GB307705A - Manufacture of dyestuffs - Google Patents
Manufacture of dyestuffsInfo
- Publication number
- GB307705A GB307705A GB7920/29A GB792029A GB307705A GB 307705 A GB307705 A GB 307705A GB 7920/29 A GB7920/29 A GB 7920/29A GB 792029 A GB792029 A GB 792029A GB 307705 A GB307705 A GB 307705A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- dyestuff
- amino
- chromium
- trisazo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 239000000975 dye Substances 0.000 abstract 16
- 239000002253 acid Substances 0.000 abstract 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 6
- 229920000742 Cotton Polymers 0.000 abstract 6
- 239000007864 aqueous solution Substances 0.000 abstract 6
- 238000004043 dyeing Methods 0.000 abstract 6
- 229920000297 Rayon Polymers 0.000 abstract 5
- 239000003795 chemical substances by application Substances 0.000 abstract 5
- 229910021563 chromium fluoride Inorganic materials 0.000 abstract 5
- FTBATIJJKIIOTP-UHFFFAOYSA-K trifluorochromium Chemical compound F[Cr](F)F FTBATIJJKIIOTP-UHFFFAOYSA-K 0.000 abstract 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 4
- 239000012670 alkaline solution Substances 0.000 abstract 4
- 229910052804 chromium Inorganic materials 0.000 abstract 4
- 239000011651 chromium Substances 0.000 abstract 4
- 238000010992 reflux Methods 0.000 abstract 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 3
- 238000009835 boiling Methods 0.000 abstract 3
- 229910052802 copper Inorganic materials 0.000 abstract 3
- 239000010949 copper Substances 0.000 abstract 3
- SWFNPENEBHAHEB-UHFFFAOYSA-N 2-amino-4-chlorophenol Chemical compound NC1=CC(Cl)=CC=C1O SWFNPENEBHAHEB-UHFFFAOYSA-N 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 238000007689 inspection Methods 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 abstract 2
- QXYMVUZOGFVPGH-UHFFFAOYSA-N picramic acid Chemical compound NC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O QXYMVUZOGFVPGH-UHFFFAOYSA-N 0.000 abstract 2
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 2
- 235000011152 sodium sulphate Nutrition 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- DOPJTDJKZNWLRB-UHFFFAOYSA-N 2-Amino-5-nitrophenol Chemical compound NC1=CC=C([N+]([O-])=O)C=C1O DOPJTDJKZNWLRB-UHFFFAOYSA-N 0.000 abstract 1
- 229920002955 Art silk Polymers 0.000 abstract 1
- GXDVEXJTVGRLNW-UHFFFAOYSA-N [Cr].[Cu] Chemical compound [Cr].[Cu] GXDVEXJTVGRLNW-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000010446 mirabilite Substances 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 239000004627 regenerated cellulose Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000344 soap Substances 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B45/00—Complex metal compounds of azo dyes
- C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
- C09B45/24—Disazo or polyazo compounds
- C09B45/26—Disazo or polyazo compounds containing chromium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B33/00—Disazo and polyazo dyes of the types A->K<-B, A->B->K<-C, or the like, prepared by diazotising and coupling
- C09B33/18—Trisazo or higher polyazo dyes
- C09B33/22—Trisazo dyes of the type A->B->K<-C
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B45/00—Complex metal compounds of azo dyes
- C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
- C09B45/24—Disazo or polyazo compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B45/00—Complex metal compounds of azo dyes
- C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
- C09B45/24—Disazo or polyazo compounds
- C09B45/28—Disazo or polyazo compounds containing copper
Abstract
307,705. Soc. of Chemical industry in Basle. March 10, 1928. [Convention date]. Trisazo dyes and solitble, metal compounds thereof. - Trisazo dyes of the type R1 - N = N - R2 - N = N - R3, in which R1 and R3 are residues of o-oxydiazo compounds and R2 is the residue of the monoazo dyestuff 2-amino-5-Daphthol-7-sulphonic acid # (acid) 2-amino-5-naphthol-7-sulphonic acid are treated in the course of their production, in substance, in the dyebath, or on the fibre with agents yielding chromium, or with an agent or agents yieldmore than one metal, e.g. agents yielding copper- and chromium. The following examples are specified : (1) 1 mol. of the dyestuff 2: 5: 7-acid. - 7- (acid) 2: 5: 7-acid is coupled in alkaline solution with 2 mols. of diazotized 4-chlor-2- aminophenol and the trisazo dyestuff is boiled under reflux with an aqueous solution of chromium fluoride; the product gives level fast' grey dyeings on cotton or viscose from a neutral or feebly alkaline Glauber's salt bath; by boiling the trisazo dyestuff under reflux successively with aqueous solutions of suitable amounts of chromium fluoride and copper sulphate a product containing copper and chromium is obtained which gives level fast reddish-grey dyeings on cotton or viscose. (2) 1 mol. ot the dyestuff 2 : 1<1>-azonaphthalene-5: 5<1>-dioxy-2<1>-amino-7 : 71 - disulphonic acid is coupled in alkaline solution with 2 mols. of diazotized picramic acid and the trisazo dyestuff is boiled under reflux witit all aqueous solution of chromium fluoride ; the products gives uniform fastgreen-grey dyeings on cotton or viscose; the corresponding dyestuff containing copper and chromium gives blue-grey dyeings-. (3) 1 Mol. of the, dyestutf 2 : 1<1>-azonaphthalene 5:5<1>-dioxy-2<1>-amino-7:7<1>-disulphonic acid is coupled in alkaline solution with 2 mois. of diazotized 5-nitro-2-aminophenol and an aqueous solution of the trisazo dyestuff is mixed successively at the boiling point with copper sulphate and chromium fluoride; the product gives level bluegrey dyeings on cotton from an alkaline Glaubers' salt bath. (4) 1 Mol. of the dyestuff 2: 1<1>-azonaphthalene-5 : 5<1>-dioxy-2<1>-amino - -7:7<1>- disulphonic acid is coupled in alkaline solution with 1 mol. of diazotized 4-chlor-2-aminophenol and 1 mol. of diazotized picramic acid and the trisazo dyestuff is boiled under reflux with an aqueous solution of chromium fluoride; the product gives uniform jast grey dyeings on cotton or artificial silk of the regenerated cellulose type, such as viscose or cuprammonium silk; the corresponding dyestuff containing copper and chromium gives similar grey dyeings. (6) Cotton is dyed by entering the wetted goods into an aqueous soli-ttion of the dyestuff at 30-40 C., and boiling, with addition of sodium sulphate, or the dyebath may be made feebly alkaline with sodium carbonate or soap or feebly acid with acetic acid. (6) Viscose is dyed by entering the goods into a solution of the dyestuff at 20 C., and heating to 75-80 C. with addition of sodium sulphate. (7) Ordinary or loaded silk is dyed by entering the goods into an aqueous solution containing acetic acid of the dyestuff of Example (2) at 50-60<0> C. and heating to 80 C. The Specification as open to inspection under Sect. 91 (3) (a) comprises also the manufacture and use of the corresponding dyestuffs in which R.2 is one of the monoazo products 2-amino-5- naphthol-7-sulphonic acid # (acid) 2-amino-8- naphthol-6-sulphomc acid or 2-amino-8-naphthol- 6-sulphonic acid (acid) 2-amino-5-naphthol- 7-sulphonic acid, and refers to the use of agents yielding metals " of the first series of the third period of the periodic system." This subjectmatter does not appear in the Specification as accepted. Specification 26460/12 is referred to. Reference has been directed by the Comptroller to Specifications 16803/15 and 271,897 (as open to inspection under Sect. 91 of the Acts),
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH307705X | 1928-03-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB307705A true GB307705A (en) | 1930-06-11 |
Family
ID=4493250
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB7920/29A Expired GB307705A (en) | 1928-03-10 | 1929-03-11 | Manufacture of dyestuffs |
Country Status (3)
Country | Link |
---|---|
US (1) | US1843634A (en) |
CH (5) | CH133478A (en) |
GB (1) | GB307705A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2891047A (en) * | 1955-08-20 | 1959-06-16 | Bayer Ag | Metal containing polyazo dyestuffs |
US2984635A (en) * | 1957-06-03 | 1961-05-16 | Monsanto Chemicals | Composition comprising alumina particles coated with polymer of ethylenically unsaturated monomer |
-
1928
- 1928-03-10 CH CH133478D patent/CH133478A/en unknown
-
1929
- 1929-03-08 US US345588A patent/US1843634A/en not_active Expired - Lifetime
- 1929-03-11 GB GB7920/29A patent/GB307705A/en not_active Expired
- 1929-06-01 CH CH144212D patent/CH144212A/en unknown
- 1929-06-01 CH CH144213D patent/CH144213A/en unknown
- 1929-06-01 CH CH144214D patent/CH144214A/en unknown
- 1929-06-01 CH CH144215D patent/CH144215A/en unknown
Also Published As
Publication number | Publication date |
---|---|
CH144212A (en) | 1930-12-15 |
US1843634A (en) | 1932-02-02 |
CH144214A (en) | 1930-12-15 |
CH144215A (en) | 1930-12-15 |
CH133478A (en) | 1929-06-15 |
CH144213A (en) | 1930-12-15 |
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