- acid
- compound
- glauber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B45/00—Complex metal compounds of azo dyes
- C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
- C09B45/14—Monoazo compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
Azo dyes and soluble metal compounds thereof; substantive and acid wool dyes, dyeing with; regenerated celluloses, dyeing.-Azo dyestuffs containing metal are produced by treating with one or more agents yielding metal and with a nitrosating agent, in either order, an azo dyestuff obtainable by coupling in an alkaline medium an o-oxydiazo or o-carboxydiazo compound with an N-substituted 2 : 5 : 7-aminonaphtholsulphonic acid. The nitrosation of the metal compounds of the dyestuffs may be effected in the dyebath or on the fibre. Dyeings are obtainable on animal, vegetable, and regenerated cellulose fibres. The following examples are specified: (1) To an alkaline solution of the chromium compound of the dyestuff 5-nitro-2-aminophenol --> (alkaline) phenyl-2 : 5 : 7-acid is added at 4-6 DEG C. sodium nitrite and the mixture is slowly acidified with sulphuric acid while maintaining the temperature below 10 DEG C.; after neutralization with sodium carbonate the dyestuff is salted out; it dyes cotton or regenerated cellulose silk from a neutral or alkaline Glauber's salt bath, or animal fibre from an acid bath, level steel blue tints; the coupling component may be replaced by a tolyl-2 : 5 : 7-acid. (2) To an aqueous solution of the dyestuff 5-nitro - 2 - aminophenol --> (alkaline) phenyl-2 : 5 : 7-acid is added sodium nitrite, the mixture is slowly acidified with sulphuric acid at 4-10 DEG C., and the dyestuff is salted out; this nitrosated compound is boiled for several hours with a chromic salt; the product has properties similar to those of the corresponding dyestuff in (1). (3) The intermediate nitrosated compound in (2) is converted into the copper compound by treatment with copper sulphate or cupric ammonium sulphate; the product dyes vegetable fibres blue-violet tints from an alkaline p Glauber's salt bath. (4) To a solution, neutralized with caustic soda, of the chromium compound of the dyestuff 4-nitro-2-aminophenol-6-sulphonic acid (2 mols.) \sQ (alkaline) 5 : 51-dioxy-2 : 21-dinaphthylamine-7 : 71 disulphonic acid is added sodium nitrite, and the mixture is slowly acidified with sulphuric acid at 5-10 DEG C.; after neutralization with sodium carbonate and concentrating, the dyestuff is salted out; the product dyes cotton or regenerated cellulose silk level grey-blue tints from a neutral Glauber's salt bath. (5) To a solution, neutralized with caustic soda, of the copper compound of the dyestuff 2 - aminophenol - 4-sulphamide \sQ (alkaline) 5 : 51-dioxy-2 : 21-dinaphthylamine-7 : 71-disulphonic acid is added sodium nitrite, and the mixture is slowly acidified with sulphuric acid at 5-10 DEG C.; after neutralizing and concentrating the dyestuff is salted out; the product dyes vegetable fibre or regenerated cellulose silk red-violet tints from a neutral or alkaline Glauber's salt bath. (6) To a feebly alkaline solution of the dyestuff containing copper and chromium obtainable from the dyestuff 5-nitro-2-aminophenol-4-sulphamide --> (alkaline) phenyl 2 : 5 : 7-acid is added sodium nitrite, and the mixture is slowly acidified with sulphuric acid at 4-6 DEG C.; after neutralization with sodium carbonate the dyestuff is salted out; the product dyes vegetable fibres or regenerated cellulose silk level blue tints from a neutral or alkaline Glauber's salt bath. Examples are also given of the dyeing processes for cotton, viscose silk, and ordinary or weighted silk.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH349304X | 1929-05-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB349304A true GB349304A (en) | 1931-05-28 |
Family
ID=4508692
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB16201/30A Expired GB349304A (en) | 1929-05-25 | 1930-05-26 | Manufacture of metalliferous dyestuffs |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB349304A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5206043A (en) * | 1990-11-30 | 1993-04-27 | W. R. Grace & Co.-Conn. | Containers and compositions for sealing them |
US5211974A (en) * | 1990-09-28 | 1993-05-18 | W. R. Grace & C.-Conn. | Containers and compositions for sealing them |
-
1930
- 1930-05-26 GB GB16201/30A patent/GB349304A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5211974A (en) * | 1990-09-28 | 1993-05-18 | W. R. Grace & C.-Conn. | Containers and compositions for sealing them |
US5206043A (en) * | 1990-11-30 | 1993-04-27 | W. R. Grace & Co.-Conn. | Containers and compositions for sealing them |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CH628670A5 (en) | Method for producing reactive dyes. | |
US3218310A (en) | Pyrimidine azo dyestuffs | |
DE1106897B (en) | Process for the preparation of monoazo dyes | |
US3139438A (en) | Copper phthalocyanine dyestuffs containing (3'-chloro-2'-hydroxypropoxyphenyl) sulfamyl groups | |
GB349304A (en) | Manufacture of metalliferous dyestuffs | |
US3463771A (en) | Chromium or cobalt complexes of monoazo dyestuffs containing a trihalopyrimidyl group | |
US3152114A (en) | Azo dyestuffs | |
US3184280A (en) | Solid-dyeings and prints on polyhydroxylated materials | |
US3005814A (en) | Metal-containing polyazo dyestuffs | |
US2539178A (en) | Metallized azo dyestuff and process of producing the same | |
US3271397A (en) | Reactive anthraquinone dyes containing a trichloro pyrimidyl group | |
US2419334A (en) | Derivatives of amino-benzo-p-dioxans | |
US3725382A (en) | Difluoropyrimidylamino-group-containing metallized water-soluble reactive formazane dyes | |
US2228416A (en) | Azo dyes | |
US2732372A (en) | Chromable monoazo dyestuffs | |
US2143956A (en) | Soluble azo dyestuffs | |
AT220742B (en) | Process for the production of new azo dyes | |
CH606345A5 (en) | Tetrakis:azo dyes contg. two fibre-reactive triazinyl gps. | |
US3169125A (en) | Water-soluble disazo dyes containing reactive groups | |
DE731755C (en) | Process for the production of azo dyes on animal fibers and natural or artificial cellulose fibers as well as on mixtures of animal fibers with cellulose fibers | |
US2322750A (en) | Trisazo dye | |
GB307705A (en) | Manufacture of dyestuffs | |
GB364147A (en) | Manufacture of azo-dyestuffs containing chromium | |
GB363897A (en) | Manufacture of new cellulose derivatives | |
GB374186A (en) | Manufacture of new dyestuffs |